GB185555A - Initial primers and a process for their manufacture - Google Patents
Initial primers and a process for their manufactureInfo
- Publication number
- GB185555A GB185555A GB1751921A GB1751921A GB185555A GB 185555 A GB185555 A GB 185555A GB 1751921 A GB1751921 A GB 1751921A GB 1751921 A GB1751921 A GB 1751921A GB 185555 A GB185555 A GB 185555A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salts
- diazotizing
- acid
- decomposing
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Dental Preparations (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Explosive salts of tetrazole or triazole or their derivatives are used in detonators, percussion caps, &c. These salts may be mixed or precipitated simultaneously to form double or mixed crystals with other ingredients such as azoimide, mono- and polynitrated phenols and their substitution products such as di- and tri-nitroresorcin and trinitrophloroglucinol, also m-dinitro, o-dinitrosobenzene and trinitrodinitroso-b -naphthol. The salts may also be granulated with paraffin or resins dissolved in benzene, xylene, or carbon tetrachloride. Blasting detonators may contain a top charge of such compositions, for example a charge of lead azotetrazole over lead or cadmium tetrazylnitride over tetranitromethylaniline. The preparation of the following substances is described, namely:-(1) Tetrazole, synthetically from dilute hydrazoic acid and prussic acid, or by reduction of diazotetrazole salts by chloride of tin or alcohol, or by oxidation of naphthyltetrazole or aminophenyltetrazole with potassium permanganate; (2) tetrazylazoimide, by splitting tetrazenes or treating tetrazylhydrazine with sodium nitrite and hydrochloric acid; (3) azotetrazole, by oxidizing aminotetrazole in alcoholic solutions with permanganates or persulphates, the aminotetrazole being obtained synthetically from cyanamide and hydrazoic acid or by reconstruction in the presence of sodium acetate of guanylazide salts formed when aminoguanidine salts are diazotized; (4) oxyazotetrazole, by treating diazotetrazole salts with carbonic acid; (5) diazoaminotetrazole, by diazotizing aminoguanidine salts with sodium nitrite in acetic acid solution; (6) diazotetrazole, by boiling phenyltetrazolecyanide with alcoholic synthetically from cyanogen gas and hydrocyanic acid solution; (8) phenyltetrazole-carboxylic acid, by boiling phenytetrazolecyanide with alcoholic potash lye; (9) methylmercaptotetrazole, by diazotizing methylthiosemicarbazide; (10) phenylethenyldioxytetrazole, by decomposing with alcoholic potash lye the phenylacetamidine salt thereof obtained during the diazotizing of phenylacetamidinenitrate; (11) b -naphthenyldioxytetrazole, by decomposing the b -naphthenylamidine salt obtained in diazotizing b -naphthenylamidine; (12) phenylglycolenyldioxytetrazole, by decomposition of the phenylglycolenylamidine salts obtained by diazotizing phenylglycolenylamidine; (13) benzenyldioxytetrazole, by diazotizing acid benzenylamidine and decomposing the benzenylamidine salt thus obtained; (14) m-nitrobenzenyldioxytetrazole, by diazotizing m-nitrobenzenylamidine; and (15) p-tolenyldioxytetrazole, by diazotizing p-tolenylamidine and decomposing the resulting p-tolenylamidine salt with alcoholic potash lye.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1751921A GB185555A (en) | 1921-06-27 | 1921-06-27 | Initial primers and a process for their manufacture |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1751921A GB185555A (en) | 1921-06-27 | 1921-06-27 | Initial primers and a process for their manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
GB185555A true GB185555A (en) | 1922-09-14 |
Family
ID=10096609
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1751921A Expired GB185555A (en) | 1921-06-27 | 1921-06-27 | Initial primers and a process for their manufacture |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB185555A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4024818A (en) * | 1976-03-16 | 1977-05-24 | The United States Of America As Represented By The Secretary Of The Navy | Stab-initiated explosive device containing a single explosive charge |
FR2584066A1 (en) * | 1985-06-28 | 1987-01-02 | Poudres & Explosifs Ste Nale | USE OF 5-OXO 3-NITRO, 1,2,4-TRIAZOLE AS AN EXPLOSIVE SUBSTANCE AND PYROTECHNIC COMPOSITIONS CONTAINING 5-OXO 3-NITRO 1,2,4-TRIAZOLE |
DE102010024728A1 (en) * | 2009-12-23 | 2011-06-30 | Diehl BGT Defence GmbH & Co. KG, 88662 | Bis-Tetrazolytriazenate, process for its preparation and explosives or fuel containing bis-Tetrazolytriazenat |
DE102010025104A1 (en) * | 2010-04-14 | 2011-10-20 | Diehl Bgt Defence Gmbh & Co. Kg | 5,5'-azotetrazolate explosives |
DE102010036950A1 (en) * | 2010-08-11 | 2012-02-16 | Nammo Germany Gmbh | New metal-tetrazole complex useful as initiating explosive for preparing an explosive, which is useful as blasting agent, propellant, fuel composition or ignition composition |
EP2548857A1 (en) * | 2011-07-20 | 2013-01-23 | Diehl BGT Defence GmbH & Co.KG | Use of a bistetrazolyl amine salt |
CN103214503A (en) * | 2013-05-10 | 2013-07-24 | 南昌航空大学 | Non-heart cadmium metal complex containing tetrazole-5-acetic acid organic ligand as well as preparation method and application thereof |
CN103333183A (en) * | 2013-06-25 | 2013-10-02 | 南昌航空大学 | Non-center cadmium metal complex and synthetizing method and application thereof |
GB2517119A (en) * | 2013-01-17 | 2015-02-18 | Utm Ip Ltd | Explosive composition for use in telescopically expanding non-lethal training ammunition |
-
1921
- 1921-06-27 GB GB1751921A patent/GB185555A/en not_active Expired
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4024818A (en) * | 1976-03-16 | 1977-05-24 | The United States Of America As Represented By The Secretary Of The Navy | Stab-initiated explosive device containing a single explosive charge |
FR2584066A1 (en) * | 1985-06-28 | 1987-01-02 | Poudres & Explosifs Ste Nale | USE OF 5-OXO 3-NITRO, 1,2,4-TRIAZOLE AS AN EXPLOSIVE SUBSTANCE AND PYROTECHNIC COMPOSITIONS CONTAINING 5-OXO 3-NITRO 1,2,4-TRIAZOLE |
EP0210881A1 (en) * | 1985-06-28 | 1987-02-04 | Societe Nationale Des Poudres Et Explosifs | Use of 5-oxo-3-nitro-1,2,4-triazole as a secondary explosive and pyrotechnical compositions comprising 5-oxo-3-nitro-1,2,4-triazole |
US5034072A (en) * | 1985-06-28 | 1991-07-23 | Societe Nationale Des Poudres Et Explosifs | 5-oxo-3-nitro-1,2,4-triazole in gunpowder and propellant compositions |
DE102010024728A1 (en) * | 2009-12-23 | 2011-06-30 | Diehl BGT Defence GmbH & Co. KG, 88662 | Bis-Tetrazolytriazenate, process for its preparation and explosives or fuel containing bis-Tetrazolytriazenat |
EP2338863A3 (en) * | 2009-12-23 | 2011-10-26 | Diehl BGT Defence GmbH & Co.KG | Bis-tetrazolytriazenate, method for producing same and explosive or fuel containing bis-tetrazolyltriazenate |
DE102010025104B4 (en) * | 2010-04-14 | 2015-06-11 | Diehl Bgt Defence Gmbh & Co. Kg | initiating explosive |
DE102010025104A1 (en) * | 2010-04-14 | 2011-10-20 | Diehl Bgt Defence Gmbh & Co. Kg | 5,5'-azotetrazolate explosives |
EP2377840A3 (en) * | 2010-04-14 | 2012-01-11 | Diehl BGT Defence GmbH & Co.KG | 5,5'-azotetrazolate explosive |
DE102010036950A1 (en) * | 2010-08-11 | 2012-02-16 | Nammo Germany Gmbh | New metal-tetrazole complex useful as initiating explosive for preparing an explosive, which is useful as blasting agent, propellant, fuel composition or ignition composition |
DE102010036950B4 (en) * | 2010-08-11 | 2014-04-03 | Nammo Germany Gmbh | Explosive metal complexes, their preparation and use, as well as detonators |
EP2548857A1 (en) * | 2011-07-20 | 2013-01-23 | Diehl BGT Defence GmbH & Co.KG | Use of a bistetrazolyl amine salt |
EP2679567A3 (en) * | 2011-07-20 | 2017-10-04 | Diehl Defence GmbH & Co. KG | Use of a bistetrazolyl amine salt |
GB2517119A (en) * | 2013-01-17 | 2015-02-18 | Utm Ip Ltd | Explosive composition for use in telescopically expanding non-lethal training ammunition |
GB2517119B (en) * | 2013-01-17 | 2021-03-03 | Utm Ltd | Explosive composition for use in telescopically expanding non-lethal training ammunition |
CN103214503A (en) * | 2013-05-10 | 2013-07-24 | 南昌航空大学 | Non-heart cadmium metal complex containing tetrazole-5-acetic acid organic ligand as well as preparation method and application thereof |
CN103214503B (en) * | 2013-05-10 | 2016-03-02 | 南昌航空大学 | A kind of non-heart Metal cadmium complex containing tetrazole-5-acetic acid organic ligand and its preparation method and application |
CN103333183A (en) * | 2013-06-25 | 2013-10-02 | 南昌航空大学 | Non-center cadmium metal complex and synthetizing method and application thereof |
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