GB1592341A - Dry bearing material - Google Patents

Dry bearing material Download PDF

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Publication number
GB1592341A
GB1592341A GB2482/78A GB248278A GB1592341A GB 1592341 A GB1592341 A GB 1592341A GB 2482/78 A GB2482/78 A GB 2482/78A GB 248278 A GB248278 A GB 248278A GB 1592341 A GB1592341 A GB 1592341A
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United Kingdom
Prior art keywords
layer
bearing material
ptfe
dry bearing
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2482/78A
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Karl Schmidt GmbH
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Karl Schmidt GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Karl Schmidt GmbH filed Critical Karl Schmidt GmbH
Publication of GB1592341A publication Critical patent/GB1592341A/en
Expired legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/20Sliding surface consisting mainly of plastics
    • F16C33/201Composition of the plastic
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0094Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with organic materials as the main non-metallic constituent, e.g. resin

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Sliding-Contact Bearings (AREA)

Description

(54) DRY BEARING MATERIAL (71) We, KARL SCHMIDT GmbH, a body corporate organised under the laws of the German Federal Republic, of Christian-Schmidt Strasse 8/12, 7107 Neckarsulm, German Federal Republic, do hereby declare the invention for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement: This invention relates to a dry bearing material.
Polytetrafluoroethylene, hereinafter abbreviated to PTFE, possesses, in a unique manner, very advantageous properties, including low frictional resistance, a large temperature working range of-200 to +2800C, chemical inertness and absolute resistance to solvents and water, which properties make it useful as a dry bearing material.
However, the use of PTFE as a massive bearing material is restricted to low loadings because of the low strength, high thermal expansion and low thermal conductivity of PTFE. A further reason for the limited use of PTFE is its high price.
It has been proposed to produce a plain bearing by applying a layer of PTFE on to the surface of a porous metallic structure produced by sintering metallic powder and forcing the PTFE into at least the surface pores of the metallic structure by the application of pres sure. In producing such a bearing a copper-tinlead of e.g. 80: 10: 10 composition is applied on to a copper-plated steel strip and sintered to produce a porous structure the pores of which are filled to a depth of at least 0.762 to 1.016 mm. with PTFE.
A dry bearing material has been also pro posed in which a porour layer of tin bronze is sintered on to a copper-plated steel back and the pores are filled up with a mixture of PTFE and lead powder, there additionally being present a covering layer of the same mixture (ATZ 62 , 6, 1960, pp. 154-157). In this dry bearing material, the remarkable dry running properties of PTFE are combined with the good properties of s self-lubricating metal bearing in regard to good thermal con ductivity and low thermal expansion as well as high loading capacity.
During the short running-in period, of a journal or like member in a dry bearing of the dry bearing material, some of the covering layer of PTFE-lead mixture is transferred to the surface of the journal or the like, and unevennesses are thus equalised, a running surface with low co-efficient of friction and low wear being formed. During this running-in, the bearing surface frequently assumes a greygreen colour and covering-layer material present in excess is worn away in extremely fine particles. After the running-in, the surface of the journal or the like slides on the porous metallic carrier layer and the pore-filling mixture of PTFE and lead powder immediately again forms a film as a result of the higher expansion coefficient, whereby in this previously proposed dry bearing material the low wear and the low coefficient of friction are achieved.
In view of the aim further to lower the repair costs and energy costs, e.g. in general mechanical engineering and plant construction, in vehicle and aircraft construction, as well as in electrical appliance manufacture and in precision instrument technology, dry bearing materials are today demanded which have a still lower wear and coefficient of friction.
It is therefore an object of the present invention to take account of these criteria but in particular without negatively influencing the loading capacity.
According to the present invention there is provided a dry bearing material, wherein the material comprises a metallic supporting layer on to which is sintered a porous metallic carrier layer which is 0.1 to 0.5 mm. thick and which consists of an alloy of the composition 0.5 to 50% by weight of lead and 0.5 to 20% by weight of tin, the remainder being copper, the metallic supporting layer comprising a metallic backing layer and a metallic inter mediate layer arranged between the backing layer and the carrier layer, and wherein the pores of the carrier layer and filled completely with a mateiral comprising PTFE alone or mixed with one or more substances which improve the sliding and a layer of such material is present in a thickness of up to 50 um over the carrier layer.
Preferably, the alloy is composed of S to 25% by weight of lead and 5 to 15% of tin, the remainder being copper.
The present dry bearing material is an improvement over the previously proposed material because the lead incorporated in the individual particles of the porous sintered carrier layer is available in extremely finely divided form as additional lubricant during contact of the surface of the joumal or the like with the carrier layer, and, as a result, the coefficient of friction and wear are considerably reduced.
The metallic intermediate layer preferably consists of copper, and may be plated onto the backing layer.
The PTFE which fills the pores of the carrier layer and which is present in a thickness of up to 50 pm over the carrier layer may, if desired, contain one or more substances which improve the sliding properties, such as molybdenum sulphide (MoS2), graphite, lead monoxide (PbO), a polyamide, a polyimide or a microencapsulated lubricant. The PTFE may contain up to 20% by weight of one or more of said substances, but, in the case where a polyamide or polyimide is present, the proportion thereof may be larger than the proportion of PTFE.
Comparative experiments between slide bearings consisting of the previously proposed dry bearing material and slide bearings made from a dry bearing material according to the present invention have shown that the life of the dry bearing material according to the present invention is greater by more than 100%.
Plain bearing bushes to be compared made of the aforesaid previously proposed dry bearing material comprised an approximately 030 mm thick layer of tin bronze powder porously sintered on to a steel backing layer which had been copper-plated to provide an intermediate layer of copper. The pores had been completely filled up in a rolling process with a mixture of PTFE (80% by volume) and lead powder (20% by volume), and there was additionally present thereon an approximately 20 pm thick covering layer of the same mixture.
Part of a plain bearing bush made of the dry bearing material according to the invention, is shown diagrammatically in cross-section in Figure 1 of the accompanying drawings, (the intermediate layer not being shown), and, in contrast to the prior art, instead of the porous tin bronze layer there is sintered on to the copper-plated steel back 2 a porous carrier layer 1 consisting of 10% by weight of lead and 10% by weight of tin, the remainder copper, the pores being filled with the aforesaid PTFE-lead powder mixture 3, which also forms a covering layer.
In carrying out experiments to compare the two plain bearing bushes, a slide speed v of 1.5 m/s and a specific loading of 33.5 N/cm2 were used.
Figure 2 of the accompanying drawings shows the average values of running time L, total wear G, wear per hour V and coefficient of friction R from experiments with, in each case, (a) 10 plain bearing bushes according to the prior art and (b) 10 plain bearing bushes according to the invention contrasted in the form of column diagrams, all values being expressed as percentages.
The same total wear, comprising wear during running-in and operational wear, has been chosen as a reference basis.
The dry slide bearings according to the invention showed, in comparison with the dry slide bearings according to the prior art, a running time higher by 187%, a wear per hour lower by 64% and a coefficient of friction lower by 20%.
WHAT WE CLAIM IS: 1. A dry bearing material, wherein the material comprises a metallic supporting layer on to which is sintered a porous metallic carrier layer which is 0.1 to 0.5 mm. thick and which consists of an alloy of the composition 0.5 to 50% by weight of lead and 0.5 to 20% by weight of tin, the remainder being copper, the metallic supporting layer comprising a metallic backing layer and a metallic intermediate layer arranged between the backing layer and the carrier layer, and wherein the pores of the carrier layer are filled completely with a material comprising PTFE alone or mixed with one or more substances which improve the sliding and a layer of such material is present in a thickness of up to 50 calm over the carrier layer.
2. A dry bearing material as claimed in Claim 1, wherein the carrier layer consists of an alloy of the composition 5 to 25% by weight of lead and 5 to 15% by weight of tin, the remainder being copper.
3. A dry bearing material as claimedin Claim 1 or 2, wherein the intermediate layer is plated onto the backing layer.
4. A dry bearing material as claimed in Claim 3, wherein the intermediate layer is copper.
5. A dry bearing material as claimed in any one of Claims 1 to 4, wherein the material(s) present in the PTFE to improve the sliding is (are) selected from molybdenum sulphide, graphite, lead monoxide, a polyamide, a polyimide or a micro-encapsulated lubricant.
6. A dry bearing material as claimed in Claim 5, wherein the PTFE contains up to 20% by weight of one or more of said material(s) to improve the sliding.
7. A dry bearing material as claimed in Claim 5, wherein the proportion of polyamide or of polyimide is larger than the proportion of PTFE.
8. A dry bearing material in accordance with Claim 1 substantially as hereinbefore described with reference to the accompanying drawings.
9. A bearing made with the dry bearing material claimed in any preceding claim.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (9)

**WARNING** start of CLMS field may overlap end of DESC **. Preferably, the alloy is composed of S to 25% by weight of lead and 5 to 15% of tin, the remainder being copper. The present dry bearing material is an improvement over the previously proposed material because the lead incorporated in the individual particles of the porous sintered carrier layer is available in extremely finely divided form as additional lubricant during contact of the surface of the joumal or the like with the carrier layer, and, as a result, the coefficient of friction and wear are considerably reduced. The metallic intermediate layer preferably consists of copper, and may be plated onto the backing layer. The PTFE which fills the pores of the carrier layer and which is present in a thickness of up to 50 pm over the carrier layer may, if desired, contain one or more substances which improve the sliding properties, such as molybdenum sulphide (MoS2), graphite, lead monoxide (PbO), a polyamide, a polyimide or a microencapsulated lubricant. The PTFE may contain up to 20% by weight of one or more of said substances, but, in the case where a polyamide or polyimide is present, the proportion thereof may be larger than the proportion of PTFE. Comparative experiments between slide bearings consisting of the previously proposed dry bearing material and slide bearings made from a dry bearing material according to the present invention have shown that the life of the dry bearing material according to the present invention is greater by more than 100%. Plain bearing bushes to be compared made of the aforesaid previously proposed dry bearing material comprised an approximately 030 mm thick layer of tin bronze powder porously sintered on to a steel backing layer which had been copper-plated to provide an intermediate layer of copper. The pores had been completely filled up in a rolling process with a mixture of PTFE (80% by volume) and lead powder (20% by volume), and there was additionally present thereon an approximately 20 pm thick covering layer of the same mixture. Part of a plain bearing bush made of the dry bearing material according to the invention, is shown diagrammatically in cross-section in Figure 1 of the accompanying drawings, (the intermediate layer not being shown), and, in contrast to the prior art, instead of the porous tin bronze layer there is sintered on to the copper-plated steel back 2 a porous carrier layer 1 consisting of 10% by weight of lead and 10% by weight of tin, the remainder copper, the pores being filled with the aforesaid PTFE-lead powder mixture 3, which also forms a covering layer. In carrying out experiments to compare the two plain bearing bushes, a slide speed v of 1.5 m/s and a specific loading of 33.5 N/cm2 were used. Figure 2 of the accompanying drawings shows the average values of running time L, total wear G, wear per hour V and coefficient of friction R from experiments with, in each case, (a) 10 plain bearing bushes according to the prior art and (b) 10 plain bearing bushes according to the invention contrasted in the form of column diagrams, all values being expressed as percentages. The same total wear, comprising wear during running-in and operational wear, has been chosen as a reference basis. The dry slide bearings according to the invention showed, in comparison with the dry slide bearings according to the prior art, a running time higher by 187%, a wear per hour lower by 64% and a coefficient of friction lower by 20%. WHAT WE CLAIM IS:
1. A dry bearing material, wherein the material comprises a metallic supporting layer on to which is sintered a porous metallic carrier layer which is 0.1 to 0.5 mm. thick and which consists of an alloy of the composition 0.5 to 50% by weight of lead and 0.5 to 20% by weight of tin, the remainder being copper, the metallic supporting layer comprising a metallic backing layer and a metallic intermediate layer arranged between the backing layer and the carrier layer, and wherein the pores of the carrier layer are filled completely with a material comprising PTFE alone or mixed with one or more substances which improve the sliding and a layer of such material is present in a thickness of up to 50 calm over the carrier layer.
2. A dry bearing material as claimed in Claim 1, wherein the carrier layer consists of an alloy of the composition 5 to 25% by weight of lead and 5 to 15% by weight of tin, the remainder being copper.
3. A dry bearing material as claimedin Claim 1 or 2, wherein the intermediate layer is plated onto the backing layer.
4. A dry bearing material as claimed in Claim 3, wherein the intermediate layer is copper.
5. A dry bearing material as claimed in any one of Claims 1 to 4, wherein the material(s) present in the PTFE to improve the sliding is (are) selected from molybdenum sulphide, graphite, lead monoxide, a polyamide, a polyimide or a micro-encapsulated lubricant.
6. A dry bearing material as claimed in Claim 5, wherein the PTFE contains up to 20% by weight of one or more of said material(s) to improve the sliding.
7. A dry bearing material as claimed in Claim 5, wherein the proportion of polyamide or of polyimide is larger than the proportion of PTFE.
8. A dry bearing material in accordance with Claim 1 substantially as hereinbefore described with reference to the accompanying drawings.
9. A bearing made with the dry bearing material claimed in any preceding claim.
GB2482/78A 1977-01-22 1978-01-20 Dry bearing material Expired GB1592341A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772702599 DE2702599A1 (en) 1977-01-22 1977-01-22 DRY STORAGE MATERIAL

Publications (1)

Publication Number Publication Date
GB1592341A true GB1592341A (en) 1981-07-08

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ID=5999299

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Application Number Title Priority Date Filing Date
GB2482/78A Expired GB1592341A (en) 1977-01-22 1978-01-20 Dry bearing material

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DE (1) DE2702599A1 (en)
FR (1) FR2378203A1 (en)
GB (1) GB1592341A (en)
IT (1) IT7819349A0 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000028226A1 (en) * 1998-11-10 2000-05-18 Ks Gleitlager Gmbh Rolled-up plain bearing bush

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3027409A1 (en) * 1980-07-19 1982-02-25 Karl Schmidt Gmbh, 7107 Neckarsulm COMPOSITE SLIDE BEARING MATERIAL
IT1178784B (en) * 1984-12-21 1987-09-16 Samim Soc Azionaria Minero Met COMPOSITE MATERIAL
US4868066A (en) * 1987-10-19 1989-09-19 Macdermid, Incorporated Mechanically plated coatings containing lubricant particles
DE19506684A1 (en) * 1995-02-25 1996-09-05 Glyco Metall Werke Self-lubricating bearing material and plain bearing with such a bearing material

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3969232A (en) * 1974-01-25 1976-07-13 Sargent Industries, Inc. Bearing and bearing liner wear resistant compliant layer
DE2601647A1 (en) * 1975-01-20 1976-07-22 Garlock Inc BEARING DIMENSIONS, SLIDING BEARINGS AND METHOD OF MANUFACTURING THEREOF

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000028226A1 (en) * 1998-11-10 2000-05-18 Ks Gleitlager Gmbh Rolled-up plain bearing bush
DE19851759C2 (en) * 1998-11-10 2000-10-12 Ks Gleitlager Gmbh Rolled plain bearing bush
US6464396B1 (en) 1998-11-10 2002-10-15 Ks Gleitlager Gmbh Rolled-up plain bearing bush

Also Published As

Publication number Publication date
IT7819349A0 (en) 1978-01-18
FR2378203A1 (en) 1978-08-18
DE2702599A1 (en) 1978-07-27

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years

Effective date: 19980119