GB2127866A - Pattern densified fabric comprising conjugate fibers - Google Patents

Pattern densified fabric comprising conjugate fibers Download PDF

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Publication number
GB2127866A
GB2127866A GB08326034A GB8326034A GB2127866A GB 2127866 A GB2127866 A GB 2127866A GB 08326034 A GB08326034 A GB 08326034A GB 8326034 A GB8326034 A GB 8326034A GB 2127866 A GB2127866 A GB 2127866A
Authority
GB
United Kingdom
Prior art keywords
fibers
web
melting point
regions
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08326034A
Other versions
GB2127866B (en
GB8326034D0 (en
Inventor
Charles J Shimalla
Alfred T Mays
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chicopee Inc
Original Assignee
Chicopee Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23706961&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=GB2127866(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Chicopee Inc filed Critical Chicopee Inc
Publication of GB8326034D0 publication Critical patent/GB8326034D0/en
Publication of GB2127866A publication Critical patent/GB2127866A/en
Application granted granted Critical
Publication of GB2127866B publication Critical patent/GB2127866B/en
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/55—Polyesters
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/34—Core-skin structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/544—Olefin series

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Multicomponent Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Artificial Filaments (AREA)
  • Laminated Bodies (AREA)
  • Materials For Medical Uses (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A nonwoven fabric comprising at least 15 percent conjugate fibers having a low melting point component and method of making the same, said fabric comprising high loft regions immediately adjacent densified regions produced by compressing the web at a temperature below the softening point of the low melting point component of the conjugate fiber and at a temperature and pressure sufficient to deform and compact the fibers of the web in only the densified regions.

Description

1 GB 2 127 866 A 1
SPECIFICATION
Pattern densified fabric comprising conjugate 65 fibers Background of the invention
Methods of compression embossing fibrous webs are known in the art. Methods of heat embossing fibrous webs including fibrous webs comprising thermoplastic fibers are also known.
In general, the heat embossing is done by means of heated rollers, with the fibrous web traveling through the nip between the counterrotating heated rollers. To maintain a good through-put speed, the rollers are usually heated a few 75 degrees higher than the melting point of the thermoplastic fibers in the web or the temperature desired in the embossing process.
This is necessary so that the web traveling quickly through the nip achieves the desired temperature. 80 Fabrics which have been heat embossed and in particular fabrics which have been heat embossed in a pattern by patterned rollers often display damage from excessive heat. In particular, in order to achieve heat sufficient to fuse the fibers in 85 the patterned regions, the fibers immediately adjacent the patterned regions are heated to a temperature sufficient to cause shrinkage and damage. The heat radiated to the fibers next adjacent the patterned area also shrinks the web blurring the line of demarkation of the pattern. In the method of the present invention, a combination of heat and pressure is used to compact the fibers in the patterned regions in the web. This combination of factors does not 95 effectively radiate to the fibers next adjacent the pattern region of the fabric, creating a fabric with very sharp pattern delineation and high loft adjacent the pattern region.
It is also old in the art to cold emboss to form or laminate fibrous layers. Cold embossing of moist fibrous layer produces a compacted product which exhibits deformation of fibers and hydrogen bonding. Paper toweling is often made by such a method. The compaction achieved with cold embossing can be undone with water. In the method and fabric of the present invention, the compaction of the fibrous web may not be reversed or undone by the application of water.
Summary of the invention
The present invention comprises a method of pattern embossing a nonwoven web of fibers comprising conjugate fibers and the fabric formed thereby. The method comprises heat embossing the web at a temperature slightly below the softening point of the low melting point component of the conjugate fiber, and with the combination of pressure and temperature sufficient to cause cold flow of at least the low melting point component of the conjugate fibers to deform and compact the conjugate fibers compacting the fibers of the web in only the patterned regions. The fabric formed according to the method has a very sharp pattern delineation 125 and high loft immediately adjacent the pattern.
The web contains at least 15 percent conjugate fibers. In a preferred embodiment, the conjugate fibres are a sheath/core of high density polyethylene/polyester fibers.
Description of the drawing
The Figure is a photomicrograph showing a cross-section of a fabric prepared according to the method of the present invention.' Detailed description of the invention
The present invention comprises a method of embossing a web comprising at least 15 percent conjugate fibers and the fabric formed thereby.
The conjugate fibers comprise a low melting point component and a high melting point component, and preferably comprise a sheath/core polyethylene/polyester fiber.
Preferably, the conjugate fibers employ high density polyethylene, that is, linear polyethylene that has a density of at least about 0.94, and a Melt Index (---M1-) by ASTM DA 238(E) (1 900C., 2160 gms.) of greater than 1, preferably greater than about 10, and more preferably from about to about 50. Usually the fibers will be composed of about 40 to 60 weight percent, and preferably 45 to 55 weight percent, polyester, the remainder being polyethylene.
The fabrics of the invention are produced by first forming a fibrous web comprising a loose array of the conjugate fibers, as by carding, air laying, or the like. The exact weight of the fibrous web has not been found to be narrowly critical, although useful weights have been found within the range from about 0.2 to about 4.2 ounces per square yard. This web is then conveyed to the nip of the embossing rollers.
According to the method of the present invention, a combination of heat and pressure is applied at the embossing nip combined to cause the low melting point component of the conjugate fibers of the web to cold flow. The method of the present invention encompasses using patterned embossed rolls generally known in the art. The pattern embossed rollers have raised patterned surface areas which contact and compress the web as it passes through the nip of a pair of counterrotating pattern emboss rollers. In the conventional heat embossing operation, the rollers are heated to a temperature many degrees above the effective temperature needed at the nip. This is necessary to maintain a good throughput speed of the web. The elevated temperature assures that during the short amount of time that the web spends in the nip, the effective temperature within the web is reached.
In the metod of the present invention, the rollers are heated to a temperature below the softening point of the low melting point component of the conjugate fiber of the web which is to be processed through the nip of the rollers. As the web passes through the nip, the combination of heat and pressure applied by the patterned embossed rollers causing at least the low melting point component of the conjugate 2 GB 2 127 866 A 2 fibers of the web to cold flow and deform and compact the conjugate fibers, compacting the fibers in the web, in only the patterned regions. By using a combination of pressure and temperature, the method of the present invention avoids fiber shrinkage and web damage in the regions 60 immediately adjacent the patterned regions normally caused by the radiation of heat from the super heated rollers used when heat alone is used to fuse the fibers of the web.
The fibrous webs used in practicing the 65 method according to the present invention comprise at least 15 percent conjugate fibers and preferably sheet/core high density polyethylene/polyester conjugate fibers. Examples of other conjugate fibers which may be used in 70 the method of the present invention are copolyester/polyester and nylon 6/nyiori 66 fibers.
Optionally, before passing to the nip, the web may be heated with heated air at a temperature sufficient to fuse the conjugate fibers to each 75 other and to other fibers in the web to strengthen the fabric in the remaining, unpatterned regions.
Figure 1 illustrates a microscopic cross-section of a fabric formed according to the present invention. The fabric shown generally at 10 has embossed densified regions 12 created by the deforming and compacting of the conjugate fiber, compacting all the fibers in the web in only the pattern embossed region. The deformation and compaction of the conjugate fibers are 85 accomplished by a combination of heat and pressure. In the method of the present invention, the heated embossed rollers are heated to a temperature slightly below the softening point of the low melting point component of the conjugate fibers. Sufficient pressure is applied in the patterned area to permanently deform the low melting point component of the conjugate fiber and hence the conjugate fiber. Any other fibers in the patterned regions of the web are compacted and the web is maintained in a densified state by the deformation of the conjugate fibers. The patterned regions display an opacity that is believed due to the air fiber interfaces. One could speculate that the deformation of the conjugate fibers is caused by cold flow of at least the sheath 100 and perhaps the core of the fibers. In the regions 14 immediately adjacent the densified patterned regions, the fabric shows a very high loft and individual fibers 16 are seen. The high loft delineates the pattern of the fabric and indicates a 105 lack of fiber damage in the regions immediately adjacent the patterned regions.

Claims (8)

Claims
1. A nonwoven fabric having high loft regions immediately adjacent densified patterned regions, said fabric comprising at least 15 percent conjugate fibers having a polyethylene component and another component of a higher melting point, and said densified patterned regions comprising deformed and compacted conjugate fibers, compacting the fibers in only the patterned regions.
2. A fabric as in Claim 1 wherein said conjugate fiber forms about 75 percent of the fibers of said web.
3. A method of making a nonwoven fabric having high loft regions immediately adjacent densified patterned regions from a web comprising at least 15 percent conjugate fibers having a low melting point component and high melting point component, said method comprising compressing said web at a temperature below the softening point of the low melting point component, and at a combination of temperature and pressure to deform and compact the conjugate fibers and compact the fibers of the web in only the patterned regions.
4. A method of making a nonwoven fabric having high loft regions immediately adjacent densified patterned regions from a web comprising at least 15 percent conjugate fibers having a low melting point component and high melting point component, said method comprising heating said web with heated air at a temperature sufficient to fuse the conjugate fibers to each other and to other fibers in the web, and subsequently compressing said web at a temperature below the softening point of the low melting point component, and at a combination of temperature and pressure to deform and compact the conjugate fibers and compact the fibers of the web in only the patterned regions.
5. A method as claimed in claim 3 or 4 wherein said low melting point component is a polyethylene component.
6. A fabric as in claim 1 wherein said conjugate fiber forms 70 to 80 percent of the fibers of said web.
7. A fabric made by a method as claimed in claim 3, 4 or 5.
8. A fabric as in claim 1, 2, 6 or 7 having densified regions and high loft regions substantially as indicated in and with reference to the accompanying drawings.
Printed for Her Majesty's Stationery Office by the Courier Press, Leamington Spa, 1984. Published by the Patent Office. 25 Southampton Buildings, London. WC2A 'I AY, from which copies maybe obtained.
GB08326034A 1982-09-30 1983-09-29 Pattern densified fabric comprising conjugate fibers Expired GB2127866B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US43030782A 1982-09-30 1982-09-30

Publications (3)

Publication Number Publication Date
GB8326034D0 GB8326034D0 (en) 1983-11-02
GB2127866A true GB2127866A (en) 1984-04-18
GB2127866B GB2127866B (en) 1986-06-11

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ID=23706961

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08326034A Expired GB2127866B (en) 1982-09-30 1983-09-29 Pattern densified fabric comprising conjugate fibers

Country Status (23)

Country Link
EP (1) EP0105729B1 (en)
JP (1) JPS59130354A (en)
KR (1) KR930010809B1 (en)
AT (1) ATE43655T1 (en)
AU (1) AU565659B2 (en)
BR (1) BR8305377A (en)
CA (1) CA1250412A (en)
DE (1) DE3379965D1 (en)
DK (1) DK449583A (en)
ES (1) ES8504289A1 (en)
FI (1) FI833520A (en)
GB (1) GB2127866B (en)
GR (1) GR79362B (en)
HK (1) HK98686A (en)
IE (1) IE54580B1 (en)
IN (1) IN162943B (en)
MX (1) MX158330A (en)
MY (1) MY8700092A (en)
NO (1) NO833546L (en)
NZ (1) NZ205684A (en)
PH (1) PH19570A (en)
PT (1) PT77418B (en)
ZA (1) ZA837301B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0401538A2 (en) * 1989-06-07 1990-12-12 Chisso Corporation Cellulose-based, inflammable, bulky processed sheets and method for making such sheets
EP0455990A1 (en) * 1990-04-09 1991-11-13 Hoechst Aktiengesellschaft Thermally stable, melting-binder-strengthened nonwoven web and method for making the same
EP0465203A1 (en) * 1990-07-02 1992-01-08 Hoechst Celanese Corporation Improved wet laid bonded fibrous web containing bicomponent fibers including LLDPE
WO1998049395A1 (en) * 1997-04-25 1998-11-05 Kimberly-Clark Worldwide, Inc. Scrim-like paper wiping product and method for making the same

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2538602B2 (en) * 1987-08-03 1996-09-25 旭化成工業株式会社 Fiber for spunbond nonwovens
JPH01227385A (en) * 1988-03-07 1989-09-11 Takashi Seike Exothermic sheet and its manufacture
US4915763A (en) * 1988-08-24 1990-04-10 Hunter Douglas Inc. Non-woven fabric, opaque and non-opaque, with and without weave-like finish and process for producing these
JP2581994B2 (en) * 1990-07-02 1997-02-19 チッソ株式会社 High precision cartridge filter and method of manufacturing the same
US5382400A (en) 1992-08-21 1995-01-17 Kimberly-Clark Corporation Nonwoven multicomponent polymeric fabric and method for making same
US5405682A (en) 1992-08-26 1995-04-11 Kimberly Clark Corporation Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material
CA2092604A1 (en) 1992-11-12 1994-05-13 Richard Swee-Chye Yeo Hydrophilic, multicomponent polymeric strands and nonwoven fabrics made therewith
US5482772A (en) 1992-12-28 1996-01-09 Kimberly-Clark Corporation Polymeric strands including a propylene polymer composition and nonwoven fabric and articles made therewith
US5424115A (en) * 1994-02-25 1995-06-13 Kimberly-Clark Corporation Point bonded nonwoven fabrics
US5545464A (en) * 1995-03-22 1996-08-13 Kimberly-Clark Corporation Conjugate fiber nonwoven fabric
US5858515A (en) * 1995-12-29 1999-01-12 Kimberly-Clark Worldwide, Inc. Pattern-unbonded nonwoven web and process for making the same
US5931823A (en) * 1997-03-31 1999-08-03 Kimberly-Clark Worldwide, Inc. High permeability liner with improved intake and distribution
CN113512820B (en) * 2021-05-19 2023-03-17 杭州科百特科技有限公司 Coarse fiber melt-blown fabric, preparation method thereof and coarse fiber melt-blown fabric filter element

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1245088A (en) * 1967-11-10 1971-09-02 Ici Ltd Improvements in or relating to the bonding of structures
GB1581486A (en) * 1977-10-20 1980-12-17 Kimberly Clark Co Non-woven fabric and method of producing same
GB2061339A (en) * 1979-10-22 1981-05-13 Kimberly Clark Co Autogeneously Bonded Absorbent Pad

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56140153A (en) * 1980-04-01 1981-11-02 Asahi Chemical Ind Strong and flexible nonwoven fabric
US4315965A (en) * 1980-06-20 1982-02-16 Scott Paper Company Method of making nonwoven fabric and product made thereby having both stick bonds and molten bonds
JPS5813761A (en) * 1981-07-17 1983-01-26 チッソ株式会社 Production of nonwoven fabric
JPS58169560A (en) * 1982-03-26 1983-10-06 日本バイリーン株式会社 Production of nonwoven fabric

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1245088A (en) * 1967-11-10 1971-09-02 Ici Ltd Improvements in or relating to the bonding of structures
GB1581486A (en) * 1977-10-20 1980-12-17 Kimberly Clark Co Non-woven fabric and method of producing same
GB2061339A (en) * 1979-10-22 1981-05-13 Kimberly Clark Co Autogeneously Bonded Absorbent Pad

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0401538A2 (en) * 1989-06-07 1990-12-12 Chisso Corporation Cellulose-based, inflammable, bulky processed sheets and method for making such sheets
EP0401538A3 (en) * 1989-06-07 1991-04-03 Chisso Corporation Cellulose-based, inflammable, bulky processed sheets and method for making such sheets
EP0599812A2 (en) * 1989-06-07 1994-06-01 Chisso Corporation Cellulose-based, inflammable, bulky processed sheets and method for making such sheets
EP0599812A3 (en) * 1989-06-07 1994-12-07 Chisso Corp Cellulose-based, inflammable, bulky processed sheets and method for making such sheets.
EP0455990A1 (en) * 1990-04-09 1991-11-13 Hoechst Aktiengesellschaft Thermally stable, melting-binder-strengthened nonwoven web and method for making the same
EP0465203A1 (en) * 1990-07-02 1992-01-08 Hoechst Celanese Corporation Improved wet laid bonded fibrous web containing bicomponent fibers including LLDPE
US5167765A (en) * 1990-07-02 1992-12-01 Hoechst Celanese Corporation Wet laid bonded fibrous web containing bicomponent fibers including lldpe
WO1998049395A1 (en) * 1997-04-25 1998-11-05 Kimberly-Clark Worldwide, Inc. Scrim-like paper wiping product and method for making the same
US5989682A (en) * 1997-04-25 1999-11-23 Kimberly-Clark Worldwide, Inc. Scrim-like paper wiping product and method for making the same

Also Published As

Publication number Publication date
NZ205684A (en) 1987-02-20
DK449583D0 (en) 1983-09-29
ES526134A0 (en) 1985-04-16
BR8305377A (en) 1984-05-08
DE3379965D1 (en) 1989-07-06
DK449583A (en) 1984-03-31
GR79362B (en) 1984-10-22
KR930010809B1 (en) 1993-11-11
EP0105729A2 (en) 1984-04-18
EP0105729B1 (en) 1989-05-31
IE832315L (en) 1984-03-30
FI833520A (en) 1984-03-31
HK98686A (en) 1986-12-24
GB2127866B (en) 1986-06-11
ATE43655T1 (en) 1989-06-15
AU1975783A (en) 1984-04-05
ES8504289A1 (en) 1985-04-16
AU565659B2 (en) 1987-09-24
FI833520A0 (en) 1983-09-29
GB8326034D0 (en) 1983-11-02
ZA837301B (en) 1985-05-29
MX158330A (en) 1989-01-25
PH19570A (en) 1986-05-21
JPH0545708B2 (en) 1993-07-09
PT77418B (en) 1986-03-20
KR840006025A (en) 1984-11-21
MY8700092A (en) 1987-12-31
IN162943B (en) 1988-07-23
EP0105729A3 (en) 1986-02-19
CA1250412A (en) 1989-02-28
PT77418A (en) 1983-10-01
IE54580B1 (en) 1989-11-22
NO833546L (en) 1984-04-02
JPS59130354A (en) 1984-07-26

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