GB214221A - An improved process of making metallo-organic compounds - Google Patents
An improved process of making metallo-organic compoundsInfo
- Publication number
- GB214221A GB214221A GB7382/24A GB738224A GB214221A GB 214221 A GB214221 A GB 214221A GB 7382/24 A GB7382/24 A GB 7382/24A GB 738224 A GB738224 A GB 738224A GB 214221 A GB214221 A GB 214221A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- alloy
- alkyl
- metal
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 229910000528 Na alloy Inorganic materials 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001350 alkyl halides Chemical class 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 2
- 229960003750 ethyl chloride Drugs 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910001297 Zn alloy Inorganic materials 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 150000001351 alkyl iodides Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- UAZMXAXHGIZMSU-UHFFFAOYSA-N sodium tin Chemical compound [Na].[Sn] UAZMXAXHGIZMSU-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000001256 steam distillation Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Alkyl derivatives of metals of the second subgroup of the fourth periodic group are prepared by treating a finely divided alloy of the metal with an alkali or alkaline earth metal, under pressure, with an alkyl halide other than an alkyl iodide; metallic zinc, or aluminium or ferric chloride may also be present as a catalyst. Alloys containing 10-20 per cent of sodium are referred to. The reaction vessel is advantageously provided with heating or cooling coils or jacket and also stirring mechanism: it may for example contain balls and be capable of being rotated: the excess alkyl halide is distilled off and the metal alkyl isolated by steam distillation or extraction with a solvent. Examples are given in which a tin-sodium alloy is treated with methyl chloride, a lead-sodium alloy with ethyl chloride or bromide, and a lead-sodium-zinc alloy with ethyl chloride.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US214221XA | 1923-04-13 | 1923-04-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB214221A true GB214221A (en) | 1925-07-22 |
Family
ID=21804129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7382/24A Expired GB214221A (en) | 1923-04-13 | 1924-03-22 | An improved process of making metallo-organic compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB214221A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2513659A (en) * | 1948-11-16 | 1950-07-04 | Ethyl Corp | Recovery of alkyllead |
| US2513654A (en) * | 1948-11-16 | 1950-07-04 | Ethyl Corp | Recovery of alkyllead compounds |
| US2535190A (en) * | 1949-04-01 | 1950-12-26 | Ethyl Corp | Manufacture of alkyllead compounds |
| US2852543A (en) * | 1954-10-14 | 1958-09-16 | Ethyl Corp | Process for the preparation of alkyl tin chlorides |
| US3085102A (en) * | 1959-04-15 | 1963-04-09 | Nippon Catalytic Chem Ind | Process for producing alkyl tin halide compounds |
| DE1169933B (en) * | 1959-04-29 | 1964-05-14 | Ethyl Corp | Process for the production of tetramethyl lead |
-
1924
- 1924-03-22 GB GB7382/24A patent/GB214221A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2513659A (en) * | 1948-11-16 | 1950-07-04 | Ethyl Corp | Recovery of alkyllead |
| US2513654A (en) * | 1948-11-16 | 1950-07-04 | Ethyl Corp | Recovery of alkyllead compounds |
| US2535190A (en) * | 1949-04-01 | 1950-12-26 | Ethyl Corp | Manufacture of alkyllead compounds |
| US2852543A (en) * | 1954-10-14 | 1958-09-16 | Ethyl Corp | Process for the preparation of alkyl tin chlorides |
| US3085102A (en) * | 1959-04-15 | 1963-04-09 | Nippon Catalytic Chem Ind | Process for producing alkyl tin halide compounds |
| DE1169933B (en) * | 1959-04-29 | 1964-05-14 | Ethyl Corp | Process for the production of tetramethyl lead |
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