GB1599366A - Submerged injection of gas into liquid pyro-metallurgical bath - Google Patents
Submerged injection of gas into liquid pyro-metallurgical bath Download PDFInfo
- Publication number
- GB1599366A GB1599366A GB16975/78A GB1697578A GB1599366A GB 1599366 A GB1599366 A GB 1599366A GB 16975/78 A GB16975/78 A GB 16975/78A GB 1697578 A GB1697578 A GB 1697578A GB 1599366 A GB1599366 A GB 1599366A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lance
- gas
- slag
- tube
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002347 injection Methods 0.000 title claims description 15
- 239000007924 injection Substances 0.000 title claims description 15
- 239000007788 liquid Substances 0.000 title claims description 14
- 239000007789 gas Substances 0.000 claims description 56
- 239000002893 slag Substances 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 30
- 238000003723 Smelting Methods 0.000 claims description 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 11
- 229910000831 Steel Inorganic materials 0.000 claims description 9
- 239000000446 fuel Substances 0.000 claims description 9
- 239000010959 steel Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000011160 research Methods 0.000 claims description 4
- 238000012546 transfer Methods 0.000 claims description 4
- 239000000295 fuel oil Substances 0.000 claims description 3
- 239000003517 fume Substances 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 235000013980 iron oxide Nutrition 0.000 claims description 3
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 3
- 239000011253 protective coating Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims description 2
- 230000002093 peripheral effect Effects 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 description 16
- 239000010949 copper Substances 0.000 description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 229910052718 tin Inorganic materials 0.000 description 10
- 239000011135 tin Substances 0.000 description 10
- 239000012141 concentrate Substances 0.000 description 7
- 238000007670 refining Methods 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 239000003245 coal Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 238000003780 insertion Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 241001062472 Stokellia anisodon Species 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- WETINTNJFLGREW-UHFFFAOYSA-N calcium;iron;tetrahydrate Chemical compound O.O.O.O.[Ca].[Fe].[Fe] WETINTNJFLGREW-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052952 pyrrhotite Inorganic materials 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/4606—Lances or injectors
- C21C5/4613—Refractory coated lances; Immersion lances
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/12—Dry methods smelting of sulfides or formation of mattes by gases
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/10—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals with refining or fluxing agents; Use of materials therefor, e.g. slagging or scorifying agents
- C22B9/103—Methods of introduction of solid or liquid refining or fluxing agents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Furnace Details (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPD004177 | 1977-05-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1599366A true GB1599366A (en) | 1981-09-30 |
Family
ID=3766976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB16975/78A Expired GB1599366A (en) | 1977-05-09 | 1978-04-28 | Submerged injection of gas into liquid pyro-metallurgical bath |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4251271A (enExample) |
| JP (1) | JPS53141107A (enExample) |
| CA (1) | CA1107080A (enExample) |
| DE (1) | DE2819587A1 (enExample) |
| GB (1) | GB1599366A (enExample) |
| MY (1) | MY8300150A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5350158A (en) * | 1990-10-31 | 1994-09-27 | Mincorp Limited | Metallurgical lance and method of cooling the lance |
| US5374299A (en) * | 1990-09-26 | 1994-12-20 | Johannesburg Consolidated Investment Company Limited | Pyrometallurgical process for treating a feed material |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1275174C (en) * | 1985-03-07 | 1990-10-16 | Richard Graham Hollis | Secondary lead production |
| EP0196800B1 (en) * | 1985-03-07 | 1990-07-18 | Mount Isa Mines Limited | Secondary lead production |
| GB8514587D0 (en) * | 1985-06-10 | 1985-07-10 | Britannia Refined Metals Ltd | Recovery of metals from their alloys with lead |
| SG45386A1 (en) * | 1989-09-29 | 1998-01-16 | Ausmelt Ltd | Top submerged injection with a shrouded lance |
| JPH06506759A (ja) * | 1991-04-23 | 1994-07-28 | コモンウェルス・サイエンティフィック・アンド・インダストリアル・リサーチ・オーガニゼイション | 加熱冶金法の浴に浸すためのランスおよびランスを含む方法 |
| IN181041B (enExample) * | 1991-09-20 | 1998-04-18 | Ausmelt Ltd | |
| US5591271A (en) * | 1994-08-26 | 1997-01-07 | Comesi S.A.I.C. | Process for cleaning inductor channels of furnaces melting non-ferrous metal alloys |
| IT1302798B1 (it) | 1998-11-10 | 2000-09-29 | Danieli & C Ohg Sp | Dispositivo integrato per l'iniezione di ossigeno e gastecnologici e per l'insufflaggio di materiale solido in |
| AUPQ535500A0 (en) * | 2000-01-31 | 2000-02-17 | Technological Resources Pty Limited | Apparatus for injecting gas into a vessel |
| FI115536B (fi) * | 2001-09-21 | 2005-05-31 | Outokumpu Oy | Menetelmä raakakuparin tuottamiseksi |
| US7749301B2 (en) * | 2004-04-07 | 2010-07-06 | Ausmelt Limited | Process for copper converting |
| EP1652940B1 (en) * | 2004-10-15 | 2009-12-30 | Technological Resources Pty. Ltd. | Apparatus for injecting gas into a vessel |
| JP5800990B2 (ja) * | 2011-06-30 | 2015-10-28 | オウトテック オサケイティオ ユルキネンＯｕｔｏｔｅｃ Ｏｙｊ | 上部浸漬注入ランス |
| PH12014500341A1 (en) * | 2011-09-02 | 2014-03-31 | Outotec Oyj | Lances for top submerge injection |
| KR101690393B1 (ko) | 2011-11-30 | 2016-12-27 | 오토텍 오와이제이 | 상부 침지 주입을 위한 유체 냉각 랜스들 |
| JP5962162B2 (ja) * | 2012-04-13 | 2016-08-03 | Ｊｆｅスチール株式会社 | 溶銑の精錬方法 |
| WO2013192386A1 (en) | 2012-06-21 | 2013-12-27 | Orchard Material Technology Llc | Production of copper via looping oxidation process |
| AU2013204818B2 (en) | 2013-04-12 | 2015-02-19 | Metso Metals Oy | Molten bath temperature measurement for a top submerged lance injection installation |
| WO2015056142A1 (en) | 2013-10-16 | 2015-04-23 | Outotec (Finland) Oy | Top submerged injection lance for enhanced heat transfer |
| ES2626828T3 (es) | 2013-10-16 | 2017-07-26 | Outotec (Finland) Oy | Lanza de inyección con la parte superior sumergida para combustión sumergida mejorada |
| CN104406414B (zh) * | 2014-10-27 | 2016-06-22 | 云南铜业科技发展股份有限公司 | 一种浸没式管束混合顶吹喷枪 |
| CN105039740A (zh) * | 2015-08-06 | 2015-11-11 | 中国恩菲工程技术有限公司 | 采用富氧旋涡熔池熔炼炉处理红土镍矿的方法 |
| WO2017098446A1 (en) * | 2015-12-09 | 2017-06-15 | Tenova South Africa (Pty) Ltd | Method of operating a top submerged lance furnace |
| CN109852759B (zh) * | 2019-02-12 | 2020-12-18 | 山东钢铁股份有限公司 | 用于旋流氧枪喷头的溅渣护炉方法 |
| CN117144147A (zh) * | 2023-08-31 | 2023-12-01 | 云南锡业股份有限公司铜业分公司 | 一种旋流冶炉及其冶炼工艺 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3131054A (en) * | 1954-02-20 | 1964-04-28 | Siegerlander Kupferwerke G M B | Gas nozzles and methods of operating the same |
| FR1424029A (fr) * | 1964-01-06 | 1966-01-07 | Union Carbide Corp | Procédé et appareil pour introduire un courant de gaz de traitement dans un bain de métal en fusion |
| US3310238A (en) * | 1964-06-26 | 1967-03-21 | British Oxygen Co Ltd | Furnace lances |
| DE1508154A1 (de) * | 1966-07-14 | 1969-02-06 | Demag Ag | Metallurgischer Ofen,insbesondere Herdofen,Drehofen,Konverter od.dgl.,mit Blaslanzenwagen |
| US3615362A (en) * | 1969-02-14 | 1971-10-26 | Int Nickel Co | Slagging in top blown converters |
| US3932172A (en) * | 1969-02-20 | 1976-01-13 | Eisenwerk-Gesellschaft Maximilianshutte Mbh | Method and converter for refining pig-iron into steel |
| US3634069A (en) * | 1969-03-10 | 1972-01-11 | Conzinc Riotinto Ltd | Tin smelting |
| US3876190A (en) * | 1969-06-25 | 1975-04-08 | Commw Ind Gases | Method and apparatus for feeding particulate materials to furnaces and the like |
| DE2040724A1 (de) * | 1970-08-17 | 1972-02-24 | Messer Griesheim Gmbh | Duese fuer Brenner oder Sauerstoffblaslanzen |
| DE2058967B2 (de) * | 1970-12-01 | 1975-08-21 | Sueddeutsche Kalkstickstoff-Werke Ag, 8223 Trostberg | Tauchlanze |
| FR2131674A5 (enExample) | 1971-04-10 | 1972-11-10 | Messer Griesheim Gmbh | |
| US3752402A (en) * | 1971-04-19 | 1973-08-14 | H Marioneaux | Fluid injection lance and nozzle means therefor |
| US3905807A (en) * | 1971-07-30 | 1975-09-16 | Commw Scient Ind Res Org | Recovery of tin from slags |
| SU605549A3 (ru) * | 1973-03-03 | 1978-04-30 | Эйзенверк-Гезельшафт Максимилиансхютте Гмбх (Фирма) | Фурма |
| US3898078A (en) * | 1973-03-29 | 1975-08-05 | Youngstown Sheet And Tube Co | Method and apparatus for injecting refining oxygen in steelmaking processes |
| US3843105A (en) * | 1973-04-05 | 1974-10-22 | Berry Metal Co | Apparatus and method for contacting molten metal with gas |
| SU452599A1 (ru) | 1973-07-06 | 1974-12-05 | Киевский политехнический институт им. 50-летия Великой Октябрьской социалистической революции | Фурма дл ввода газообразных и жидких реагентов в расплав |
| SU500239A1 (ru) * | 1974-06-14 | 1976-01-25 | Государственный Союзный Институт По Проектированию Агрегатов И Сталелитейного Прокатного Производства Для Черной Металлургии | Фурма дл глубинной продувки металла |
| LU73846A1 (enExample) * | 1975-11-21 | 1977-05-31 |
-
1978
- 1978-04-28 GB GB16975/78A patent/GB1599366A/en not_active Expired
- 1978-04-28 CA CA302,279A patent/CA1107080A/en not_active Expired
- 1978-05-01 US US05/901,513 patent/US4251271A/en not_active Expired - Lifetime
- 1978-05-05 DE DE19782819587 patent/DE2819587A1/de active Granted
- 1978-05-09 JP JP5544178A patent/JPS53141107A/ja active Granted
-
1983
- 1983-12-30 MY MY150/83A patent/MY8300150A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5374299A (en) * | 1990-09-26 | 1994-12-20 | Johannesburg Consolidated Investment Company Limited | Pyrometallurgical process for treating a feed material |
| US5350158A (en) * | 1990-10-31 | 1994-09-27 | Mincorp Limited | Metallurgical lance and method of cooling the lance |
Also Published As
| Publication number | Publication date |
|---|---|
| MY8300150A (en) | 1983-12-31 |
| CA1107080A (en) | 1981-08-18 |
| JPS53141107A (en) | 1978-12-08 |
| DE2819587C2 (enExample) | 1987-11-05 |
| DE2819587A1 (de) | 1978-11-16 |
| JPS6229496B2 (enExample) | 1987-06-26 |
| US4251271A (en) | 1981-02-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19980427 |