GB2032413A - Foaming agents for cement - Google Patents
Foaming agents for cement Download PDFInfo
- Publication number
- GB2032413A GB2032413A GB7933052A GB7933052A GB2032413A GB 2032413 A GB2032413 A GB 2032413A GB 7933052 A GB7933052 A GB 7933052A GB 7933052 A GB7933052 A GB 7933052A GB 2032413 A GB2032413 A GB 2032413A
- Authority
- GB
- United Kingdom
- Prior art keywords
- foaming agent
- composition according
- cement
- alkali metal
- cement foaming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Foaming agent for preparing foamed cement insulating panels comprises alkali metal monoalkylolamido sulphosuccinate and alkyl or alkyl ether sulphate. The composition may be used to form a prefoam for admixture with cement, especially cements of low or zero sand content, and provides a foamed cement of improved foam stability. The sulphosuccinate is an alkali metal salt of a sulphosuccinate half ester of an alkylolamide or alkylolamide ether of the formula RCONH(R'O)nH where R is a straight or branched chain saturated or unsaturated hydrocarbon group of 6 to 22 carbon atoms, R' is an alkylene group of 2 to 3 carbon atoms and n is 1 to 20. The sulphate has a branched or straight chain alkyl group having from 6 to 22 carbon atoms and from 0 to 20 alkyleneoxy groups.
Description
SPECIFICATION
Foaming agents for cement
The invention relates to the use of certain surfactant blends as foaming agents for cement and sand/cement slurries. Such slurries are used to produce lightweight "foamed concrete" which is used as an insulation medium in buildings. Foamed concrete is typically produced by adding a "prefoam" of surfactant and water to the cement-containing slurry, mixing the compounds and pumping the mixture to a mould where it is allowed to set. Current foaming agents are not fully satisfactory, particularly when high cement content mixes are used, as the foam in the final mixture is not stable.We have found that certain surfactant blends, including some previously proposed for use as carpet shampoos (see for example U.S.P. 3862823) are very effective foaming agents for cement and cement/sand slurries and give foams which are more stable on standing than those prepared hitherto. The improvement is particularly marked in mixes of high cement content.
Our invention according to a first aspect provides a composition for use as a cement foaming agent comprising (A) at least 20% by weight of the total surface active ingredient of an alkali metal monoalkylolamido sulphosuccinate as defined herein and (B) at least 5% by weight of the total surface active ingredient of an alkali metal alkyl sulphate or alkali metal alkyl ether sulphate.
The term "alkali metal monoalkylolamido sulphosuccinate" as used herein means an alkali metal salt of a sulphosuccinate half ester of an alkylolamide or alkylolamide ether of the formula
RCONH (R'O)nH wherein R is a straight or branched chain saturated or unsaturated hydrocarbon group of 6 to 22 carbon atoms, preferably 8 to 20 carbon atoms, e.g. 10 to 14 carbon atoms and R' is an alkylene group of 2 to 3 carbonatoms and n is from 1 to 20, e.g. 1 to 5.
Typical examples of suitable alkylolamides of alkylolamide ethers include coconut mono (hydroxyethyl bisoxyethyl) amide, coconut monoethanolamide, oleic monoisopropanolamide, lauric mono (hydroxyethyl bisoxyethyl) amide and lauric monoethanolamide.
Preferably the proportion of sulphosuccinate is from 30 to 85% by weight more preferably 40 to 75% most preferably 50 to 70% e.g. 60 to 68% of the weight of surface active material.
The alkyl sulphate or alkyl ether sulphate has a branched or straight chain alkyl group having from 6 to 22 preferably 8 to 20, e.g. 10 to 18 carbon atoms and from 0 to 20, e.g. O to 4 alkyleneoxy groups, preferably ethyleneoxy groups. Typical examples include lauryl sulphate and lauryl alcohol three mole ethoxylate sulphate. The alkyl sulphate or alkyl ether sulphate is preferably present in a proportion of 1 5 to 70% more preferably 25 to 60%, most preferably 30 to 50%, e.g. 32 to 40% of the weight of surface active material.
It is preferred that the total surface active component of our novel composition consists essentially of the ingredients (A) and (B) as hereinbefore specified. The composition may additionally contain water in an amount sufficient to maintain fluidity. The amount of water is not critical and will typically be from zero to about 75% of the total weight of the mixture at the point of manufacture, e.g. 40 to 70%. In use the mixture may be diluted to a working concentration which is usually between 0.1% and 4%, preferably 0.2% to 2%, e.g. 0.9% to 1.8% by weight of solids.
Apart from the surface active material specified above and water our composition may optionally contain minor proportions, e.g. 0.1% to 4%, based on the weight of solids, of free fatty acid monoethanolamide, usually introduced with the sulphosuccinate as unreacted starting material. The free amide can sometimes contribute to the performance of the composition, so that although the normal impurity level is typically between 0.25 and 2% by weight of the solids, higher levels, e.g.
between 2 and 5% or even higher, e.g. up to 10% or even 20% may sometimes be produced by deliberate additions.
Similarly the composition may contain unsulphated fatty alcohols or ethoxylated alcohols such as those used to prepare the sulphate component of our mixture. They may be present in substantially the same proportions and preferred proportions as those described hereinbefore in relation to the free amide.
The product may contain traces of inorganic material such as alkali metal sulphate formed as an impurity during the preparation of the sulphate surfactant.
The alkali metal cations in our composition are preferably sodium but may alternatively be potassium or lithium or mixtures.
Our invention according to a second aspect provides a method of manufacturing foamed concrete by preparing an aqueous slurry of cement and optionally sand and mixing with it a prefoam comprising water, a foam stabilising amount of a composition according to the first aspect of our invention and air.
Preferably the composition of our invention is diluted to the working concentration and stirred vigorously to generate the prefoam.
According to a third aspect our invention provides foamed concrete prepared by the aforesaid method, and foamed concrete containing an effective amount of a composition according to the first aspect of our invention.
The weight of sand used may typically be from zero up to four times the weight of cement, or even higher. Water is added to give a workable slurry and the quantity required depends on the proportion of sand in the mixture. Typical volumes are 300 to 500 ml e.g. 400 ml water per kg cement for a cement only mix, 400 to 600 ml, e.g. 500 ml water per kg cement for a 1/1 sand/cement mix, and 600 to 1,800 ml, e.g. 1,200 ml water per kg cement for a 4/1 sand/cement mix.
The invention is illustrated by the following examples, of which Examples (i) to (xii) are comparative and Examples 1 to 24 use compositions of the invention.
EXAMPLE (i)
Cement (1 kg) and water (400 ml) were mixed in a Hobart mixer, speed 1.
25 ml of a 4% solution of disodium cocosulphosuccinate (40% solids) a typical commercial foaming agent, was then foamed in a container using a simple paddle stirrer to a volume of approximately 350 ml. This foam was then added to the stirred cement/water mix. A further 3 portions of foam (100 ml aqueous surfactant solution in all) were then added. The mix was then stirred for approximately 5 minutes when the foam density was at a stabilised level.
The foam produced was then assessed by measurement of:
a) density;
b) stability, a palette knife was drawn through the foam and the bubbles exposed should not break.
The density was 0.62 which is acceptable but the stability was totally unsatisfactory; the bubbles broke readily.
EXAMPLES (ii) to (vii)
The procedure of Example (i) was repeated using each of the following commercial surfactant compositions in turn as the foaming agent: (Al) Disodium cocomonoethanolamide sulphosuccinate (35% solids); (A2) Disodium cocomonoethanolamidediethoxylate sulphosuccinate (50% solids): (A3) Disodium oleicisopropanolamide sulphosuccinate (35% solids); (B1) Sodium lauryl sulphate (28% active); (B2) Sodium lauryl alcohol three mole ethoxylate sulphate (27% active);
The concentration by weight of each surfactant composition used, the volume of water mixed with each kg cement, and the density and stability of the resulting foamed concrete are summarised in Table
1. The term "wet" used in Table 1 indicates that the foam was completely unstable as water separated out from it.
TABLE 1
Surfactant ml water per Example and concentration kg cement Density Stability (ii) Al 4.0% 380 0.46 wet (iii) A.2 1.0% 350 wet good (iv) A3 3.4% 380 0.54 poor (v) A-5 4.57% 380 Q,55 poor (vi) 81 5.71% 380 0.59 poor (vii) B2 5.93% 380 0.23 moderate EXAMPLES 7 to 9
Compositions according to the invention were produced by mixing compositions Al and B1, A2 and B1, A3 and B1 in various proportions. The mixtures were diluted to working concentration and the procedure of Example (ii) was repeated using each diluted mixture in turn as the foaming agent. The results are summarised in Table 2.
TABLE 2
Surfactants ml water per Example and concentrations kg cement Density Stability 1 Al 3.2% B1 0.8% 380 0.38 good 2 Al 2.4% B1 1.6% 380 0.33 good 3 Al 1.4% B1 1.6% 380 0.34 good 4 A2 0.5% B1 0.5% 350 0.54 good 5 A2 0.3% B1 0.7% 350 0.47 good 6 A3 2.i% 151 0.8% 380 0.42 good 7 A3 2.0% B1 1.6% 380 0.40 good 8 A3 1.4% B1 2.4% 380 0.49 quite good 9 A3 2.97% B1 2.00% 400 0.38 good EXAMPLES 10 to 13
A composition according to the invention-was produced by mixing B1 with a commercial surfactant solution (A4) Disodium lauricmonoethanolamide sulphosuccinate (40% solids) having a free lauric monoethanolamide content of 1.2%.
Further compositions according to the invention were produced by adding to the above composition various proportions of lauric monoethanolamide (LME). The procedure of Example (ii) was repeated using each composition in turn, diluted to working concentration, as the foaming agent. The results are summarised in Table 3.
TABLE 3
Concentration based Concentration ml water Example on total composition of LME based per kg Density Stability A4 B1 LME on solids cement 10 2.6% 2.0% - 1.8% 400 0.37 good ft 2.6% 2.0% 0.05 h 4.8% 400 0.37 god 19 2.6% 2.0% 0.15% 10.7% 400 0.37 good 13 2.6% 2.0% 0.30% 17.2% 400 0.34 good EXAMPLES 14to 16
Compositions according to the invention were produced by mixing compositions A3 and B2 in the two different proportions and compositions A4 and B2. The procedure of Examples (ii) was repeated using each of the three solutions in turn, diluted to working concentration, as the foaming agent. The results are summarised in Table 4.
TABLE 4
Surfactants and ml water per Example concentrations kg cement Density Stability 14 A3 2.97% B2 2.00% 380 0.46 good 15 A3 2.29% 82 2.86% 380 0.54 good *16 A4 2.6% 82 2.0% :it00 0.40 good EXAMPLE (viii)
Cement (1 kg), sand (1 kg) and water (450 ml) were mixed in a Hobart mixer, speed 1.
25 ml of a 4% solution of disodium cocosulphosuccinate (40% solids) was then foamed in a container using a simple paddle stirrer to a volume of approximately 350 ml. This foam was then added to the stirred cement/sand/water mix. A further three portions of foam (1 00 ml aqueous surfactant solution in all) were then added. The mix was then stirred for approximately 4 minutes when the foam density was at a stabilised level.
The foam produced was then assessed by measurement of:
a) density;
b) stability, a palette knife was drawn through the foam and the bubbles exposed should not break.
The foam produced had a density of 0.70 but the stability was poor.
EXAMPLES (ix) to (xi) and 17 to 22
The procedure of example (viii) was repeated using as foaming agent each in turn of the compositions of Examples (v), (vi), (vii), 9, 14, 1 5, 10, 1 3, and 1 6 diluted to the same working concentration as in those examples. The results are summarised in Table 5.
TABLE 5
Component(s) and ml water per Example Concentration(s) kg cement Density Stability (ix) A3 4.57% - - 500 1.05 poor (x) B1 5.71% - - 500 0.82 poor (xi) B2 5.93% - - 450 0.95 moderate 17 A3 2.97% B1 2.00% - 500 0.70 good 18 A3 2.97% B2 2.00% - 450 0.75 good 19 A3 2.29% B2 2.86% - 450 0.73 good 20 A4 2.6% B1 2.0% - 500 0.83 good 21 A4 2.6% B1 2.0% LME 0.30% 500 0.84 good 22 A4 2.6% B2 2.0% - 450 0.68 good EXAMPLE (xii)
Cement (1 kg), sand (4 kg) and water (750 ml) were mixed in a Hobart mixer, speed 1.
25 ml of a 4% solution of disodium cocosulphosuccinate (40% solids) was then foamed in a container using a simple paddle stirrer to a volume of approximately 350 ml. This foam was then added to the stirred cement/sand/water mix. A further three portions of foam (100 ml aqueous surfactant solution in all) were then added. The mix was then stirred for approximately 5 minutes when the foam density was at a stabilised level.
The foam produced was then assessed by measurement of:
a. density
b. stability, a palette knife was drawn through the foam and the bubbles exposed should not break
The foam produced had a density of 1.08 and was fairly stable.
EXAMPLES 23 and 24
The procedure of Example (xii) was repeated using as foaming agent the composition of Example 9 at the same working concentration as it was used in that example. It was repeated again using the composition of Example 13 at the same working concentration as in Example 1 3. The results are summarised in Table 6.
TABLE 6
Components and ml water per Example concentrations kg cement Density Stability 23 A3 2.97% B1 2.00% - 1200 1.07 moderate 24 A4 2.6% B1 2.00% LME 0.30% 1200 1.07 good Each surfactant concentration given in the foregoing Tables is the percentage by weight of that commercial surfactant composition which is present in the composition at the working concentration.
Claims (16)
1. A composition for use as a cement foaming agent which composition comprises: (a) at least 20% by weight of the total surface active ingredient of an alkali metal monoalkylolamido sulphosuccinate, which sulphosuccinate is an alkali metal salt of a sulphosuccinate half ester of an alkylolamide or alkylolamide ether of the formula RCONH (RtO)n H wherein R is a straight or branched chain saturated or unsaturated hydrocarbon group of 6 to 22 carbon atoms, R' is an alkylene group of 2 to 3 carbon atoms and n is from 1 to 20 and
(b) at least 5% by weight of the total surface active ingredient of an alkali metal alkyl sulphate or alkali metal alkyl ether sulphate which has a branched or straight chain alkyl group having from 6 to 22 carbon atoms and from 0 to 20 alkyleneoxy groups.
2. A composition according to claim 1 for use as a cement foaming agent which composition comprises free fatty acid monoethanolamide.
3. A composition according to claim 2 for use as a cement foaming agent wherein the proportion of free fatty acid monoethanolamide is 2 to 20% by weight of the solids.
4. A composition according to any preceding claim for use as a cement foaming agent wherein R is a straight or branched chain saturated or unsaturated hydrocarbon group of 10 to 14 carbon atoms.
5. A composition according to any preceding claim for use as a cement foaming agent wherein n is from 1 to 5.
6. A composition according to any preceding claim for use as a cement foaming agent wherein the alkali metal alkyl sulphate or alkali metal alkyl ether sulphate has a branched or straight chain alkyl group having from 10 to 18 carbon atoms.
7. A composition according to any preceding claim for use as a cement foaming agent wherein the alkali metal alkyl sulphate or alkali metal alkyl ether sulphate has from 0 to 4 alkyleneoxy groups.
8. A composition according to any preceding claim for use as a cement foaming agent wherein (A) comprises 30 to 85% of the total surface active ingredient.
9. A composition according to any preceding claim for use as a cement foaming agent wherein (B) comprises 1 5 to 70% of the total surface active ingredient.
10. A composition according to any preceding claim for use as a cement foaming agent wherein (A) and (B) together with any free fatty acid alkylolamide comprise substantially all of the surface active ingredient.
1 A composition according to any preceding claim substantially as described herein with reference to any of examples 1 to 24 for use as a cement foaming agent.
12. A method of manufacturing foamed concrete which comprises preparing an aqueous slurry of cement and mixing it with a prefoam comprising water, a foam stabilising amount of composition as specified in any preceding claim and air.
13. A method according to claim 12 wherein the aqueous slurry comprises sand.
1 4. A method according to claim 13 wherein the weight ratio of sand to cenient is from 1:1 to 4:1.
1 5. Foamed concrete containing an effective amount of a composition according to any of claims 1 to 11.
16. Foamed concrete prepared by the method of any of claims 12 to 14.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7933052A GB2032413A (en) | 1978-09-29 | 1979-09-24 | Foaming agents for cement |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7838672 | 1978-09-29 | ||
GB7933052A GB2032413A (en) | 1978-09-29 | 1979-09-24 | Foaming agents for cement |
Publications (1)
Publication Number | Publication Date |
---|---|
GB2032413A true GB2032413A (en) | 1980-05-08 |
Family
ID=26269007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7933052A Withdrawn GB2032413A (en) | 1978-09-29 | 1979-09-24 | Foaming agents for cement |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2032413A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2500132A1 (en) * | 1981-02-13 | 1982-08-20 | Rodie Talbere Henri | Solar heat collector used as evaporator - with cold and hot zones employed to promote flow of heat transfer medium through evaporator |
FR2605245A1 (en) * | 1985-09-03 | 1988-04-22 | Millmaster Onyx Group Inc | FOAM GENERATING COMPOSITIONS AND METHOD FOR GENERATING FOAM FROM THIS COMPOSITION |
DE4339477A1 (en) * | 1993-11-19 | 1995-05-24 | Bayer Ag | Mineral building materials contg. plasticiser |
US7819993B2 (en) * | 2002-10-29 | 2010-10-26 | Yoshino Gypsum Co., Ltd. | Method for producing light gypsum board |
CN114477833A (en) * | 2022-01-25 | 2022-05-13 | 重庆彼目加科技有限公司 | Special foaming agent for light cement base and preparation method thereof |
-
1979
- 1979-09-24 GB GB7933052A patent/GB2032413A/en not_active Withdrawn
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2500132A1 (en) * | 1981-02-13 | 1982-08-20 | Rodie Talbere Henri | Solar heat collector used as evaporator - with cold and hot zones employed to promote flow of heat transfer medium through evaporator |
FR2605245A1 (en) * | 1985-09-03 | 1988-04-22 | Millmaster Onyx Group Inc | FOAM GENERATING COMPOSITIONS AND METHOD FOR GENERATING FOAM FROM THIS COMPOSITION |
DE4339477A1 (en) * | 1993-11-19 | 1995-05-24 | Bayer Ag | Mineral building materials contg. plasticiser |
US7819993B2 (en) * | 2002-10-29 | 2010-10-26 | Yoshino Gypsum Co., Ltd. | Method for producing light gypsum board |
CN114477833A (en) * | 2022-01-25 | 2022-05-13 | 重庆彼目加科技有限公司 | Special foaming agent for light cement base and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4618370A (en) | Foam generating compositions | |
US4676835A (en) | Foam generating compositions | |
JP3504346B2 (en) | Air entrainer for cement composition and cement composition | |
JPH0662991B2 (en) | Liquid detergent composition | |
JP3719706B2 (en) | Dispersant for gypsum slurry | |
ES8306174A1 (en) | Foam enhancing agent for light duty liquid detergent | |
US4715991A (en) | Aqueous high concentration surfactant slurry containing an olefin sulfonate | |
JPH05194362A (en) | Surfactant derived from sulfosuccinic acid ester | |
GB2032413A (en) | Foaming agents for cement | |
EP0164895B1 (en) | Detergent compositions | |
JP2801258B2 (en) | Foaming agent | |
CA1209438A (en) | Surfactant | |
US5589447A (en) | Liquid dishwashing-detergent composition | |
US4476043A (en) | Surfactant product | |
EP0500819B1 (en) | Liquid dishwashing composition | |
US5340502A (en) | Liquid dishwashing compositions comprising anionic tenside and three amphoteric compounds | |
JPH05140587A (en) | Liquid composition for dish washing | |
US4019916A (en) | Air entraining agents | |
CA1210662A (en) | Anionic nonionic surfactant mixture | |
EP1086056A1 (en) | Production of foamed compostions containing gypsum | |
PL170368B1 (en) | Method of obtaining a concentrated liquid detergent agent containing magnesium alkylbenzensulfonate and alkanolamide | |
JP2003313060A (en) | Foaming agent for hydraulic composition | |
JP4171623B2 (en) | A foam stabilizer for the production of lightweight cellular concrete | |
US3554912A (en) | Basic aluminum salt fire extinguishing compositions | |
JPH0393900A (en) | Liquid surface active composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |