GB2031896B - Process for the optical resolution of d,l-2-amino-4-methylphosphinobutyric acid - Google Patents
Process for the optical resolution of d,l-2-amino-4-methylphosphinobutyric acidInfo
- Publication number
- GB2031896B GB2031896B GB7933176A GB7933176A GB2031896B GB 2031896 B GB2031896 B GB 2031896B GB 7933176 A GB7933176 A GB 7933176A GB 7933176 A GB7933176 A GB 7933176A GB 2031896 B GB2031896 B GB 2031896B
- Authority
- GB
- United Kingdom
- Prior art keywords
- amino
- optical resolution
- methylphosphinobutyric acid
- methylphosphinobutyric
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NIBLDNQQTIFBAI-UHFFFAOYSA-N 2-amino-4-methylphosphanylbutanoic acid Chemical compound CPCCC(N)C(O)=O NIBLDNQQTIFBAI-UHFFFAOYSA-N 0.000 title 1
- 230000003287 optical effect Effects 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/04—Alpha- or beta- amino acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/78—Hydrolases (3) acting on carbon to nitrogen bonds other than peptide bonds (3.5)
- C12N9/80—Hydrolases (3) acting on carbon to nitrogen bonds other than peptide bonds (3.5) acting on amide bonds in linear amides (3.5.1)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Genetics & Genomics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Molecular Biology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- General Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12039078A JPS5547630A (en) | 1978-10-02 | 1978-10-02 | Optical resolution of phosphorus-containing amino acid |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2031896A GB2031896A (en) | 1980-04-30 |
GB2031896B true GB2031896B (en) | 1983-03-23 |
Family
ID=14785011
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7933176A Expired GB2031896B (en) | 1978-10-02 | 1979-09-25 | Process for the optical resolution of d,l-2-amino-4-methylphosphinobutyric acid |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS5547630A (zh) |
DE (1) | DE2939269C2 (zh) |
FR (1) | FR2438054A1 (zh) |
GB (1) | GB2031896B (zh) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3048612C2 (de) * | 1980-12-23 | 1982-12-02 | Hoechst Ag, 6000 Frankfurt | "Verfahren zur enzymatischen Trennung von L-2-Ami no-4-methylphosphinobuttersäure" |
JPS59219297A (ja) * | 1983-05-27 | 1984-12-10 | Meiji Seika Kaisha Ltd | 光学活性な〔(3−アミノ−3−カルボキシ)プロピル−1〕−ホスフイン酸誘導体の製造法 |
DE3544376A1 (de) * | 1985-12-14 | 1987-06-19 | Hoechst Ag | Dipeptide mit c-terminalem phosphinothricin, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses |
JPH0518339Y2 (zh) * | 1987-05-11 | 1993-05-17 | ||
DE3724722A1 (de) * | 1987-07-25 | 1989-02-16 | Hoechst Ag | Verbessertes verfahren zur enzymatischen herstellung von l-2-amino-4-methylphosphinobuttersaeure |
DE3817191A1 (de) * | 1988-05-20 | 1989-11-30 | Hoechst Ag | Verfahren zur racemisierung von optisch aktiver d-2-n-phenacetylamino-4- methylphosphinobuttersaeure |
DE3842025A1 (de) * | 1988-12-14 | 1990-07-05 | Hoechst Ag | Verfahren zur herstellung von l-phosphinothricin |
DE3903446A1 (de) * | 1989-02-06 | 1990-10-18 | Hoechst Ag | Verfahren zur enzymatischen trennung von 2-amino-4-methylphosphinobuttersaeurederivaten |
EP0499376A1 (en) * | 1991-01-31 | 1992-08-19 | Hoechst Celanese Corporation | Precipitation-induced asymmetric transformation of chiral alpha-amino acids and salts thereof |
DE4422045A1 (de) * | 1994-06-26 | 1996-01-04 | Hoechst Schering Agrevo Gmbh | Verfahren zur enzymatischen Spaltung von 2-Amino-4-methylphosphinobutansäureamid-Derivaten |
US6235516B1 (en) | 1996-04-25 | 2001-05-22 | Novartis Ag | Biocatalysts with amine acylase activity |
DE19933362A1 (de) * | 1999-07-20 | 2001-02-08 | Aventis Cropscience Gmbh | Verfahren zur Herstellung von L-Aminosäuren aus ihren racemischen N-Acetyl-D,L-Derivaten durch enzymatische Racemat-Spaltung mittels isolierter, rekombinanter Enzyme |
EP2287322A1 (en) * | 2002-02-26 | 2011-02-23 | Syngenta Limited | A method of selectively producing male or female sterile plants |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3816254A (en) * | 1970-02-03 | 1974-06-11 | Tanabe Seiyaku Co | Optical resolution of racemic amino acids |
JPS5318006B2 (zh) * | 1973-09-28 | 1978-06-13 | ||
FR2352827A1 (fr) * | 1976-05-26 | 1977-12-23 | Rhone Poulenc Ind | Complexes support-aminoacylase |
-
1978
- 1978-10-02 JP JP12039078A patent/JPS5547630A/ja active Granted
-
1979
- 1979-09-25 GB GB7933176A patent/GB2031896B/en not_active Expired
- 1979-09-27 FR FR7925384A patent/FR2438054A1/fr active Granted
- 1979-09-28 DE DE2939269A patent/DE2939269C2/de not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6247520B2 (zh) | 1987-10-08 |
JPS5547630A (en) | 1980-04-04 |
FR2438054A1 (fr) | 1980-04-30 |
DE2939269C2 (de) | 1982-07-08 |
DE2939269A1 (de) | 1980-04-30 |
FR2438054B1 (zh) | 1985-02-15 |
GB2031896A (en) | 1980-04-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PG | Patent granted |