GB2119490A - Improvements in or relating to furnaces for combination metal reduction and distillation - Google Patents
Improvements in or relating to furnaces for combination metal reduction and distillation Download PDFInfo
- Publication number
- GB2119490A GB2119490A GB08310975A GB8310975A GB2119490A GB 2119490 A GB2119490 A GB 2119490A GB 08310975 A GB08310975 A GB 08310975A GB 8310975 A GB8310975 A GB 8310975A GB 2119490 A GB2119490 A GB 2119490A
- Authority
- GB
- United Kingdom
- Prior art keywords
- furnace
- metal
- reducing
- compartment
- vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B19/00—Combinations of furnaces of kinds not covered by a single preceding main group
- F27B19/04—Combinations of furnaces of kinds not covered by a single preceding main group arranged for associated working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1268—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams
- C22B34/1272—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams reduction of titanium halides, e.g. Kroll process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/14—Obtaining zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/04—Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A combination reduction, distillation, reducing metal recovery furnace and process of using the same comprising a pair of vertically displaced vessels in fluid communication wherein the upper vessel contains a perforated inner liner and means to at least periodically charge the top of the vessel with a metal salt to be reduced and a reducing metal, and wherein the lower vessel has a means to periodically withdraw the molten reducing metal salt produced by the redox reaction occuring within the furnace. By initially charging the furnace with sufficient reducing metal salt to establish a liquid level above the perforations and by maintaining this level during the redox reaction, the inner liner can be filled with solid phase reduced metal produced by the reaction. Upon completion, the molten reducing salt is drained from the furnace, the lower vessel is cooled and the unreacted reducing metal is distilled from the furnace under vacuum. Such a process and apparatus is useful in producing large quantities of high purity metals such as Zr, Ti, Hf and the like. <IMAGE>
Description
SPECIFICATION Improvements in or relating to furnaces for combination metal reduction and distillation
This invention relates to reduction, distillation furnaces for the recovery of a reduced purified metal and any unused reducing metal as well as to a process for reducing a metal salt in such a furnace.
Technical and patent literature reports numerous methods for separating and recovering various metals. Frequently the processes will involve the isolation of a purified salt of the metal to be recovered and a subsequent chemical reduction involving the addition of at least a stoichiometric amount of a more active reducing metal. The reduction step will then be followed by an appropriate separation of the desired elemental form of the metal from any excess reducing metal and reducing metal salt formed during the displacement reaction. In contemporary commercial scale production (i.e., production involving tonnage quantities of free metal) and in particular in the recovery of such metals as titanium, zirconium, hafnium, and the like, the overall reduction and recovery process is a batchwise series of high temperature and high vacuum steps.
Thus, for example, in the production of zirconium intended for use as a structural materiai in nuclear reactor applications, a hafnium-free, highly purified zirconim halide (e.g. ZrCI4) is loaded into a vessel or retort. Typically, this reduction retort is a cylindrical soft iron vessel having a centrally located cylindrical (angel-food cake pan) inner wall with the ZrCI4 loaded into the doughnut shaped annular cavity. After isolation of the ZrCI4 in this annular cavity and cooling of the retort, it is placed on top of a crucible filled with at least a stoichiqmetric amount of a reducing metal (e.g.
magnesium, sodium or the like). A lid is sealed on top of the retort and the crucible is welded to the retort thus creating a hermetically sealed retort assembly. This retort assembly is then evacuated to create the desired oxygen-nitrogen free inert atmosphere and placed in a reduction furnace wherein the retort assembly is heated to a temperature of the order of approximately 8250C for a sustained period of time. Under these conditions the ZrCI4 will evaporate and diffuse into the lower crucible containing the magnesium reducing metal and therein react, producing elemental zirconium and magnesium chloride.
Upon completion of the reduction reaction, the retort assembly is cooled and the crucible and retort are milled apart. The retort is then cleaned and returned to the ZrCI4 charging step. The crucible containing the reaction products is sent to an area where the products are removed and most of the MgCI2 layer is physically separated from the sponge zirconium layer. A series of zirconium sponge layers is collected from several crucibles (reduction batch runs) and stacked within the upper portion of a distillation vessel, typically on a support grid separating the upper and lower compartments. This distillation vessel is then hermetically sealed and under vacuum (20 microns) the upper compartment is maintained at a high temperature (approximately 1 0500C) for a period sufficient to melt and distill the MgCI2 and any unreacted magnesium.After cooling and conditioning the distillation vessel, the magnesium chloride and magnesium in the lower compartment is removed and the desired zirconium sponge disc is withdrawn from the support grid and sent on to final product handling and fabrication.
There.are several shortcomings associated with such a process. First it is labor intensive in materials handling and requires two full heat-ups from room temperature. Also, the process is long and time consuming. The in to out process time cycle on a commercial scale is approximately 1 6 to 20 days in length.
Accordingly, the present invention resides in a reduction, distillation furnace which comprises a reaction vessel having a predetermined amount of molten reducing metal salt therein to provide a molten salt surface; a means to introduce a reducing metal into said reaction vessel; a means to introduce a metal salt to be chemically reduced into said reaction vessel; a means to withdraw liquid from the lower portion of the reaction vessel such as to selectively control said molten salt surface within said reaction vessel; a means to initially create a vacuum within said furnace; and a means to heat said furnace to a temperature consistent with the occurrence of the desired reduction reaction and also to a temperature consistent with the occurrence of the desired distillation reaction.
In one particular embodiment of the invention, the furnace is provided with first and second compartments or vessels in fluid communication with each other. The first compartment contains an inner liner with at least one opening in the lower portion of the liner for allowing fluid transfer therethrough and the inner liner is adapted to confine solidified elemental metal produced within the first compartment by the chemical reducing reaction occurring therein. Preferably, in such an embodiment, a means is provided to selectively maintain the compartments at different temperatures while drawing a vacuum on the furnace.
The present invention further preferably provides that the first compartment is an upper compartment and the second compartment is a lower compartment and the compartments are separate vessels interconnected by a conduit and that the upper compartment can be opened in a manner such as to facilitate removal of an inner liner containing the reduced metal. The invention can also provide a pan suspended within the upper chamber and above the reducing metal layer to vaporize the metal salt to be reduced. A removable external heater around the lower compartment can be provided to selectively maintain the lower compartment temperature below the temperature of the upper compartment during distillation of unreacted reducing metal.
The invention also includes a process for reducing a metal salt in a reduction, distillation furnace by reaction with a reducing metal to produce by way of a redox reaction, a desired solid reduced metal phase and a corresponding molten reducing metal metal salt, which comprises initially charging a furnace with sufficient reducing metal salt to establish a molten salt surface in said furnace; establishing and maintaining a temperature and pressure within said furnace consistent with promoting said desired redox reaction; at least periodically adding said metal salt to be reduced and at least a stoichiometric amount of reducing metal to said furnace; at least periodically removing a portion of said molten metal-reducing salt to readjust said molten salt surface whereby the amount of said solid reduced metal phase that can be formed by the redox reaction is increased; upon completion of said redox reaction, removing said molten metalreducing salt phase from said furnace; removing any unreacted reducing metal from said furnace by distillation thus isolating purified solid reduced metal; and recovering said purified solid reduced metal from said furnace.
In the preferred embodiment separate first and second compartments or vessels are used with the inner liner being present in the first. After the reduction phase is completed most of the molten metal-reducing salt and unreacted reducing metal is removed by draining the liquid phase. The remaining metal-reducing salt and unreacted reducing metal is removed by maintaining the first vessel at a temperature above the temperature of the second vessel while pulling a vacuum on the furnace. The purified reduced metal is recovered by opening the upper vessel and withdrawing the inner liner.
In order that the invention can be more clearly understood, convenient embodiments thereof will now be described, by way of example, with reference to the accompanying drawing which is a simplified partial cross-sectional view of a combination reduction, distillation, reducing metal
recovery furnace.
Referring to the drawing, an upper vessel or
compartment 10 of the furnace is an enclosed,
sealed reaction vessel having a removable top
portion 1 6 that separates from the remainder of
the vessel along the shelf 1 8. This removable top
or lid 1 6 is constructed of an inner surface 20 of
sheet steel with an air space 22 behind it. The
inner wall 24 is another layer of sheet steel
backed by a layer of insulation 26 which in turn is
covered with an external layer of sheet steel 28.
Within the air gap 22 and attached to the inner
wall 24 is a series of electrical heating elements
30. The sidewalls 32 of the upper vessel 10 below
the shelf 18, the conduit 34 connecting the upper
vessel 10 with the lower vessel 12, and the lower
vessel 12 are constructed of essentially the same
sequence of layers. While the air gap in the lid 16
and the lower vessel 1 2 are essentially static, the
sidewalls 32 of upper compartment 10 are equipped with ports 36, 38 and 40 and with spiral cooling fins 42 to facilitate air movement and cooling when required. The upper portion of the sidewalls 32 are also provided with an expansion joint 44 to account for dimensional changes associated with the heat-up and cool-down cycles of the furnace operation.
The removable top or lid 1 6 is also provided with an evacuation port 46 through which a vacuum can be pulled on the top of the furnace, a pair of inlet conduits 48 and 50 leading to a suspended vaporization pan 52 for introducing into the furnace volatile metal salt to be reduced, and a centrally located inlet conduit 54 for introducing a reducing metal and reducing metal salt into the furnace below the vaporization pan 52. When removable lid 1 6 with attached vaporization pan 52 is removed, the inner liner 56 resting on the inner portion of shelf 1 8 can be withdrawn from the upper chamber 1 0. This inner liner 56 is equipped with at least one perforation in its sides and/or bottom 58 that allows for fluid transfer from within the inner liner to a lower compartment or vessel 12 via conduit 34.
This lower vessel 1 2 is also a sealed furnace with preferably the heating elements and insulation being of a clamshell or removable nature. The lower portion of the vessel 12 is equipped with a valved spigot 60 for draining liquid from the furnace into the reduced metal salt receptacle 62. The vessel 1 2 is also equipped with an evacuation port 64 for distillation of any unreacted reducing metal after the radox reaction is finished and the molten reducing metal salt has been drained from vessel 12.
In order to operate the furnace according to the present invention, the unit is either initially charged with a desired amount of the reducing metal salt and then sealed, or the unit is sealed and tested for leaks and then charged with the reducing metal salt through appropriate valving (not shown) and conduit 54. The furnace can then be brought up to the desired operating temperature and a vacuum created within the furnace via evacuation line 46 and appropriate external valving and vacuum pump (again not shown).The appropriate or desired amount of reducing metal salt corresponds to the quantity of salt required to establish a liquid phase interface of molten reducing metal salt (molten salt surface) above the perforations in the inner liner bottom 58; i.e., the amount of molten salt required to fill the lower vessel 12, the conduit 34, and the lower portion of upper vessel 1 0. The molten salt surface can then be adjusted upward by adding additional salt through conduit 54 and adjusted downward by draining liquid from the lower vessel 12 via spigot 60. Also in this manner, the liquid level of the molten reducing metal salt can be maintained above the perforated bottom 58 which is viewed as an essential and novel process step of the invention.
Having achieved the desired liquid level within the upper vessel 10 and the appropriate temperature and vacuum, the reactants to the redox reaction can be introduced. The reducing metal is added to the inner liner via inlet conduit 54 thus establishing a molten reducing metal layer on top of the salt layer. The metal salt to be reduced, usually a metal halide, is added to the vaporization pan 52 via inlet conduits 48 and 50.
At the selected conditions the metal halide in the vaporization pan distills (evaporates) and diffuses into the region directly above the molten reducing metal where it reacts with the reducing metal according to the redox reaction producing more reducing metal salt and the desired reduced metal to be recovered. The molten metal salt produced by the reaction physically settles to the bottom while the reduced metal phase continues to grow to what is ultimately a sponge-like solid phase confined to the interior of the inner liner 56. As excess reducing metal salt phase is produced by the redox reaction, spigot 60 is opened and additional space in the furnace then becomes available for more metal production.The process of at least periodically (possibly continuously) adding reducing metal and metal halide reactants and the periodic removal of reducing metal salt continues until the entire available space within the inner liner is filled with the desired metal sponge phase. At this point the addition of metal halide reactant and the reducing metal stops and the redox reaction ceases. Preferably this should occur with at least a stoichiometric amount of reducing metal having been added such that the metal salt being reduced is for all practical purposes the limiting chemical factor. This is important in that the excess unreacted reducing metal can usually be removed from the reduced metal more easily than the reverse.
Having completed the run, the liquid reacting metal salt phase is then withdrawn through spigot 60 while (optionally) an inert gas is being added to the top of the furnace via conduit 54 or other inlet conduit. Upon visual confirmation of excess liquid reducing metal exiting spigot 60, the spigot is closed. The lower vessel is cooled and then evacuated by using the appropriate vaives and vacuum (not shown) via port 64. During this step the heating elements on the lower vessel 12 are preferably removed to allow the temperature of the lower chamber to drop below the temperature of the upper chamber which is simultaneously
maintained at a temperature that promotes the distillation of any reducing metal entrained in the
reduced metal product.This step is continued until no additional reducing metal can be distilled from the furnace whereupon the furnace is filled with
an inert gas and the heater is turned off. Cooling
air can then be circulated through ports 36, 38
and 40 of upper vessel 10 to cool the entire
furnace and contents back to ambient conditions.
There are several advantages associated with
the present furnace and its use. Primarily the
improved furnace performs both the reduction
step and distillation step in a single reactor with
only one heat-up and cool-down cycle.
Consequently there is a significant savings in
labor, energy expenditure, and operating supplies.
Furthermore the in-process inventory is significantly reduced and the maintenance costs are anticipated to be much lower. The reducing metal efficiency is also expected to be very high (in excess of 95% for Mg).
The particular metal to be recovered in the furnace described herein, in the broadest sense, can be any metal that in the elemental form remains in the solid state at the redox conditions being employed, and also provided that the reducing metal salt being formed is a liquid at these conditions. Preferably the metal salt to be reduced is volatile at the furnace operating conditions. Therefore, such compounds as zirconium chloride, titanium chloride, and hafnium chloride are particularly useful in the present invention.However, other halides of these metals and generally other metal halides such as metal chlorides, bromides, iodides or fluorides which react with reducing metals (particularly alkali or alkaline earth metals such as sodium, potassium, lithium, magnesium, calcium and the like) to produce the elementalform of the metal are to be considered equivalent for purposes of this invention. In such cases an alternative to the vaporization pan to distribute the reactant can readily be employed in the top of the furnace. Any appropriate means well known in the art to accomplish the task, in principle, can be employed; for example, spray nozzles, sprinkler pipes, powder distributions and the like.
The overall shape and configuration of the vessels making up the furnace is somewhat arbitrary provided the basic concept of establishing and readjusting the molten salt surface during operation or its equivalent is present. Thus the furnace can be a single vessel with the perforated inner liner or the equivalent (such as perforated partitions, weirs, baffles or the like for establishing the first and second compartments, or the unit can be two separate vessels. The separate vessels in fluid communication can be side by side or vertically displaced (as illustrated) with the position of molten salt removal being appropriately selected.
Various well known engineering and design principles can be readily employed such as heat tracing of various pipes, valves and other equipment. Portholes and manways can be provided for access for repair, or for rodding out the condensed solid deposit from pipes and the like. Recirculation of molten reducing metal salt for liquid level maintenance can be incorporated.
And various measurements can be employed during operation to monitor the progress of the redox reaction including weight of reactants, weight of reducing salt withdrawn, liquid level detection and the like.
Claims (14)
1. A reduction, distillation furnace which comprises a reaction vessel having a predetermined amount of molten reducing metal salt therein to provide a molten salt surface; a means to introduce a reducing metal into said reaction vessel; a means to introducing a metal salt to be chemically reduced into said reaction vessel; a means to withdraw liquid from the lower portion of the reaction vessel such as to selectively control said molten salt surface within said reaction vessel; a means to initially create a vacuum within said furnace; and a means to heat said furnace to a temperature consistent with the occurrence of the desired reduction reaction and also to a temperature consistent with the occurrence of the desired distillation reaction.
2. A furnace according to claim 1, wherein the reaction vessel further comprises a first compartment containing an inner liner, said inner liner having at least one opening in the lower portion thereof for allowing fluid transfer therethrough, and said inner liner adapted to confine solidifed elemental metal produced within said first compartment by a chemical reducing reaction occurring therein; and a second compartment in fluid communication with said first compartment.
3. A furnace according to claim 2, wherein said furnace further comprises a means to selectively maintain said second compartment at a lower temperature than said first compartment; and a means to draw a vacuum on said furnace when said second compartment is being maintained at a temperature below said first compartment temperature.
4. A furnace according to claim 2 or 3, wherein the first compartment is an upper compartment and the second compartment is a lower compartment and said compartments are separate vessels in communication with each other through an interconnecting conduit.
5. A furnace according to claim 4, wherein the upper compartment is adapted to be separable such as to facilitate the removal of the inner liner containing reduced metal.
6. A furnace according to claim 5, wherein the means to introduce a metal salt to be reduced is at least one conduit through the top of the upper compartment leading to at least one vaporizing pan suspended within the upper chamber and above the reducing metal layer.
7. A furnace of claim 4, 5 or 6, wherein the lower compartment contains a removable external heater as the means to selectively maintain said lower compartment temperature.
8. A process for reducing a metal salt in a reduction, distillation furnace by reaction with a reducing metal to produce by way of a redox reduction, a desired solid reduced metal phase and a corresponding molten reducing metal salt, which comprises initially charging a furnace with sufficient reducing metal salt to establish a molten salt surface in said furnace; establishing and maintaining a temperature and pressure within said furnace consistent with promoting said desired redox reaction; at least periodically adding said metal salt to be reduced and at least a stoichiometric amount of reducing metal to said furnace; at least periodically removing a portion of said molten metal-reducing salt to readjust said molten salt surface whereby the amount of said solid reduced metal phase that can be formed by the redox reaction is increased; upon completion of said redox reaction, removing said molten metal-reducing salt phase from said furnace; removing any unreacted reducing metal from said furnace by distillation thus isolating purified solid reduced metal; and recovering said purified solid reduced metal from said furnace.
9. A process according to claim 8, wherein the furnace comprises a first vessel containing an inner liner having at least one opening in a lower portion thereof, said first vessel being in fluid communication with a second vessel of said furnace.
10. A process according to claim 9, wherein the molten metal-reducing salt phase is removed by draining the liquid phase from the first vessel.
11. A process according to claim 9 or 10, wherein any unreacted reducing metal is removed by maintaining the first vessel of the furnace at a temperature above the temperature of the second vessel while pulling a vacuum on said furnace.
12. A process according to claim 9, 10 or 11, wherein the purified solid reduced metal is removed by opening the first vessel and withdrawing the inner liner containing said metal.
13. A process according to claim 12, wherein the metal is Ti, Zr or Hf.
14. A process of claim 12, wherein the metal salt to be reduced is ZrCI4, the reducing metal salt is MgCI2 and the reducing metal is Mg.
1 5. Reduction, distillation furnaces as claimed in claim 1 and substantially as described herein with particular reference to the accompanying drawing.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37358882A | 1982-04-30 | 1982-04-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB8310975D0 GB8310975D0 (en) | 1983-05-25 |
GB2119490A true GB2119490A (en) | 1983-11-16 |
Family
ID=23473040
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08310975A Withdrawn GB2119490A (en) | 1982-04-30 | 1983-04-22 | Improvements in or relating to furnaces for combination metal reduction and distillation |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS58217647A (en) |
DE (1) | DE3315527A1 (en) |
FR (1) | FR2526140A1 (en) |
GB (1) | GB2119490A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2554129A1 (en) * | 1983-10-27 | 1985-05-03 | Westinghouse Electric Corp | Process for recovering purified reduced metal by redox reaction |
WO2005085485A1 (en) * | 2004-03-10 | 2005-09-15 | Joint-Stock Company 'avisma Titanium-Magnesium Works' (Jsc 'avisma') | Device for magnesium-thermal titanium sponge production |
EP2510297A1 (en) * | 2009-12-10 | 2012-10-17 | Novelis, Inc. | Molten metal containment structure having flow through ventilation |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0270029A (en) * | 1988-09-02 | 1990-03-08 | Nippon Mining Co Ltd | Manufacture of ta or nb and its manufacturing apparatus |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB638840A (en) * | 1948-07-08 | 1950-06-14 | British Aluminium Co Ltd | Improvements in the manufacture of metallic titanium |
GB678286A (en) * | 1948-06-30 | 1952-09-03 | Battelle Memorial Institute | Production of refractory metals |
GB749608A (en) * | 1952-07-23 | 1956-05-30 | Nat Lead Co | Improvements in or relating to apparatus for the production of refractory metals |
GB758763A (en) * | 1953-04-16 | 1956-10-10 | Nat Lead Co | Process and apparatus for the production of a refactory metal |
GB768124A (en) * | 1953-06-13 | 1957-02-13 | Peter Spence & Sons Ltd | Improved method and apparatus for obtaining ductile titanium or zirconium |
GB788525A (en) * | 1955-05-20 | 1958-01-02 | Ferdinand Leferrer | Improvements in or relating to the recovery of zinc from the zinc crust obtained in the separation of silver from lead |
GB790868A (en) * | 1954-08-12 | 1958-02-19 | Montedison Spa | Method and apparatus for the production of titanium or like metal sponge |
GB799195A (en) * | 1955-06-23 | 1958-08-06 | Knapsack Ag | Process and apparatus for the continuous production of easily vapourizable metals |
GB820783A (en) * | 1954-10-16 | 1959-09-23 | Ishizuka Hiroshi | Apparatus for the manufacture of metallic titanium |
GB831315A (en) * | 1956-12-18 | 1960-03-30 | Hoerder Huettenunion Ag | Improvements relating to vacuum furnaces |
GB1187367A (en) * | 1968-02-28 | 1970-04-08 | Halomet Ag | Process of Obtaining Metals from Metal Halides |
GB1321374A (en) * | 1971-03-01 | 1973-06-27 | Vni Pi Aljuminievoi Magnievoi | Apparatus for metal production |
-
1983
- 1983-04-22 GB GB08310975A patent/GB2119490A/en not_active Withdrawn
- 1983-04-28 JP JP7606683A patent/JPS58217647A/en active Pending
- 1983-04-28 FR FR8307072A patent/FR2526140A1/en not_active Withdrawn
- 1983-04-29 DE DE19833315527 patent/DE3315527A1/en not_active Withdrawn
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB678286A (en) * | 1948-06-30 | 1952-09-03 | Battelle Memorial Institute | Production of refractory metals |
GB638840A (en) * | 1948-07-08 | 1950-06-14 | British Aluminium Co Ltd | Improvements in the manufacture of metallic titanium |
GB749608A (en) * | 1952-07-23 | 1956-05-30 | Nat Lead Co | Improvements in or relating to apparatus for the production of refractory metals |
GB758763A (en) * | 1953-04-16 | 1956-10-10 | Nat Lead Co | Process and apparatus for the production of a refactory metal |
GB768124A (en) * | 1953-06-13 | 1957-02-13 | Peter Spence & Sons Ltd | Improved method and apparatus for obtaining ductile titanium or zirconium |
GB790868A (en) * | 1954-08-12 | 1958-02-19 | Montedison Spa | Method and apparatus for the production of titanium or like metal sponge |
GB820783A (en) * | 1954-10-16 | 1959-09-23 | Ishizuka Hiroshi | Apparatus for the manufacture of metallic titanium |
GB788525A (en) * | 1955-05-20 | 1958-01-02 | Ferdinand Leferrer | Improvements in or relating to the recovery of zinc from the zinc crust obtained in the separation of silver from lead |
GB799195A (en) * | 1955-06-23 | 1958-08-06 | Knapsack Ag | Process and apparatus for the continuous production of easily vapourizable metals |
GB831315A (en) * | 1956-12-18 | 1960-03-30 | Hoerder Huettenunion Ag | Improvements relating to vacuum furnaces |
GB1187367A (en) * | 1968-02-28 | 1970-04-08 | Halomet Ag | Process of Obtaining Metals from Metal Halides |
GB1321374A (en) * | 1971-03-01 | 1973-06-27 | Vni Pi Aljuminievoi Magnievoi | Apparatus for metal production |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2554129A1 (en) * | 1983-10-27 | 1985-05-03 | Westinghouse Electric Corp | Process for recovering purified reduced metal by redox reaction |
WO2005085485A1 (en) * | 2004-03-10 | 2005-09-15 | Joint-Stock Company 'avisma Titanium-Magnesium Works' (Jsc 'avisma') | Device for magnesium-thermal titanium sponge production |
EP2510297A1 (en) * | 2009-12-10 | 2012-10-17 | Novelis, Inc. | Molten metal containment structure having flow through ventilation |
CN102812319A (en) * | 2009-12-10 | 2012-12-05 | 诺维尔里斯公司 | Molten Metal Containment Structure Having Flow Through Ventilation |
EP2510297A4 (en) * | 2009-12-10 | 2014-01-08 | Novelis Inc | Molten metal containment structure having flow through ventilation |
US8883070B2 (en) | 2009-12-10 | 2014-11-11 | Novelis Inc. | Molten metal containment structure having flow through ventilation |
Also Published As
Publication number | Publication date |
---|---|
FR2526140A1 (en) | 1983-11-04 |
DE3315527A1 (en) | 1983-11-03 |
JPS58217647A (en) | 1983-12-17 |
GB8310975D0 (en) | 1983-05-25 |
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