GB1597363A - Fungicidal combinations - Google Patents

Fungicidal combinations Download PDF

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Publication number
GB1597363A
GB1597363A GB37251/77A GB3725177A GB1597363A GB 1597363 A GB1597363 A GB 1597363A GB 37251/77 A GB37251/77 A GB 37251/77A GB 3725177 A GB3725177 A GB 3725177A GB 1597363 A GB1597363 A GB 1597363A
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GB
United Kingdom
Prior art keywords
formulation
combination
maneb
mixture
active ingredients
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37251/77A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lilly Industries Ltd
Original Assignee
Lilly Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lilly Industries Ltd filed Critical Lilly Industries Ltd
Priority to GB37251/77A priority Critical patent/GB1597363A/en
Priority to IE1685/78A priority patent/IE47245B1/en
Priority to CA309,834A priority patent/CA1090247A/en
Priority to NZ188229A priority patent/NZ188229A/en
Priority to IL7855441A priority patent/IL55441A0/en
Priority to GR57104A priority patent/GR63167B/en
Priority to ZA00784883A priority patent/ZA784883B/en
Priority to TR20300A priority patent/TR20300A/en
Priority to FI782685A priority patent/FI61608C/en
Priority to IN961/CAL/78A priority patent/IN149680B/en
Priority to AR273534A priority patent/AR218330A1/en
Priority to FR7825298A priority patent/FR2402409A1/en
Priority to BG7840814A priority patent/BG32111A3/en
Priority to IT50962/78A priority patent/IT1106132B/en
Priority to DK391378A priority patent/DK156753C/en
Priority to DE19782838575 priority patent/DE2838575A1/en
Priority to CH933078A priority patent/CH634462A5/en
Priority to BE6046599A priority patent/BE870237A/en
Priority to CS785753A priority patent/CS207667B2/en
Priority to BR7805811A priority patent/BR7805811A/en
Priority to SE7809387A priority patent/SE447441B/en
Priority to PH21574A priority patent/PH14333A/en
Priority to JP10954378A priority patent/JPS5452727A/en
Priority to AU39616/78A priority patent/AU526357B2/en
Priority to HU78LI332A priority patent/HU180831B/en
Priority to SU782658657A priority patent/SU816390A3/en
Priority to UA2658657A priority patent/UA6333A1/en
Priority to NO783044A priority patent/NO147091C/en
Priority to NL7809096A priority patent/NL7809096A/en
Priority to PL1978209466A priority patent/PL111723B1/en
Priority to MX787381U priority patent/MX5503E/en
Priority to ES473293A priority patent/ES473293A1/en
Priority to JO1978983A priority patent/JO983B1/en
Priority to DD78207689A priority patent/DD138593A5/en
Priority to AT647578A priority patent/AT361248B/en
Publication of GB1597363A publication Critical patent/GB1597363A/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A fungicidal composition and a process for the fungicidal treatment of crops are described. The composition consists of a mixture of [[1,2-ethanediylbis[carbamodithioato]](2-)]manganese and pyrimidinemethanol, optionally mixed with a non-phytotoxic, inert vehicle, diluent or excipient. Application to the treatment of cereals, in particular of barley and of winter barley, of oats and of wheat.

Description

(54) FUNGICIDAL COMBINATIONS (71) We, LILLY INDUSTRIES LIMITED, a British company of Lilly House, Hanover Square, London, W1R OPA, England, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement: The present invention relates to a method of reducing the incidence and severity of fungal infections in cultivated plants especially cereals, to a novel combination useful in such treatment and to fungicidal formulations containing said novel combination.
According to a first aspect of the present invention there is provided a novel combination of [[1 ,2-ethanediylbis[carbamoodithioato] ](2-)]-manganese and a pyrimidine methanol of formula (I):
where X is chlorine or fluorine.
[[1,2-Ethanediylbis[carbamodithioato]](2-)l-manganeseis a known compound (see U.S.
Patents Nos. 2,504,404 and 2,710,822) having the generic name "Maneb". The pyrimidine methanols of formula (I) are also known and can be prepared by the process described in U.K. Patent Specification No. 1,218,623. The compound of formula (I) where Xis fluorine is preferred.
The novel combination of the present invention is surprisingly effective in controlling or combatting fungal infections in cereals. It is especially active when applied as a seed dressing, controlling many important diseases of which the following are a representative sample: 1. Diseases of Barley (Hordeum vulgare) Pyrenophora grnminea Cochliobolus sativus Calonectria nivalis Typhula incarnata Erysiphae graminis 2. Diseases of Oats (Avena sativa) Pyrenophora avenae 3. Diseases of Wheat Cercosporella herpotrichoides Tilletia spp.
Calonectria nivalis Leptosphaeria nodorum Accordingly, in a second aspect of the invention there is provided a method of reducing the incidence or severity of fungal infections in cereals which comprises dressing seeds of said cereals with a chemotherapeutically effective amount of the novel combination defined above.
Although the novel combination is preferably utilised in the form of a seed dressing, beneficial results have also been derived from foliar application of the novel combination at any time after crop emergence up until harvest; the actual frequency and duration of treatment being determined by the severity of the actual or expected disease. The components of the combinations may be applied sequentially or simultaneously to the crop to be treated.
The pyrimidine methanol is preferably applied to the seeds in an amount of from 0.05 to 0.8 g/Kg, most preferably at 0.1g/Kg for wheat and 0.2 g/Kg, for barley, of seed whereas the Maneb is preferably applied in an amount of from 0.2 to 1.6 g/Kg, most preferably at approximately 0.8 g/Kg, of seed. A preferred ratio of the pyrimidine methanol to the Maneb is from 1 : 2 to 1: 32, preferably 1: 4 to 1: 8.
The novel combination of the invention is preferably utilised in the form of a fungicidal formulation comprising the pyrimidine methanol and the Maneb associated with a non-phytotoxic, inert carrier therefor.
The fungicidal formulations of the invention may comprise from 5 to 90% by weight of active ingredients and will usually be in the form of a wettable powder or dust.
Wettable powders or dusts comprise an intimate mixture of the active ingredients, one or more inert carriers and appropriate surfactants. The inert carrier may be chosen from the attapulgite clays, the montmorillonite clays, the diatomaceous earths, kaolins, micas, talcs and purified silicates. Effective surfactants may be found among the sulfonated lignins, the naphthalene sulfonates and condensed naphthalene sulfonates, the alkyl succinates, the alkylbenzene sulfonates, the alkyl surfaces and nonionic surfactants such as ethylene oxide adducts of phenol. When used for seed dressing, formulations of the invention will also preferably comprise an adhesive to bind the formulation to the seeds, a pigment to indicate whether or not any particular batch of seed has been treated, an insecticide and a bird-repellent.
Illustrative of wettable powders falling within the scope of the invention are those having the following composition: Wettable Powders % by weight Pyrimidine methanol 2.5 to 15 Maneb 20 to 40 Insecticide 0 to 25 Bird-repellent 0 to 25 Wetting agent(s) 2 to 10 Dispersing agent 0 to 10 Anticaking 1 to 10 Adhesive 0 to 5 Pigment 0 to 5 Inert(s) to 100 Illustrative of dust formulations of value in the invention are those having the following compositions: Dust % by weight Pyrimidine methanol 2.5 to 20 Maneb 20 to 40 Insecticide 0 to 25 Bird-repellent 0 to 25 Surfactant(s) 0 to 10 Oil 0 to 10 Pigment 0 to 5 Inert(s) to 100 The following non-limitative specific examples are given to further illustrated the invention. In these examples, CCPM represents the compound a-(2-chlorophenyl)-a-(4chlorophenyl)-5-pyrimidine methanol and CFPM represents the compound a-(2 chlorophenyl)-a-4-fluornphenyl)-5-pyn.midine methanol.Examples 1 to 3 illustrate embodiments of wettable powders whereas Examples 4 and 5 are concerned with dust formulations.
EXAMPLE 1 % by weight CFPM 8 Maneb 32 Sodium alpha olefin sulphonate 5 Sodium lignin sulphonate 5 Silica 5 Kaolin 45 EXAMPLE 2 % by weight CFPM 6.5 Maneb 26.5 Lindane* 16.5 Sodium alkyl aryl sulphonate 2 Silica 1.5 Polyvinyl pyrrolidone 1 Kaolin 46 EXAMPLE 3 % by weight CCPM 6.5 Maneb 26.5 Lindane* 16.5 Anthraquinone 16.5 Sodium N-alkyl-N-palmitoyltaurate 5 Sodium lignin sulphonate 5 Silica 5 Permanent red 4 Kaolin 15 *Lindane is the generic name for y-1,2,3,4,5,6,-hexachlorocyclohexane.
In the above Examples 1 to 3, the active ingredients are reduced in size by conventional means and then blended with the other ingredients in conventional mixing equipment. The blend is then milled in a fluid energy mill to a size range from 1 to 10 microns. The mixture is then reblended and deaerated prior to packaging.
EXAMPLE 4 % by weight CFPM 10 MANEB 40 10 W Motor oil 1 Red iron oxide 5 Talc 44 EXAMPLE 5 % by weight CCPM 20 Maneb 40 Alkyl phenol ethylene oxide condensate 4 Permanent red 4 Talc 32 In Examples 4 and 5, the active ingredients are reduced in size by conventional means and then blended with other ingredients, the oil or surfactant being sprayed into the blend.
The mixture is then milled to give particles of sizes from 5 - 50 microns. The mixture is reblended and deaerated prior to packaging.
The formulation of Example 1 when applied as a seed dressing in connection with the control of Septoria (Leptosphaeria nodorum) in wheat gave a synergistic effect.
WHAT WE CLAIM IS: 1. A combination of [[1,2-ethanediylbis[carbamodithioato]](2-)]-manganese and a pyrimidine methanol of formula (I)
where X is chlorine or fluorine.
2. A combination according to claim 1 wherein the ratio of pyrimidine methanol maneb is in the range 1 : 2 to 1 : 32.
3. A combination according to claim 2 wherein the ratio is in the range 1: 6 to 1: 8.
4. A fungicidal formulation comprising a combination as claimed in Claim 1 to 3 associated with a non-phytotoxic, inert carrier therefor.
5. A formulation according to claim 4 which comprises 5-90% active ingredients.
6. A formulation according to claim 4 or 5 which is a wettable powder or dust.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (7)

  1. **WARNING** start of CLMS field may overlap end of DESC **.
    In the above Examples 1 to 3, the active ingredients are reduced in size by conventional means and then blended with the other ingredients in conventional mixing equipment. The blend is then milled in a fluid energy mill to a size range from 1 to 10 microns. The mixture is then reblended and deaerated prior to packaging.
    EXAMPLE 4 % by weight CFPM 10 MANEB 40
    10 W Motor oil 1 Red iron oxide 5 Talc 44 EXAMPLE 5 % by weight CCPM 20 Maneb 40 Alkyl phenol ethylene oxide condensate 4 Permanent red 4 Talc 32 In Examples 4 and 5, the active ingredients are reduced in size by conventional means and then blended with other ingredients, the oil or surfactant being sprayed into the blend.
    The mixture is then milled to give particles of sizes from 5 - 50 microns. The mixture is reblended and deaerated prior to packaging.
    The formulation of Example 1 when applied as a seed dressing in connection with the control of Septoria (Leptosphaeria nodorum) in wheat gave a synergistic effect.
    WHAT WE CLAIM IS: 1. A combination of [[1,2-ethanediylbis[carbamodithioato]](2-)]-manganese and a pyrimidine methanol of formula (I)
    where X is chlorine or fluorine.
  2. 2. A combination according to claim 1 wherein the ratio of pyrimidine methanol maneb is in the range 1 : 2 to 1 : 32.
  3. 3. A combination according to claim 2 wherein the ratio is in the range 1: 6 to 1: 8.
  4. 4. A fungicidal formulation comprising a combination as claimed in Claim 1 to 3 associated with a non-phytotoxic, inert carrier therefor.
  5. 5. A formulation according to claim 4 which comprises 5-90% active ingredients.
  6. 6. A formulation according to claim 4 or 5 which is a wettable powder or dust.
  7. 7. A method of treating cereal seeds to reduce the incidence or severity of fungal
    infections in the cereal crop grown therefrom which comprises applying a combination as claimed in Claims 1-3, or a formulation as claimed in Claims 4-6, to said cereal seeds.
GB37251/77A 1977-09-07 1977-09-07 Fungicidal combinations Expired GB1597363A (en)

Priority Applications (35)

Application Number Priority Date Filing Date Title
GB37251/77A GB1597363A (en) 1977-09-07 1977-09-07 Fungicidal combinations
IE1685/78A IE47245B1 (en) 1977-09-07 1978-08-21 Fungicidal combinations
CA309,834A CA1090247A (en) 1977-09-07 1978-08-22 Fungicidal combinations
NZ188229A NZ188229A (en) 1977-09-07 1978-08-23 Fungicidal compositions containing (1,2-ethanediylbis (carbamo dithioato)) (2)-manganese and a primidyl methanol
IL7855441A IL55441A0 (en) 1977-09-07 1978-08-25 Novel synergistic fungicidal compositions comprising a pyrimidyl-methanol derivative
GR57104A GR63167B (en) 1977-09-07 1978-08-28 Fungicidal combinations
ZA00784883A ZA784883B (en) 1977-09-07 1978-08-28 Fungicidal combinations
TR20300A TR20300A (en) 1977-09-07 1978-08-29 FUNGISID COMPOSITIONS
FI782685A FI61608C (en) 1977-09-07 1978-09-01 FUNGICIDKOMPOSITIONER
IN961/CAL/78A IN149680B (en) 1977-09-07 1978-09-01
AR273534A AR218330A1 (en) 1977-09-07 1978-09-01 A COMBINATION OF ((1,2-ETHANODIYLBIS (CARBAMODITIOATE)) (2)) - MANGANESE AND A PIRIMIDIN-METHANOL AND A FUNGICIDE FORMULATION CONTAINING IT FOR THE TREATMENT OF CEREAL SEEDS IN ORDER TO REDUCE THE INCIDENCE OR SEVERITY OF INFECTION FUNGICIDES IN THE CULTIVATION OF CEREALS FROM THE SAME
FR7825298A FR2402409A1 (en) 1977-09-07 1978-09-01 FUNGICIDE COMPOSITION AND FUNGICIDE TREATMENT METHOD FOR CROPS
BG7840814A BG32111A3 (en) 1977-09-07 1978-09-04 Fungicide composition
IT50962/78A IT1106132B (en) 1977-09-07 1978-09-04 FUNGICIDE COMPOSITION PARTICULARLY EFFECTIVE FOR THE APPLICATION OF A SEED LINE
DK391378A DK156753C (en) 1977-09-07 1978-09-05 FUNGICIDE AGENT CONTAINING A MIXTURE OF ((1,2-ETHAN-DIYLBIS (CARBAMODITHIOATO)) (2 -)) - MANGANE AND A PYRIMIDINE METHANOL, AND PROCEDURES FOR REDUCING FUNGUS INFECTIONS IN CORN CROPS
DE19782838575 DE2838575A1 (en) 1977-09-07 1978-09-05 MIXTURE, FUNGICIDE AGENT CONTAINING IT AND USE THEREOF TO TREAT GRAIN SEEDS
CH933078A CH634462A5 (en) 1977-09-07 1978-09-05 Fungicidal composition and process for the fungicidal treatment of crops
BE6046599A BE870237A (en) 1977-09-07 1978-09-05 FUNGICIDE COMPOSITION AND FUNGICIDE TREATMENT METHOD FOR CROPS
CS785753A CS207667B2 (en) 1977-09-07 1978-09-05 Fungicide means
BR7805811A BR7805811A (en) 1977-09-07 1978-09-05 FUNGICIDE FORMULATION AND PROCESS TO TREAT CEREAL SEEDS
SE7809387A SE447441B (en) 1977-09-07 1978-09-06 FUNGICIDAL AGENT IN THE FORM OF A COMBINATION OF / / 1,2-ETHANETYLBIS / CARBAMODITIOATO // (2-) / MANGANE AND A PYRIMIDINE METHANOL AND USE THEREOF
PH21574A PH14333A (en) 1977-09-07 1978-09-06 Fungicidal compositions
JP10954378A JPS5452727A (en) 1977-09-07 1978-09-06 Fungicidal composition
AU39616/78A AU526357B2 (en) 1977-09-07 1978-09-06 Fungicidal combinations
HU78LI332A HU180831B (en) 1977-09-07 1978-09-06 Fungicide compositions containing synergetic combination of manganege-ethylene-bis/dithiocarbamate/ and of a pyrmidine-methanol derivative
SU782658657A SU816390A3 (en) 1977-09-07 1978-09-06 Fungicidic composition
UA2658657A UA6333A1 (en) 1977-09-07 1978-09-06 Fungicidal composition
NO783044A NO147091C (en) 1977-09-07 1978-09-06 FUNGICID PREPARATION INCLUDING A MIXTURE OF ((1,2-ETHANETYLBIS (CARBAMODITIOATOL)) (2 -)) - MANGANE AND A PYRIMIDINE METHANOL COMPOUND
NL7809096A NL7809096A (en) 1977-09-07 1978-09-06 FUNGICIDE MIXTURES.
PL1978209466A PL111723B1 (en) 1977-09-07 1978-09-07 Fungicide
MX787381U MX5503E (en) 1977-09-07 1978-09-07 PROCEDURE FOR PREPARING A FUNGICIDE COMPOSITION
ES473293A ES473293A1 (en) 1977-09-07 1978-09-07 Fungicidal combinations
JO1978983A JO983B1 (en) 1977-09-07 1978-09-07 Fungicidal combinations
DD78207689A DD138593A5 (en) 1977-09-07 1978-09-07 FUNGICIDES AND METHOD FOR THE PRODUCTION THEREOF
AT647578A AT361248B (en) 1977-09-07 1978-09-07 FUNGICIDE AGENT

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB37251/77A GB1597363A (en) 1977-09-07 1977-09-07 Fungicidal combinations

Publications (1)

Publication Number Publication Date
GB1597363A true GB1597363A (en) 1981-09-09

Family

ID=10394975

Family Applications (1)

Application Number Title Priority Date Filing Date
GB37251/77A Expired GB1597363A (en) 1977-09-07 1977-09-07 Fungicidal combinations

Country Status (35)

Country Link
JP (1) JPS5452727A (en)
AR (1) AR218330A1 (en)
AT (1) AT361248B (en)
AU (1) AU526357B2 (en)
BE (1) BE870237A (en)
BG (1) BG32111A3 (en)
BR (1) BR7805811A (en)
CA (1) CA1090247A (en)
CH (1) CH634462A5 (en)
CS (1) CS207667B2 (en)
DD (1) DD138593A5 (en)
DE (1) DE2838575A1 (en)
DK (1) DK156753C (en)
ES (1) ES473293A1 (en)
FI (1) FI61608C (en)
FR (1) FR2402409A1 (en)
GB (1) GB1597363A (en)
GR (1) GR63167B (en)
HU (1) HU180831B (en)
IE (1) IE47245B1 (en)
IL (1) IL55441A0 (en)
IN (1) IN149680B (en)
IT (1) IT1106132B (en)
JO (1) JO983B1 (en)
MX (1) MX5503E (en)
NL (1) NL7809096A (en)
NO (1) NO147091C (en)
NZ (1) NZ188229A (en)
PH (1) PH14333A (en)
PL (1) PL111723B1 (en)
SE (1) SE447441B (en)
SU (1) SU816390A3 (en)
TR (1) TR20300A (en)
UA (1) UA6333A1 (en)
ZA (1) ZA784883B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1143721B (en) * 1977-12-01 1986-10-22 Sipcam Spa FUNGICIDAL COMPOSITION FOR THE FIGHT AGAINST PLANT DISEASES

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1561634A (en) * 1975-10-29 1980-02-27 Lilly Industries Ltd Fungicidal compositions

Also Published As

Publication number Publication date
CS207667B2 (en) 1981-08-31
AU526357B2 (en) 1983-01-06
IT7850962A0 (en) 1978-09-04
HU180831B (en) 1983-04-29
PL209466A1 (en) 1979-06-04
ATA647578A (en) 1980-07-15
FI61608C (en) 1982-09-10
AR218330A1 (en) 1980-05-30
IT1106132B (en) 1985-11-11
NO783044L (en) 1979-03-08
JO983B1 (en) 1979-12-01
BG32111A3 (en) 1982-05-14
FI782685A (en) 1979-03-08
SU816390A3 (en) 1981-03-23
IE781685L (en) 1979-03-07
FR2402409A1 (en) 1979-04-06
DK391378A (en) 1979-03-08
FI61608B (en) 1982-05-31
AU3961678A (en) 1980-03-13
TR20300A (en) 1981-01-07
DK156753C (en) 1990-02-26
BR7805811A (en) 1979-04-24
NL7809096A (en) 1979-03-09
ZA784883B (en) 1979-08-29
GR63167B (en) 1979-09-26
IL55441A0 (en) 1978-10-31
DE2838575A1 (en) 1979-03-08
FR2402409B1 (en) 1983-04-22
NZ188229A (en) 1981-05-01
MX5503E (en) 1983-09-05
IN149680B (en) 1982-03-13
JPS5452727A (en) 1979-04-25
AT361248B (en) 1981-02-25
PH14333A (en) 1981-05-29
PL111723B1 (en) 1980-09-30
CH634462A5 (en) 1983-02-15
UA6333A1 (en) 1994-12-29
DE2838575C2 (en) 1988-06-01
DD138593A5 (en) 1979-11-14
SE447441B (en) 1986-11-17
IE47245B1 (en) 1984-01-25
DK156753B (en) 1989-10-02
BE870237A (en) 1979-03-05
NO147091C (en) 1983-02-02
ES473293A1 (en) 1979-10-16
CA1090247A (en) 1980-11-25
NO147091B (en) 1982-10-25
SE7809387L (en) 1979-03-08

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
704A Declaration that licence is not available as of right for an excepted use (par. 4a/1977)
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19950531