GB2018782A - (Co)polymerization of conjugated diolefins using a chromium-containing catalyst system - Google Patents
(Co)polymerization of conjugated diolefins using a chromium-containing catalyst systemInfo
- Publication number
- GB2018782A GB2018782A GB7907994A GB7907994A GB2018782A GB 2018782 A GB2018782 A GB 2018782A GB 7907994 A GB7907994 A GB 7907994A GB 7907994 A GB7907994 A GB 7907994A GB 2018782 A GB2018782 A GB 2018782A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pentadiene
- chromium
- cis
- catalyst system
- isoprene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 229910052804 chromium Inorganic materials 0.000 title abstract 2
- 239000011651 chromium Substances 0.000 title abstract 2
- 150000001993 dienes Chemical class 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 4
- PMJHHCWVYXUKFD-PLNGDYQASA-N (3z)-penta-1,3-diene Chemical compound C\C=C/C=C PMJHHCWVYXUKFD-PLNGDYQASA-N 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 2
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 2
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- 150000001845 chromium compounds Chemical class 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- -1 diaryl hydrogen phosphites Chemical class 0.000 abstract 1
- 229920001198 elastomeric copolymer Polymers 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- LUVCTYHBTXSAMX-UHFFFAOYSA-N tris(2-chloroethyl) phosphite Chemical compound ClCCOP(OCCCl)OCCCl LUVCTYHBTXSAMX-UHFFFAOYSA-N 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Abstract
There is disclosed a method for homo-polymerizing cis-1,3-pentadiene or copolymerizing it with trans-1,3- pentadiene to prepare cis-1,4 polypentadienes. Other conjugated diolefins, including butadiene, isoprene, 2-ethyl- 1,3-butadiene and 2-methyl-1,3- pentadiene also may be copolymerized with the cis-1,3-pentadiene isomer to prepare elastomeric copolymers. There is also disclosed a method for the copolymerization of isoprene with trans-1,3-pentadiene. The polymerization catalyst employed in all of these polymerizations is a ternary catalyst system comprising (a) an organometallic compound selected from aluminum trialkyls, magnesium dialkyls and zinc dialkyls, (b) a soluble chromium compound selected from chromium salts of organic acids containing from 2 to 20 carbon atoms, organic complex compounds of chromium containing tridentate ligands and pi -bonded organochromium compounds, and (c) a member selected from dialkyl hydrogen phosphites, diaryl hydrogen phosphites and tris(2-chloro ethyl) phosphite.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/893,904 US4168374A (en) | 1978-04-05 | 1978-04-05 | Copolymerization of conjugated diolefins using a chromium-containing catalyst system |
| US05/893,725 US4148983A (en) | 1978-04-05 | 1978-04-05 | Polymerization and copolymerization of trans-piperylene and isoprene |
| US05/893,724 US4168357A (en) | 1978-04-05 | 1978-04-05 | Preparation of high cis-1,4-polypentadiene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2018782A true GB2018782A (en) | 1979-10-24 |
| GB2018782B GB2018782B (en) | 1982-08-04 |
Family
ID=27420550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7907994A Expired GB2018782B (en) | 1978-04-05 | 1979-03-07 | (co) polymerization of conjugated diolefins using a chronium-containing catalyst system |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS54135884A (en) |
| BR (1) | BR7902011A (en) |
| DE (1) | DE2911307A1 (en) |
| FR (1) | FR2421916A1 (en) |
| GB (1) | GB2018782B (en) |
| IT (1) | IT1116536B (en) |
| NL (1) | NL7902612A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3538130A1 (en) * | 1985-10-26 | 1987-04-30 | Bunawerke Huels Gmbh | METHOD AND CATALYST FOR PRODUCING SYNDIOTACTIC 1,2-POLYBUTADIENE |
| US6348550B1 (en) * | 2000-04-13 | 2002-02-19 | Bridgestone Corporation | Molybdenum-based catalyst composition and process for controlling the characteristics of conjugated diene polymers |
-
1979
- 1979-03-07 GB GB7907994A patent/GB2018782B/en not_active Expired
- 1979-03-22 DE DE19792911307 patent/DE2911307A1/en not_active Withdrawn
- 1979-04-02 IT IT48570/79A patent/IT1116536B/en active
- 1979-04-02 FR FR7908264A patent/FR2421916A1/en active Pending
- 1979-04-03 BR BR7902011A patent/BR7902011A/en unknown
- 1979-04-03 NL NL7902612A patent/NL7902612A/en not_active Application Discontinuation
- 1979-04-04 JP JP4086579A patent/JPS54135884A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54135884A (en) | 1979-10-22 |
| NL7902612A (en) | 1979-10-09 |
| IT1116536B (en) | 1986-02-10 |
| GB2018782B (en) | 1982-08-04 |
| FR2421916A1 (en) | 1979-11-02 |
| DE2911307A1 (en) | 1979-10-25 |
| BR7902011A (en) | 1979-11-27 |
| IT7948570A0 (en) | 1979-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4476240A (en) | Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier | |
| CA1124945A (en) | Copolymerization of conjugated diolefins using a chromium-containing catalyst system | |
| AU4773997A (en) | No-compounds for pseudo-living radical polymerization | |
| JPS5688409A (en) | Preparation of reinforced polybutadiene rubber | |
| ATE174350T1 (en) | METHOD FOR POLYMERIZATION USING DIE-CONTAINING CATALYSTS | |
| GB969900A (en) | Process for the polymerization of diolefins | |
| ES8102152A1 (en) | Process for polymerization of alpha -olefins and catalysts therefor | |
| GB1280030A (en) | A method for producing alternating copolymers | |
| SE7506393L (en) | POLYMERS AND CO-POLYMERS WITH MODIFIED STERIC COMPOSITION AND WAY TO PRODUCE THE SAME | |
| GB2018782A (en) | (Co)polymerization of conjugated diolefins using a chromium-containing catalyst system | |
| US4473661A (en) | Polymerization catalyst system containing organolithium, dialkyl magnesium and/or trialkyl aluminum, and a phosphine oxide | |
| ES8100314A1 (en) | Catalyst, catalyst composition and process for the polymerization of olefins. | |
| US4401800A (en) | Lithium alkoxide diamines as modifiers for polymerization of dienes using lithium-based initiators | |
| ES459105A1 (en) | Novel initiators for anionic polymerization | |
| US4530984A (en) | Process for production of polymers having increased 1,2-microstructure | |
| GB1525912A (en) | Manufacture of ethylene polymers | |
| ES409956A1 (en) | Solution polymerization process | |
| GB1487352A (en) | Method of chromizing a niobium containing steel substrate | |
| GB1400975A (en) | Process for the co-polymerization of isobutylene | |
| GB1153048A (en) | Improvements in and relating to Polymerisation and Copolymerisation of Conjugated Dienes | |
| ES250367A1 (en) | Improvements relating to the polymerisation of butadiene | |
| JPS56109205A (en) | Preparation of diene rubber | |
| GB1351511A (en) | Process for preparating a copolymer of a conjugated diene and ethylene | |
| GB1400497A (en) | Polymerisation of conjugated dienes | |
| JPS56112911A (en) | Improved polymerization method of alpha-olefin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |