GB214836A - Improvements in the manufacture of ªÐ-dialkylamino-arylphosphinous acids - Google Patents
Improvements in the manufacture of ªÐ-dialkylamino-arylphosphinous acidsInfo
- Publication number
- GB214836A GB214836A GB1197123A GB1197123A GB214836A GB 214836 A GB214836 A GB 214836A GB 1197123 A GB1197123 A GB 1197123A GB 1197123 A GB1197123 A GB 1197123A GB 214836 A GB214836 A GB 214836A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- salts
- dimethylaniline
- dialkylarylamines
- arylphosphinous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 6
- 150000007513 acids Chemical class 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 abstract 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001805 chlorine compounds Chemical class 0.000 abstract 2
- 239000010949 copper Chemical class 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 239000011133 lead Chemical class 0.000 abstract 2
- LFZLVJBOEONQHV-UHFFFAOYSA-N 1-n,1-n,3-n,3-n-tetramethylbenzene-1,3-diamine Chemical compound CN(C)C1=CC=CC(N(C)C)=C1 LFZLVJBOEONQHV-UHFFFAOYSA-N 0.000 abstract 1
- CHHCCYVOJBBCIY-UHFFFAOYSA-N 3-chloro-n,n-dimethylaniline Chemical compound CN(C)C1=CC=CC(Cl)=C1 CHHCCYVOJBBCIY-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 239000011575 calcium Chemical class 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 125000005265 dialkylamine group Chemical group 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- CIPVVROJHKLHJI-UHFFFAOYSA-N n,n-diethyl-3-methylaniline Chemical compound CCN(CC)C1=CC=CC(C)=C1 CIPVVROJHKLHJI-UHFFFAOYSA-N 0.000 abstract 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract 1
- 239000011591 potassium Chemical class 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 230000001225 therapeutic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/4841—Aromatic acids or derivatives (P-C aromatic linkage)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
p-Dialkylaminoarylphosphinous acids are prepared by action of phosphorus trichloride upon an excess of the dialkylarylamines; a diluting agent such as benzene may be present; the phosphenyl chlorides so produced are then hydrolyzed to the corresponding acids or salts, for instance by means of caustic soda. Substitution products of the dialkylarylamines may be used, particularly meta-substituted derivatives. Examples are given of the production of phosphenyl chlorides, and acids in the form of salts, from dimethylaniline, and dimethyl- or diethyl-mtoluidine: sodium, potassium, calcium, copper, iron, and lead salts are described. Other dialkylamines which may be used are 3-chlor-dimethylaniline, 3-alkyloxy-dimethylaniline and tetramethyl-m-phenylenediamine. The products are of therapeutic value.ALSO:Copper, iron, and lead salts of the p-dialkylamino-arylphosphinous acids prepared from dialkylarylamines and phosphous trichloride, followed by hydrolysis with caustic alkali, are described. The salts of the acids from dimethylaniline and dimethyl- or diethyl-m-toluidine are mentioned.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1197123A GB214836A (en) | 1923-05-03 | 1923-05-03 | Improvements in the manufacture of ªÐ-dialkylamino-arylphosphinous acids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1197123A GB214836A (en) | 1923-05-03 | 1923-05-03 | Improvements in the manufacture of ªÐ-dialkylamino-arylphosphinous acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB214836A true GB214836A (en) | 1924-05-01 |
Family
ID=9996022
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1197123A Expired GB214836A (en) | 1923-05-03 | 1923-05-03 | Improvements in the manufacture of ªÐ-dialkylamino-arylphosphinous acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB214836A (en) |
-
1923
- 1923-05-03 GB GB1197123A patent/GB214836A/en not_active Expired
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