GB2010323B - Preparation of gasoline containing tertiaryamyl methyl ether - Google Patents

Preparation of gasoline containing tertiaryamyl methyl ether

Info

Publication number
GB2010323B
GB2010323B GB7848248A GB7848248A GB2010323B GB 2010323 B GB2010323 B GB 2010323B GB 7848248 A GB7848248 A GB 7848248A GB 7848248 A GB7848248 A GB 7848248A GB 2010323 B GB2010323 B GB 2010323B
Authority
GB
United Kingdom
Prior art keywords
catalytic reaction
proportion
gasoline
methyl ether
fraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7848248A
Other versions
GB2010323A (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Canada Ltd
Original Assignee
Gulf Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/905,903 external-priority patent/US4193770A/en
Application filed by Gulf Canada Ltd filed Critical Gulf Canada Ltd
Publication of GB2010323A publication Critical patent/GB2010323A/en
Application granted granted Critical
Publication of GB2010323B publication Critical patent/GB2010323B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Gasoline containing tertiaryamyl methyl ether is prepared by (1) separating from a mixture of hydrocarbons a portion of olephinic hydrocarbons having predominantly 5 carbon atoms including 2-methyl butenes (2) catalytically reacting the hydrocarbon portion with methanol to etherify at least some of the 2-methyl butene, (3) fractionally distilling under reflux at least a proportion of the effluent stream from the catalytic reaction, a bottom fraction containing a major proportion of the ethers being withdrawn from the bottom of the distillation column and a distillate fraction being withdrawn from the top of the distillation column, (4) blending the bottom fraction and any remainder of the effluent stream from the catalytic reaction with gasoline and (5) recycling a proportion of the distillate fraction to the catalytic reaction, a proportion of the distillate fraction also being blended with the gasoline when the entire effluent from the catalytic reaction is passed to the fractional distillation. o
GB7848248A 1977-12-16 1978-12-13 Preparation of gasoline containing tertiaryamyl methyl ether Expired GB2010323B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA293245 1977-12-16
US05/905,903 US4193770A (en) 1977-12-22 1978-05-15 Preparation of gasoline containing tertiaryamyl methyl ether

Publications (2)

Publication Number Publication Date
GB2010323A GB2010323A (en) 1979-06-27
GB2010323B true GB2010323B (en) 1982-05-06

Family

ID=25668613

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7848248A Expired GB2010323B (en) 1977-12-16 1978-12-13 Preparation of gasoline containing tertiaryamyl methyl ether

Country Status (6)

Country Link
JP (1) JPS5494507A (en)
BR (1) BR7808273A (en)
DE (1) DE2854250C2 (en)
FR (1) FR2411881A1 (en)
GB (1) GB2010323B (en)
NL (1) NL7812230A (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2477570A1 (en) * 1980-03-10 1981-09-11 Inst Francais Du Petrole HYDROGENATION AND ETHERIFICATION OF AN UNCURRENT C5 CUTTING OF HYDROCARBONS IN ORDER TO IMPROVE OCTANE INDEX AND REDUCE THE MONO-OLEFINS CONTENT
DE3024147C2 (en) * 1980-06-27 1983-05-05 Edeleanu Gmbh, 6000 Frankfurt Process for the separation of the reaction products obtained in the etherification of lower i-olefins with methanol
FR2567534B1 (en) * 1984-07-10 1986-12-26 Inst Francais Du Petrole PROCESS FOR PRODUCING A CUP OF HIGH OCTANE INDEX HYDROCARBONS, BY ETHERIFICATION OF OLEFINS
JPH0220215Y2 (en) * 1987-07-09 1990-06-01
US4820877A (en) * 1987-12-28 1989-04-11 Mobil Oil Corporation Etherification process improvement
CA2043815C (en) * 1990-09-04 1997-04-01 Harvey D. Hensley Methyl-tertiary ether production
DE4215570C2 (en) * 1992-03-06 1995-12-14 Intevep Sa Process for preparing an ether-rich additive for gasoline and a plant
US5752992A (en) * 1993-12-15 1998-05-19 Exxon Chemical Patents Inc. (Ecpi) Use of tertiary-hexyl methyl ether as a motor gasoline additive
DE69602252T2 (en) * 1995-01-13 1999-08-19 Shell Int Research METHOD FOR PRODUCING ALKYL-TERTIARY ALKYL ETHERS

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR825559A (en) * 1936-08-15 1938-03-07 Standard Oil Dev Co Fuel
NL103620C (en) * 1957-06-27
US3482952A (en) * 1968-04-29 1969-12-09 Chevron Res Process for production of gasoline
GB1176620A (en) * 1968-07-09 1970-01-07 Shell Int Research Recovery of Tertiary Olefins
US3849082A (en) * 1970-06-26 1974-11-19 Chevron Res Hydrocarbon conversion process
CA958213A (en) * 1972-04-20 1974-11-26 Maurice Moyle Gasolines containing dialkyl ether azeotropes
PH12545A (en) * 1975-06-06 1979-06-07 Texaco Development Corp Method for preparation of ethers
DE2629769B2 (en) * 1976-07-02 1980-03-13 Chemische Werke Huels Ag, 4370 Marl Process for the production of pure methyl tertiary butyl ether

Also Published As

Publication number Publication date
JPS5494507A (en) 1979-07-26
FR2411881B1 (en) 1984-03-16
NL7812230A (en) 1979-06-19
JPS6133877B2 (en) 1986-08-05
FR2411881A1 (en) 1979-07-13
GB2010323A (en) 1979-06-27
DE2854250C2 (en) 1986-01-23
BR7808273A (en) 1979-08-14
DE2854250A1 (en) 1979-06-21

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee