GB2061616A - Pyroelectric detector - Google Patents

Pyroelectric detector Download PDF

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Publication number
GB2061616A
GB2061616A GB8030792A GB8030792A GB2061616A GB 2061616 A GB2061616 A GB 2061616A GB 8030792 A GB8030792 A GB 8030792A GB 8030792 A GB8030792 A GB 8030792A GB 2061616 A GB2061616 A GB 2061616A
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GB
United Kingdom
Prior art keywords
pyroelectric
substrate
face
holes
wafer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8030792A
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GB2061616B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP54122947A external-priority patent/JPS6037413B2/en
Priority claimed from JP3804380A external-priority patent/JPS56133632A/en
Priority claimed from JP3803580A external-priority patent/JPS56133631A/en
Application filed by Tokyo Shibaura Electric Co Ltd filed Critical Tokyo Shibaura Electric Co Ltd
Publication of GB2061616A publication Critical patent/GB2061616A/en
Application granted granted Critical
Publication of GB2061616B publication Critical patent/GB2061616B/en
Expired legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • G01J5/34Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using capacitors, e.g. pyroelectric capacitors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N15/00Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
    • H10N15/10Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point

Abstract

A pyroelectric detector comprises a body of pyroelectric material (11), an electrode (12) for receiving infrared rays on one face of the pyroelectric material, a shield electrode (13) at the other face of the pyroelectric material, a substrate (15) made of a semiconductor or conductive material which is fastened to the shield electrode (13), the substrate having a hole (16) corresponding in position to the position of the infrared receiving electrode, and a support (18) to which the substrate is fastened. The method of manufacturing the pyroelectric detector comprises the steps of forming a shield electrode (13) at one face of a pyroelectric wafer (31), making holes (16) in a substrate (15), fastening the substrate to the shield electrode, grinding the other face of the wafer, forming electrodes (12) on the other face of the wafer for receiving infrared rays, the position of the electrodes corresponding to the position of the holes, and dicing the pyroelectric material between the holes to form a single pyroelectric detector. <IMAGE>

Description

SPECIFICATION Pyroelectric detector and method for manufacturing same This invention relates to a device for detecting infrared rays utilizing the pyroelectric effect and methods for manufacturing the same.
Generally, pyroelectric materials are used in pyroelectric detectors for detecting infrared rays by utilizing the pyroelectric effect. However, if the heat capacity of the pyroelectric material is great, the pyroelectric material cannot respond to a fast change in the energy of infrared rays. Therefore, various techniques are used in the prior art to reduce the heat capacity of pyroelectric materials. For example, by reducing the thickness of the pyroelectric material to about 30-50 lim, heat capacity is reduced.
In the prior art, heat capacity also is reduced by exposing the pyroelectric material to air and mounting the pyroelectric material on a heat insulated substrate. A technique for exposing the pyroelectric material to air is shown in Fig. 1. A piezoelectric crystal 3 is mounted on a stand 5 by the wires 4 and 5.
The electrode 1 for receiving infrared rays and the shield electrode 2 are formed on different sides of the piezoelectric crystal 3. Although heat capacity is reduced, the pyroelectric detector shown in Fig. 1 is not reliable or durable; it also is very difficult to manufacture and treat the pyroelectric detector because the pyroelectric crystal 3 is so thin.
Another prior art technique is shown in Fig.
2. The shield electrode 2, which is formed on one side of piezoelectric crystal 3, is connected to the heat insulated substrate 6 which is in turn mounted on the stand 5. The pyroelectric detector shown in Fig. 2 has the disadvantage that it is difficult to connect wire 4 to the shield electrode 2.
Another known structure is shown in Fig. 3.
This structure is described in Japanese patent publication no. 12272/1976 (Tokkosho). The shield electrode 2, which is mounted on one side of piezoelectric crystal 3, is formed around a heat insulated substrate 6 and mounted on stand 5 by conductive glue. The heat insulated substrate 6 is covered by an SnO2 film 7 so it is unnecessary to connect the shield electrode 2 to stand 5 by wire 4.
However, because the piezoelectric crystal 3 is mounted on the substrate 6, the heat capacity is great which prevents the detector from responding to fast changes in the energy of infrared rays. It also is difficult to manufacture and treat the detector shown in Fig. 3 because it is necessary to mount a very thin pyroelectric crystal.
The present invention seeks to provide a pyroelectric detector which can respond to fast changes in the energy of infrared rays.
The invention also seeks to provide a pyroelectric detector having a strong structure, high durability and high reliability.
The invention further seeks to provide an improved method for manufacturing pyroelectric detectors using thin pyroelectric material, and to provide a method which can be readily used for mass production of pyroelectric detectors.
According to the present invention there is provided a pyroelectric detector comprising: a pyroelectric material; and infrared receiving electrode mounted on one face of said pyroelectric material for receiving infrared rays; and a shield electrode on the other face of said pyroelectric material, the shield electrode being adhesively attached to a substrate made of semiconductive or conductive material which is in turn attached to a support member, the substrate having an aperture beneath the said infrared receiving electrode which aperture is larger in area than the electrode.
The invention also extends to a method of manufacturing pyroelectric detectors, in which a shield electrode is formed on one face of a wafer of pyroelectric material and hoes are made in a substrate of semiconductive or conductive material which is bonded to the shield electrode by conductive adhesive. The other face of the waer of pyroelectric material is ground and infrared receiving electrodes are formed therein for receiving infrared rays.
Each infrared receiving electrode, which has an area substantially less than the area of each hole in the substrate, is positioned over one of the holes. The water of pyroelectric material then is diced at positions between the holes.
Some embodiments of the invention will now be described by way of example with reference to the accompanying drawings, in which: Figure 1 shows a longitudinal sectional view of one prior art embodiment of a pyroelectric detector, Figure 2 shows a longitudinal sectional view of another prior art embodiment of a pyroelectric detector, Figure 3 shows a longitudinal sectional view of a third prior art embodiment of a pyroelectric detector, Figure 4a shows a longitudinal sectional view of one embodiment of the pyroelectric detector of the present invention; Figure 5 shows a wiring diagram for the pyroelectric detector; Figure 6 illustrates a sequence of steps in accordance with one method of making the pyroelectric detector; Figure 7 illustrates a sequence of steps in accordance with another method of making the invention; and; Figure 8 illustrates a sequence of steps in accordance with a further embodiment of the method of the invention.
Fig. 4a shows a cross sectional view of the preferred embodiment of th pyroelectric detector of the invention The crystal 11 is a wafer of pyroelectric material, such as a pyroelectric crystal like Lira03. The pyroelectric crystal 11 is approximately 50 lim thick and measures 3.5mm by 3.5mm.
An infrared receiving electrode 12, which receives infrared rays, is mounted on the upper face of pyroelectric crystal 11. The infrared receiving electrode 12 is a disk which measures 2mm in diameter. At the other face of pyroelectric crystal 11 is a shield electrode 13; shield electrode 13 covers the whole face of crystal 11. A substrate 15 made of semiconductive material such as silicon is fastened to the shield electrode 13 by conductive adhesive 14. The main plane of silicon substrate 15 has an orientation in the (100) plane; it measures 250 ym thick and is a square measuring 3.5 mm by 3.5mm. In the center of silicon substrate 15 is a square hole 16 which measures 2.5mm by 2.5mm. The hole 16 is made by selective etching.The position of the open area of hole 16 corresponds to the position of infrared receiving electrode 12 although hole 16 is substantially broader than infrared receiving electrode 12. The legs of silicon substrate 15 are fastened to stand 18 by conductive glue 17. The stand 18 and the lead terminal 20 are insulated from each other by insulating material 19. A lead wire 21 electrically connects lead terminal 20 and the infrared receiving electrode 12. Lead wire 21 is made of a material such as gold or aluminum.
The pyroelectric detector shown in Fig. 4A is mounted and assembled in a package as shown in Fig. 4B and an electric circuit for the pyroelectric detector of Fig. 4B is shown in Fig. 5. In this embodiment, infrared receiving electrode 12 contacts conductive supporting members 22a and 22b. On the stand next to pyroelectric crystal 11, resistors 23 and 24 and field effect transistor FET 25 are mounted. Stand 18 is hermetically sealed with N2 gas by cap 26; cap 26 has a silicon window 27 at the center. Three pins or terminals TI, T2, and T3 project through stand 18. The pin T1, which is grounded, is connected directly to stand 18; the pin T2 is connected to resistor 24 and the source of FET 25; and the pin T3 is connected to the drain of FET 25.Conductive supporting member 22b is connected to the gate of FET 25 and conductive supporting member 22a is connected to resistor 23. Resistors 23 and 24, which also are connected to stand 18, have resistance values of 10" and 104 ohms, respectively. When infrared rays pass through silicon window 27, they strike infrared receiving electrode 12 producing an output voltage between pin T1 and pin T2.
In the embodiment shown in Figs. 4A and 4B, the heat capacity is small because of the hole in substrate 15. Also, it is unnecessary to interconnect shield electrode 13 and and 18 with wire because substrate 15 is made of conductive or semiconductive material such as silicon and the substrate is fastened by conductive glue 14 and 17. Furthermore, this pyroelectric detector is durable because pyroelectric crystal 11 is supported by substrate 15.
The pyroelectric detector shown in Fig. 4A is manufactured in accordance with the method shown in Fig. 6. In Fig. 6(a), a shield electrode 13 is formed on a pyroelectric crs- tal wafer 31 which measures 63mm in diameter and 250 jim thick and which is made of a Z substrate of Lira03. The shield electrode 13, which may be made of nichrome, is formed by vacuum evaporation or sputtering.
In Fig. 6(b), an oxide film is formed on one face of a silicon substrate 15 which measures 63 mm in diameter and 250 jim thick The silicon substrate has an orientation (100). The oxide film 32 has square holes measuring 2.8mm X 2.8mm and it acts as a mask pattern for etching. As shown in Fig. 6(c), the other face of silicon substrate 15 is fastened to the shield electrode 13 of the wafer 31 by conductive adhesive 14. Then, as shown in Fig. 6(d), the other face of the pyroelectric crystal wafer 31 is ground until the wafer achieves a thickness of 50 jim.
The combined pyroelectric crystal wafer 31 and silicon substrate 15 is dipped into liquid Hydrazine at 100 C. The Hydrazine has a fast etching rate in the < 100 > direction and a a slow etching rate in the < 111 > direction.
Therefore, silicon substrate 15 is etched selec- tively at a 57 angle against the < 100 > face of the crystal. By selective etching, square holes 16, which each measure 2.5mum X 2.5mm, are made in silicon substrate 15 as shown in Fig. 6(e). As shown in Fig. 6(f), the oxide film 32 is removed and infrared receiving electrodes 12 are formed on the ground face of water 31. Each electrode 12 is a disk measuring 2.0mm in diameter.
The position of each electrode 12 corresponds to the position of a hole 16 and each electrode 12 has an area substantially less than the area of the corresponding hole 16.
Fig. 6(g) is an upper view of the wafer 31 after completion of the steps in Figs. 6(a)-(f).
In Fig. 6(g), the dotted line squares indicate holes 16 although the actual distance between holes 16 is greater than shown in Fig.
6(g). The wafer 32 is diced between holes 16 by a dicing machine to form a plurality of chips as shown in Figs. 6(h) and 6(i). The chip then is mounted on stand 18 and fastened by conductive glue 17 as shown in Fig.
6(j).
The method shown in Fig. 6 makes it easy to manufacture pyroelectric detectors because one large wafer is used. Therefore, it is possible to mass-produce the pyroelectric detectors.
Also, by using a universal dicing machine, cheap pyroelectric detectors can be obtained.
Various modifications can be made in the method shown in Fig. 6. Instead of the silicon substrate 15, substrates made of Ge, GaAS, or Gap can be used. Also, the step of making holes may be done before the step of grinding the other face of pyroelectric crystal wafer 31.
Fig. 7 shows another embodiment of the invention for manufacturing pyroelectric detectors. A shield electrode 42 is formed on one whole side of pyroelectric crystal wafer 41 in Fig. 7(a). As shown in Fig. 7(b), circular holes 43 are made through a substrate 44. The substrate 44 is made of a semiconductive or conductive material such as Si, Ge, GaAs, GaP, or metal. Circular holes 43 are made by a conventional mechanical process such as an ultrasonic horn method or a sand brass method.
As shown in Fig. 7(c), substrate 44 is fastened to the shield electrode 42 of the wafer 41 by conductive adhesive 45. In Fig.
7(d), the other face of the pyroelectric crystal wafer 41 is ground until the wafer is about 50 jim thick. In Fig. 7(e), on the ground face of wafer 41, infrared receiving electrodes 46 are formed. Each of the infrared receiving electrodes 46 is a disk, and the diameter of each disk is less than the diameter of each circular hole 43. The position of each infrared receiving electrode 46 corresponds to the position a hole 43. Then, as shown in Figs. 7(f) and (g), bonding electrodes 47 are formed between infrared receiving electrodes 46. Fig.
7(g) shows an upper view of the wafer 41 in which holes 43 are designated by dotted lines.
The wafer 41 shown in Fig. 7(9) is diced into chips by a universal dicing machine between circular holes 43. Figs. 7(h) and 7(i) show an individual chip. The chip of pyroelectric crystal 48 is mounted on stand 49 by conductive glue 50 as shown in Fig. 7(j). A lead terminal 51, which is supported by insulating material 52, is electrically connected to bonding electrode 47 by lead wire 53. Bonding electrode 47 corresponds to conductive supporting members 22a and 22b in Fig. 4B.
The pyroelectric detector in Fig. 7(i) is assembled as shown in Fig. 4B.
In the method shown in Fig. 7, the step of making holes is done by a mechanical process, and the time to manufacture pyroelectric detectors is short. The pyroelectric detector manufactured according to Fig. 7 is more durable than the pyroelectric detector of Fig.
6 because the hole 46 of substrate 44 is circular and the contact area between substrate 44 and stand 49 is large.
Fig. 8 shows yet another embodiment of the invention for manufacturing pyroelectric detectors. A shield electrode 62 is formed on one whole side of pyroelectric crystal wafer 61 in Fig. 8(a). Next, as shown in Fig. 8(b), a substrate 63 made of conductive thick-film paste and having circular holes 64 is formed on the shield electrode 62. The conductive thick-film paste is applied to the shield electrode 62, except in areas where the holes 64 are made, by screen printing for one hour.
The conductive thick-film paste then is baked for one hour.
As shown in Fig. 8(c), the other face of pyroelectric crystal wafer 61 is ground until the thickness is about 50 jim. As shown in Fig. 8(d), on the ground face of wafer 61, infrared receiving electrodes 65 are formed.
The infrared receiving electrodes 65 are formed by sputtering or vacuum evaporation of nichrome. Each of the infrared receiving electrodes 65 is a disk which measures 2.0 mm in diameter; the diameter of electrodes 65 is less than the diameter of each of the circular holes 64. The position of each electrode 65 corresponds to the position of a hole 64. Bonding electrodes 66 are formed adjacent to and in contact with the infrared receiving electrodes 65 as shown in Fig. 8(e).
Bonding electrodes 66, which are made of aluminum about 1 jim thick, are formed by vaccum evaporation.
The wafer 61 is diced between holes 64 at the dotted line positions shown in Fig. 8(e) by a universal dicing machine to form individual chips. A chip then is mounted on stand 68 and fastened by conductive glue 69. The chip 67 is assembled and packaged as shown in Fig. 4B.
In the method shown in Fig. 8, it is easy to manufacture pyroelectric detectors because a substrate 63 made of conductive thick-film paste is directly formed on the pyroelectric crystal wafer 61 without making holes.
In all the embodiments of the method of this invention, pyroelectric crystals such as a crystal of Lira03, are used as elements for detecting infrared rays. Other pyroelectric materials can be used such as triglycine sulphate (TGS), strontium barium niobate (SBN), PbTiO3 and PZT-type ferroelectric ceramics.

Claims (16)

1. A pyroelectric detector comprising: a pyroelectric material; an infrared receiving electrode mounted on one face of said pyroelectric material for receiving infrared rays; and a shield electrode on the other face of said pyroelectric material, the shield electrode being adhesively attached to a substrate made of semiconductive or conductive material which is in turn attached to a support member, the substrate having an aperture beneath the said infrared receiving electrode, which apertures is larger in area than the electrode.
2. A pyroelectric detector as claimed in claim 1 wherein said substrate is made of silicon.
3. A pyroelectric detector as claimed in claim 1, wherein said substrate is made of germanium.
4. A pyroelectric detector as claimed in claim 1 wherein said substrate is made of GaAs.
5. A pyroelectric detector as claimed in claim 1 wherein said substrate is made of GaP.
6. A pyroelectric detector as claimed in claim 1 wherein said substrate is made of a metal.
7. A pyroelectric detector as claimed in claim 1 wherein said substrate is made of conductive thick-film paste.
8. A pyroelectric detector as claimed in claim 1 wherein said pyroelectric material is Lira03 crystal.
9. A method of manufacturing pyroelectric detectors comprising the step of: forming a shield electrode on one face of a wafer of pyroelectric material; fastening a substrate made of semiconductive material to said one face of the wafer of pyroelectric material by means of conductive adhesive; grinding the other face of said shield electrode; making holes in said substrate; forming infrared receiving electrode for receiving infrared rays on the other face of said wafer of pyroelectric material, each of said infrared receiving electrodes being positioned over one of said holes on said other face of shield electrode; and dicing said pyroelectric material at positions between said holes.
10. A method of manufacturing pyroelectric detectors as set forther in claim 9 wherein one of Si, Ge, GaAs, or GaP is used as said substrate.
11. A method of manufacturing pyroelectric detectors as set forth in claim 10, wherein holes are made in the substrate by selective etching.
12. A method of manufacturing pyroelectric detectors comprising the steps of: forming a shield electrode on one face of a wafer of pyroelectric material; making holes through a substrate made of semiconductor or conductive material; fastening said substrate to said one face of said wafer of pyroelectric material by conductive adhesive; grinding the other face of said wafer of pyroelectric material; forming infrared receiving electrodes for receiving infrared rays on the other face of said wafer of pyroelectric material, each of said infrared receiving electrodes having an area substantially less than the area of each of said holes, each of said infrared receiving electrodes being positioned over one of said holes on said other face; and dicing said pyroelectric material at positions between said holes.
13. A method of manufacturing pyroelectric detectors set forth in claim 12 wherein one of Si, Ge, GaAs, GaP, or a metal is used as said substrate.
14. A method of manufacturing pyroelectric detectors set forth in claim 13 wherein the step of making holes in the substrate is done by a mechanical process.
15. A method of manufacturing pyroelectric detectors comprising the steps of: forming a shield electrode on one face of a wafer of pyroelectric material; forming a conductive thick-film paste on said shield electrode, said thick-film paste having holes therein; grinding the other face of said wafer of pyroelectric material; forming infrared receiving electrodes for receiving infrared rays on the other face of each pyroelectric material, each of said infrared receiving electrodes having an area substantially less than the area of each said holes, each of said infrared electrodes being positioned over one of said holes on said other face; and dicing said pyroelectric material at positions between the holes.
16. A pyroelectric detector substantially as herein described with reference to Fig. 4a or Fig. 4b, or Fig. 5f or Fig. 6f or Fig. 7 or Fig.
8f of the accompanying drawings.
1 7. A method of manufacturing pyroelectric detectors substantially as herein de scribe.
GB8030792A 1979-09-25 1980-09-24 Pyroelectric detector Expired GB2061616B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP54122947A JPS6037413B2 (en) 1979-09-25 1979-09-25 infrared detection device
JP3804380A JPS56133632A (en) 1980-03-25 1980-03-25 Manufacture of infrared-ray detector
JP3803580A JPS56133631A (en) 1980-03-25 1980-03-25 Infrared-ray detector

Publications (2)

Publication Number Publication Date
GB2061616A true GB2061616A (en) 1981-05-13
GB2061616B GB2061616B (en) 1983-09-14

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GB8030792A Expired GB2061616B (en) 1979-09-25 1980-09-24 Pyroelectric detector

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CA (1) CA1175130A (en)
DE (1) DE3035933C2 (en)
GB (1) GB2061616B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102101A1 (en) * 1982-07-23 1984-03-07 Philips Electronics Uk Limited Pyroelectric infra-red radiation detector
EP0145457A2 (en) * 1983-12-09 1985-06-19 Kureha Kagaku Kogyo Kabushiki Kaisha (also called: Kureha Chemical Industry Co. Ltd.) An infrared sensor
GB2152750A (en) * 1983-08-12 1985-08-07 Standard Telephones Cables Ltd Infra-red sensor array
EP0558766A1 (en) * 1991-09-24 1993-09-08 Nohmi Bosai Kogyo Kabushiki Kaisha Pyroelectric element
CN112768598A (en) * 2021-01-27 2021-05-07 山东大学 Infrared pyroelectric detector and preparation method thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3413921A1 (en) * 1984-04-13 1985-10-24 Preh, Elektrofeinmechanische Werke Jakob Preh Nachf. Gmbh & Co, 8740 Bad Neustadt METHOD FOR PRODUCING AN INFRARED DETECTOR
JP3289677B2 (en) * 1998-05-25 2002-06-10 株式会社村田製作所 Infrared sensor

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE376798B (en) * 1970-05-07 1975-06-09 Western Electric Co
US3707695A (en) * 1970-10-20 1972-12-26 Matsushita Electric Ind Co Ltd Infrared intensity detector using a pyroelectric polymer
US3801949A (en) * 1973-03-08 1974-04-02 Rca Corp Thermal detector and method of making the same
US4009516A (en) * 1976-03-29 1977-03-01 Honeywell Inc. Pyroelectric detector fabrication

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102101A1 (en) * 1982-07-23 1984-03-07 Philips Electronics Uk Limited Pyroelectric infra-red radiation detector
GB2152750A (en) * 1983-08-12 1985-08-07 Standard Telephones Cables Ltd Infra-red sensor array
EP0145457A2 (en) * 1983-12-09 1985-06-19 Kureha Kagaku Kogyo Kabushiki Kaisha (also called: Kureha Chemical Industry Co. Ltd.) An infrared sensor
EP0145457A3 (en) * 1983-12-09 1986-03-12 Kureha Kagaku Kogyo Kabushiki Kaisha (Also Called: Kureha Chemical Industry Co. Ltd.) An infrared sensor
EP0558766A1 (en) * 1991-09-24 1993-09-08 Nohmi Bosai Kogyo Kabushiki Kaisha Pyroelectric element
EP0558766A4 (en) * 1991-09-24 1993-11-18 Nohmi Bosai Kogyo Kabushiki Kaisha Pyroelectric element
US5420426A (en) * 1991-09-24 1995-05-30 Nohmi Boasai Ltd. Pyroelectric device
CN112768598A (en) * 2021-01-27 2021-05-07 山东大学 Infrared pyroelectric detector and preparation method thereof

Also Published As

Publication number Publication date
CA1175130A (en) 1984-09-25
DE3035933C2 (en) 1986-04-03
DE3035933A1 (en) 1981-04-09
GB2061616B (en) 1983-09-14

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Effective date: 19980915

PE20 Patent expired after termination of 20 years

Effective date: 20000923