GB1571809A

GB1571809A - Method and apparatus for combusting cabronaceous fuel

Info

Publication number: GB1571809A
Application number: GB5387576A
Authority: GB
Original assignee: Engelhard Minerals and Chemicals Corp
Current assignee: Engelhard Minerals and Chemicals Corp
Priority date: 1975-12-29
Filing date: 1976-12-23
Publication date: 1980-07-16
Also published as: MX4352E; ES454623A1; SE424226B; AR220311A1; SE7614588L; CA1073334A; DE2659225A1; IT1075234B; AU506873B2; BE849927A; JPS5284309A; BR7608734A; ES465675A1; CH615008A5; AU2089976A; FR2337306B1; FR2337306A1

Abstract

To ensure that the process is flexible with respect to the fuels which can be used and that also the utilisation of, for example, sulphur-containing fuels is possible, the process operates as follows: A first mixture (18) of carbonaceous fuel (10) and air (14) is burned in the presence of a catalyst (25) under at least approximately adiabatic conditions. The catalyst (25) operates at a temperature which is above the instantaneous auto-ignition temperature of the first mixture (18) but below a temperature at which a noticeable formation of nitrogen oxides would take place. The waste gas from this combustion is mixed with a fuel-containing component (32) other than the first mixture (18), and the mixture (40) is homogeneously burned in order to produce a waste gas (50) which can be used as an energy source. The fuel in the said fuel-containing component (32) can - in contrast to the fuel (10) in the first mixture (18) - also be a fuel which would poison the catalyst and/or which is difficult to vaporise and to mix with air. The process is intended especially for producing a hot waste gas for use as a heat source (for example in an oven) or as an energy source (for example in a turbine installation). <IMAGE>

Description

(54) METHOD AND APPARATUS FOR COMBUSTING CARBONACEOUS FUEL (71) We, ENGELHARD MINERALS & CHEMICALS CORPORATION, of 70 Wood Avenue South, Metro Park Plaza, Iselin, New Jersey, United States of America, formerly of 430 Mountain Avenue, Murray Hill, New Jersey, United States of America, a corporation organized under the laws of the State of Delaware, one of the United States of America, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement::- This invention relates to a method and apparatus for combusting carbonaceous fuels, and more particularly to methods and apparatus for combusting carbonaceous fuels to produce a hot gaseous effluent for use as a source of heat (e.g. in a fumace) or power (e.g. as a motive fluid in a turbine system).

In U.S. Patent No. 3,928,961, there is disclosed a process designated catalyticallysupported, thermal combustion. According to this method, carbonaceous fuels can be combusted very efficiently and at thermal reaction rates in the presence of a solid oxidation catalyst at temperatures below nitrogen-oxideforming temperatures.

As described in U.S. Patent No. 3,928,961, this combustion method involves essentially adiabatic combustion of a mixture of fuel and air, or of fuel, air, and inert gases, in the presence of a catalyst operating at a temperature substantially above the instantaneous auto-ignition temperature of the mixture, but below a temperature that would result in any substantial formation of oxides of nitrogen.

Essentially adiabatic combustion means that the operating temperature of the catalyst does not differ by more than about 300"F, more typically no more than about 1500F, from the adiabatic flame temperature of the mixture due to heat losses from the catalyst. The instantaneous auto-ignition temperature of the mixture is defined herein and in U.S.

Patent No. 3,928,961 to mean the temperature at which the ignition lag of the mixture entering the catalyst is negligible relative to the residence time in the combustion zone of the mixture undergoing combustion. Typically, the operating temperature of the catalyst is in the range from about 1,7000 to about 3,200 F, preferably from about 2,000 to about 3,0000F. As pointed out in U.S. Patent No. 3,928,961, the combustion occurs under these conditions at a rate substantially higher than the conventional catalytic combustion rate. Combustion of the gases exiting from the catalyst zone may be substantially complete, or combustion may continue downstream of the zone containing the catalyst.

According to the present invention, there is provided a method of combusting carbonaceous fuel, which comprises the steps of providing a first mixture of carbonaceous fuel and air; passing the first mixture to a catalyst for combustion of at least a portion thereof under essentially adiabatic conditions, the catalyst operating at a temperature substantially above the "instantaneous auto-ignition temperature" (as defined herein) of the first mixture but below a temperature effecting substantial formation of nitrogen oxides, to obtain a first gaseous effluent; providing a second carbonaceous fuel-containing component comprising a high energy fuel, differing at least in proportions from the first mixture, the fuel in the fuel-containing component having a potential adiabatic flame temperature of at least about 3,300 F upon burning with a stoichiometric amount of air; and admixing the first effluent and the fuel-containing component in proportions such as to form a second mixture having a temperature at least sufficient to sustain homogeneous combustion of the second mixture and an adiabatic flame temperature substantially above the temperature of the first effluent but below about 3,7000 F, thereby homogeneously combusting the second mixture to produce a utilizable second gaseous effluent.

The present invention also provides apparatus for combusting carbonaceous fuel to produce a hot gaseous effluent, comprising means for forming a first mixture of a first carbonaceous fuel and air; a combustion chamber arranged to receive the first mixture and including extending thereacross a catalyst body having gas flow passageways therethrough for combustion of the first mixture in the presence of the catalyst under essentially adiabatic conditions to produce a first gaseous effluent; means for supplying a second fuel-containing component comprising a high energy fuel, differing at least in proportions from the first mixture; and means for mixing and thereby homogeneously combusting a second mixture formed of the first gaseous effluent and the second fuel-containing component to produce a second gaseous effluent.

In accordance with this invention, a first mixture of carbonaceous fuel and air is provided and passed to a catalyst for at least partial combustion in the presence of the catalyst under essentially adiabatic conditions, as described above, to produce a first gaseous effluent. Any of the fuels mentioned in U.S. Patent No. 3,928,961 may be used to form the first mixture and any of the fuelair proportions mentioned in that application may comprise the first mixture. Similarly, although atmospheric air will usually be the source of oxygen for combustion of the fuel in the first mixture (as well as for combustion of the additional fuel combusted in accordance with the principles of this invention), it will be understood that the term "air" is used herein to mean any gas or combination of gases including oxygen available for combustion.It will sometimes be necessary herein to refer specifically to inert or recycle gases which in various applications of the present invention can be mixed with the fuel and air being combusted; this does not mean that the gases referred to as air herein cannot also include inert gases.

The first effluent produced as described above is mixed with a second carbonaceous fuel-containing component provided for that purpose, which may be with or without nonfuel components (i.e., air), to form a second mixture. This fuel-containing component is different from the first mixture and advantageously may utilize a fuel different from the fuel used in the first mixture. The fuel in the second fuel-containing component is a high energy fuel having an adiabatic flame temperature of at least about 3,3000 F if burr.ed with a stoichiometric amount of air.

The term "stoichiometric amount of air" as used herein means the amount of air of atmospheric compcsition which is theoretically just sufficient for complete combustion of all the carbon in a given amount of fuel to carbon dioxide and for complete combustion of any hydrocarbons in the fuel to carbon dioxide and water. The foregoing statement that the fuel in the second fuel-containing component has an adiabatic flame temperature of at least about 3,300 F if burned with a stoichiometric amount of air does not mean that the fuel in the second fuel-containing component is in fact necessarily burned with a stoichiometric amount of air in the method and apparatus of this invention.

The second mixture referred to above includes oxygen available for at least partial combustion of the fuel in the second fuelcontaining component. This oxygen may be uncombined oxygen in the first effluent, or it may be air in the second fuel-containing component, or both. In addition, the second mixture has a temperature upon mixing at least sufficient to sustain homogeneous combustion of the second mixture and has an adiabatic flame temperature substantially above the temperature of the first effluent but below about 3,700 F. Typically, the adiabatic flame temperature of the second mixture is in the range from about 1,700 to about 3,7000F, preferably from about 2,5000 to about 3,3000 F. As used herein, the term "homogeneous combustion" means thermal combustion, which should be carried out with sufficiently uniform admixture of the components of the second mixture to avoid localized regions of substantially higher tem peratures than the average temperature of the combustion zone.

The second mixture is homogeneously combusted to produce a second gaseous effluent which can be used as a source of heat or power. This combustion preferably occurs at a temperature low enough, and for a residence time of the mixture in the combustion zone short enough, to avoid substan tial formation of nitrogen oxides. The com bustion of the second mixture may be sub stantially adiabatic (for example, if the second effluent is to be used as a motive fluid for a turbine), or heat may be withdrawn from the combustion zone (for example, if the system is a furnace). Additional combustion stages similar to the combustion of the second mix ture may be provided by mixing all or part of the second effluent with additional air if combustion of the second effluent is not com plete, or with additional fuel-containing com ponents with or without additional non-fuel components (e.g., air). Inert gases, such as the exhaust gases of the system, may be mixed with any of the fuel or air or both supplied to the system to improve the thermal effi ciency of the system and control temperatures in the system. Any of the gases supplied to the system may be preheated, e.g., by heat exchange with the exhaust gases of the system, by compression in a compressor (in a turbine system), or by any other means.

For a better understanding of the inven tion, reference will now be made, by way of example, to the accompanying drawings in which: Figure 1 is a partly schematic, partly simplified sectional view of combustor apparatus constructed and adapted for operation in accordance with this invention; Figure 2 is a partly schematic, partly simplified sectional view showing a turbine system including combustor apparatus constructed and adapted for operation in accordance with this invention; Figure 3 is a partly schematic, partly sectional view of a furnace constructed and adapted for operation in accordance with this invention; and Figure 4 illustrates an alternative embodiment of the furnace of Figure 3.

In the apparatus known in Figure 1, fuel is supplied via line 10 having valve 12 and air is supplied via line 14 having valve 16.

Fuel from line 10 and air from line 14 are mixed to form a first mixture of fuel and air in line 18. The amounts and proportions of fuel and air in the first mixture are respec tively controlled by valves 12 and 16 in accordance with the principles disclosed in U.S. Patent No. 3,928,961. Thus any of the fuels discussed in U.S. Patent No. 3,928,961 may be supplied via line 10 and mixed with air from line 14 in any amounts and proportions for effecting combustion at the desired operating temperature of the catalyst under the conditions existing in the combustion zone containing the catalyst. An example of a suit able fuel is propane. If desired, the air and/ or fuel can be preheated (e.g., by compression in the system compressor if the system is a turbine system, by heat exchange with the exhaust gases of the system, etc.).Similarly, if desired, inert or substantially inert gases, such as the exhaust gases of the system, can be mixed with the fuel or air or both supplied via lines 10 and 12 (or mixed with the first mixture in line 18 or introduced separately into initial mixing zone 22) for thermal efficiency and to control temperatures in combustor 20. For convenience herein, any such inert gases supplied to combustor 20 will be referred to as "recycle gases", since in many cases these gases will be a recycled portion of the exhaust gases of the system.

However, if a stream of inert or substantially inert gases is available from another source (e.g., a waste stream from another process), it will be understood that the term "recycle gases" also includes such gases.

The first mixture in line 18 is passed to combustor 20 having cylindrical housing 21, a longitudinal sectional view of which is shown in Figure 1. Although a cylindrical combustor is shown in Figure 1, it will be understood that a wide variety of shapes can be employed, depending, for example, on the nature and configuration of the system in which the combustor is used. The first mix nire is introduced into the initial portion of .ombustor 20, referred to herein as initial mixing zone 22. Although in the particular embodiment shown in Figure 1, the first mixture of fuel and air is formed in line 18 prior to initial mixing zone 22, it will be understood that the fuel and air alternatively can be introduced into initial mixing zone 22 separately and mixed in that zone to form the first mixture.Initial mixing zone 22 includes an ignitor 24 which operates as discussed in U.S. Patent No. 3,928,961 to ignite the first mixture in zone 22 to heat catalyst 25 in cataslyst-containing combustion zone 26 during start.uof the system. While ignitor 24 is operating, it may be necessary to supply fuel and air to the system in different amounts and proportions to insure a flammable mixture in zone 22 as discussed in the above-mentioned application. However, when catalyst 25 is at normal operating temperatures, ignitor 24 normally does not operate and there is preferably no combustion in initial mixing zone 22 prior to catalytic zone 26 at temperatures which would result in any substantial formation of nitrogen oxides.

The combustion zone 26 is disposed in combustor 20 downstream of the initial mixing zone 22 so that the gases in zone 22 pass through zone 26 to catalyst exit zone 28.

Zone 26 includes a catalyst 25, which in the particular embodiment shown in Figure 1 is a body disposed transverse to the longitudinal axis of combustor 20 and held in position by lugs or annular rings 27 on the inner surface of combustor housing 21. Catalyst 25 preferably occupies most or all of the flow crosssection of the combustion zone and includes a plurality of channels from initial mixing zone 22 to catalyst exit zone 28. At least a portion of the gases passing through the zone 26 containing the catalyst 25 thus are combusted in the presence of the catalyst, under the conditions described in U.S. Patent No.

3,928,961 and summarized above, to produce a first gaseous effluent. Any of the catalyst compositions and structures discussed in U.S.

Patent No. 3,928,961 may be used for solid oxidation catalyst 25. For example, catalyst 25 may be a honeycomb catalyst having a plurality of channels parallel to the longitudinal axis of combustor 20.

A particular example of catalyst 25 is, as described in U.S. Patent No. 3,928,961, a catalyst of the monolithic, honeycomb-type having a nominal 6-inch diameter and disposed within a metal housing as two separate pieces each having parallel flow channels 21 inches in length extending therethrough. There is a small space of about 41-inch between these pieces. Both pieces of catalyst have approximately 100 flow channels per square inch of cross-section with the walls of the channels having a thickness of 10 mils. The catalyst pieces have similar compositions and are composed of a zircon mullite honeycomb support which carries 2 coating of alumina containing palladium, chromia and ceria.The catalyst pieces are made by slurrying 2400 grams of activated alumina powder, less than 40 mesh in size, in a mixer with a solution prepared by dissolving 2526 grams of Cr(NO,),. 9H20 and 1382 grams of Ce(NO,), . 6H20 in 890 ml of H2O. The mixture is dried at 1200C over a weekend. The dried solids are crushed and screened to less than 40 mesh, and then the powder is calcined for 4 hours at 10000 C. Then, 3200 grams of the powder are charged to a 3.4 gallon ball mill along with 3200 ml of H20 and 145.4 grams of palladium nitrate. The mill is rolled for 17 hours at 54 RPM. The resulting slip has a density of 1.63 grams per ml, a pH of 4.20 and a viscosity of 12 centipoises.Then, 1625 grams of the as-recovered slip are diluted with 1180 ml of a 1 percent nitric acid solution.

The zircon mullite honeycomb is dipped in the diluted slip and held for one minute, and then withdrawn from the slip and blown with air to remove excess slip. The coated honeycomb is dried for 16 hours at 1100 C, and then calcined for 2 hours at 500"C. The honeycomb is cooled, and showed a pickup of 11.0 weight percent slip or coating.

The adiabatic flame temperature of the fuel air mixture extering the catalyst is in the range from about 1,7000 to about 3,2000F, preferably from about 2,0000 to about 3,000 F, so that, for the adiabatic system illustrated in Figure 1, the operating temperature of the catalyst closely approaches this adiabatic flame temperature, and, when most of the fuel is burned while in the catalyst zone 26, the first effluent may exit from the catalyst zone at a temperature somewhat less than the adiabatic flame temperatures of the entering mixture. The gases exiting from catalyst zone 26 may be completely combusted, or combustion may continue downstream of zone 26 into catalyst exit zone 28.

The first effluent passes from catalyst exit zone 28 to second mixing and combustion zone 30 where it is mixed and thermally combusted with a second fuel-containing component as will now be described. The second fuel-containing component is supplied to combustor 20 via line 40 and sprayed into second mixing and combustion zone 30 by nozzle 42 for mixing with the first effluent from catalyst exit zone 28 to produce a second mixture in zone 30. The second fuel-containing component differs in the nature, or proportion, or both, of the fuel, as compared with the first mixture entering the catalyst 25, and includes fuel supplied to line 40 via line 32 having valve 34 and may also include nonfuel components (e.g. air) supplied to line 40 via line 36 having valve 38. Examples of suitable fuels supplied via line 32 are methane, No. 2 fuel oil and No. 6 fuel oil.

As discussed in U.S. Patent No. 3,928,961, the proportions of fuel and air in the first mixture (at least partially combusted in catalyst zone 26 as discussed above) may be approximately stoichiometric if desired catalyst operating temperature is not exceeded, or the proportions may be non-stoichiometric on the fuel-rich or fuel-lean side. If the mixture is approximately stoichiometric, substantially all the fuel in the first mixture is typically combusted in catalyst zone 26 and in catalyst exit zone 28. If the first mixture is fuel-rich, there will be uncombusted fuel values in the first effluent. If the first mixture is fuel-lean, there will be oxygen in the first effluent available for combustion of additional fuel.If there is sufficient oxygen available in the first effluent for combustion of the fuel in the second fuel-containing component, additional air may not be required or desired in the second fuel-containing component. On the other hand, if there is insufficient oxygen in the first effluent for combustion of the fuel in the second fuel-containing component or if there is uncombusted fuel in the first effluent, the second fuel-containing component contains air for combustion of the fuel in the second fuel-containing component and any uncom busted fuel in the first effluent. In any event, it is preferred in accordance with the present invention that the fuel-air mixture in the second fuel-containing component, especially when the same fuel is used, be substantially richer in fuel values than the first fuel-air mixture.

The fuel supplied via line 32 may be the same as the fuel supplied via line 10 but in a different mixture with air, or it may be a different fuel. In any event, the fuel in the second fuel-containing component is a high energy fuel having an adiabatic flame tem perature of at least about 3,3000F if burned with a stoichiometric amount of air. One of the advantages of this invention is that fuel which may be inconvenient or unsuitable for combustion in the presence of the catalyst in zone 26 can be supplied via line 32 and combusted downstream of the catalyst. Thus, for example, fuels substantially contaminated with sulfur which might poison the catalyst in zone 26 can be supplied via line 32 and combusted without danger to the catalyst.

Other examples are fuels yielding combustion products with substantial ash content, and fuels having high boiling points and difficult to vaporize and admix intimately with air prior to contacting the catalyst 25 upon reaching the inlet to zone 26.

As in the case of the components supplied via lines 10 and 14, either or both of the components supplied via lines 32 and 36 can be preheated if desired by any of the means mentioned above. Similarly, recycle gases can be mixed with either or both of the components supplied via lines 32 and 36 for.

thermal efficiency and to control temperatures in combustor 20, particularly in mixing and combustion zone 30.

As mentioned above, the second fuel-containing component is mixed with the first effluent to form a second mixture in zone 30.

This second mixture has a temperature at least sufficient to sustain homogeneous combustion of the second mixture and has an adiabatic flame temperature substantially above the temperature of the first effluent but below about 3,700 F. Typically, the temperature of the second mixture upon mixing is at least about 1,700 F, preferably at least about 2,000 F, and the adiabatic flame temperature of the second mixture is in the range from about 1,700" to about 3,7000 F, preferably from about 2,5000 to about 3,3000F.

In second mixing and combustion zone 30 the second mixture is thermally combusted to produce a second gaseous effluent. Nozzle 42 may be positioned at a point where combustion of the gases exiting from the zone 26 containing the catalyst is still continuing, so that combustion is continuous from zone 28 to zone 30, or nozzle 42 may be positioned at a point where combustion of the first effluent has stopped so that there is a discontinuity in combustion from zone 28 to zone 30. The second gaseous effluent is. used as a source of heat or power. For example, heat may be withdrawn from the gases in zone 30 by heat exchange, e.g., to generate steam.

Alternatively, the combustion taking place in combustor 20 may be substantially adiabatic throughout and the second effluent may be conducted from the combustor via line 50 for transfer of heat therefrom at another location or for use as a motive fluid for a turbine. The exhausted second effluent subsequently exits from the system. Additional heat may be recovered from the exhaust gases to preheat the fuel or air or both supplied to the system as mentioned above. A portion of the exhaust gases may be mixed with the fuel or air or both supplied to the system as the above-mentioned recycle zone.

Although only one nozzle 42 is shown in the simplified schematic of Figure 1, it will be understood that any number and arrangement of such nozzles can be provided to insure effectively complete mixing of the second fuelcontaining component with the first effluent, as is desirable to insure homogeneous combustion of the resulting second mixture with reasonable uniformity of temperature in zone 30. Similarly, although additional fuel-containing component is introduced at only one location along the longitudinal axis of combustor 20 in Figure 1, it will be understood that any number of successive mixing and combustion zones similar to zone 30 can be provided along the length of the downstream portion of combustor 20 with additional fuelcontaining component supplied to each of these zones.

A turbine system constructed and operated in accordance with this invention is shown in Figure 2. Combustor 20 in this system is similar to combustor 20 in Figure 1, except thPt two successive mixing and combustion zones 30a and 30b, each similar to the mixing and combustion zone 30 in Figure 1, are provided in the combustor shown in Figure 2. In the turbine system of Figure 2, air is brought into the system via line 6 and compressed in compressor 8. Power to drive compressor 8 is supplied from turbine 52 via shaft 54. Compressed air exits from compressor 8 via line 14. Typically, the air in line 14 is at elevated temperature as well as pressure. For example, depending on the compression ratio of compressor 8, the air in line 14 may be at a temperature as high as about 1,1000 F.

At least a portion of the air in line 14 passes through valve 16 and is mixed with a portion of the fuel supplied to the system via line 10 to form a first mixture of fuel and air in line 18 similar to the first mixture in line 18 in Figure 1. The amount of fuel from line 10 going to line 18 is controlled by valve 12 as in Figure 1. The first mixture in line 18 is supplied to initial mixing zone 22 of combustor 20. From initial mixing zone 22 the first mixture passes to the catalystcontaining zone 26 and is at least partially combusted therein, as in zone 26, in Figure 1, to produce a first gaseous effluent which passes to catalyst exit zone 28.In second mixing and combustion zone 30a, the first effluent is mixed with a second fuel-containing component supplied via line 40a and nozzle 42a to form a second mixture having similar characteristics to those of the second mixture in Figure 1 and which is homogeneously combusted in zone 30a, under conditions similar to the combustion of the second mixture in Figure 1, to produce a second gaseous effluent. Fuel is supplied to line 40a from line 10 in an amount determined by valve 34a. This fuel is similar to the fuel in the second fuel-containing component in Figure 1 in that it is a high energy fuel having an adiabatic flame temperature of at least about 3,300 F if burned with a stoichiometric amount of air.In the embodiment shown in Figure 2 the same fuel is supplied throughout the system although it will be understood that different fuels can be supplied to different combustion zones if desired as discussed above in connection with Figure 1. The second fuelcontaining component in line 40a may also include air supplied from line 14 via valve 38a and mixed with the fuel in line 40a.

The second gaseous effluent is passed to third mixing and combustion zone 30b, where it is mixed with a third fuel-containing component supplied to the combustor via line 40b and nozzle 42b to produce a third mixture.

Fuel is supplied to line 40b from line 10 in an amount determined by valve 34b. Again, although this is the same fuel supplied to the other combustion zones of the system, in the particular embodiment shown in Figure 2, a different fuel may be supplied if desired.

In any event, this fuel is a high energy fuel having an adiabatic flame temperature of at least about 3,3000F if burned with a stoichiometric amount of air. The third fuel-containing component in line 40b may also include air supplied from line 14 via valve 38b and mixed with the fuel in line 40b. The third mixture formed in zone 30b also has properties similar to those of the second mixture in Figure 1.Thus the temperature of the third mixture is at least sufficient to sustain homogeneous combustion of the third mixture and has an adiabatic flame temperature at least above the temperature of the first effluent but below about 3,7000 F. As in the case of the second mixture both in Figure 1 and Figure 2, the temperature of the third mixture is typically at least about 1,700 F, preferably at least about 2,000 F, and the adiabatic flame temperature of the third mixture is in the range from about 1,7000 to about 3,7000 F, preferably from about 2,5000 to about 3,300 F. The third mixture is homogeneously combusted in zone 30b to produce a third gaseous effluent which exits from combustor 20 via line 50.

To avoid substantially or minimize sharply any formation of oxides of nitrogen in either of the thermal combustion zones 30a and 30b, especially when the adiabatic flame temperature is in the approximate range of 3,300 F to 3,7000 F, the residence time of the mixture undergoing combustion should be limited, with or without air-quenching on leaving one or both of the thermal combustion zones, since nitrogen oxide formation is a function of both time and temperature for a given combustion mixture.

The third gaseous effluent in line 50 is supplied as a motive fluid to drive turbine 52.

A portion of the power produced by turbine 52 is used to drive compressor 8 via shaft 54 as mentioned above. The remaining power is available on shaft 54 for the purpose for which the system is being operated (e.g., to drive an electrical power generator). The gases exiting from turbine 52 via line 56 are exhausted from the system, generally into the atmosphere.

A furnace system constructed and adapted for operation in accordance with the principles of this invention is shown in Figure 3.

In the system of Figure 3 a vertically disposed furnace housing 160 has a plurality of laterally extending enclosures 162 spaced around its periphery near the bottom of the housing. Although in the particular embodi ment shown in Figure 3 housing 160 is basic ally cylindrical and enclosures 162 therefore extend radially from housing 160, any of a wide variety of configurations can be employed, as will be apparent to those skilled in the art. Each of enclosures 162 is similar to the initial portion of combustor 20 in Figures 1 and 2. Each enclosure 162 there fore includes an initial mixing zone 122 similar to initial mixing zone 22 in Figures 1 and 2 and a zone 126, containing a catalyst, similar to catalyst zone 26 in Figures 1 and 2.A portion of a first mixture of fuel and air similar to the first mixture of Figure 1 and formed as described below is supplied to each of enclosures 162 and at least partly combusted in the associated catalyst zone 126 as in catalyst zone 26 in Figure 1 to produce a first gaseous effluent, which enters the lower portion 130 of the interior of housing 160 (referred to herein as second mixing and combustion zone 130). In zone 130 the first effluent from all of enclosures 162 is mixed with a second fuel-containing component formed as described below and supplied to zone 130 by diffuser 142 to produce a second mixture similar to the second mixture formed in zone 30 in Figure 1. This second mixture is homogeneously combusted in zone 130 as in zone 30 in Figure 1 to produce a second gaseous effluent.Heat is withdrawn from this second gaseous effluent as it rises in housing 160 to heat steam in a system of boiler tubes (not shown) connected between lines 174 and 176. When the second effluent is too cool for further efficient transfer of heat to the liquid water condensate being vaporized to steam in the boiler tube system, the second effluent exits from the upper portion of housing 160 via line 150. Line 150 may conduct the second effluent to succesive heat exchanges 172 and 178 for preheating respectively condensate returned to the system via line 170 and air brought into the system via line 180.

The preheated condensate is supplied to the boiler tube system associated with housing 160 via line 174 and the fully heated steam exits from that boiler tube system via line 176. The preheated air is distributed to the system via line 114. The second effluent is finally exhausted from the system via line 182.

The first mixture of fuel and air mentioned above is formed in line 118 by mixing fuel supplied via line 110 having valve 112 with air from line 114 supplied via valve 116. As mentioned above, this first mixture has the characteristics specified above for the first mixture in Figure 1. Fuel for the second fuel-containing component is supplied to diffuser 142 via line 132 having valve 134 and line 140. This fuel may be the same as that supplied via line 110 or it may be a different fuel. In any event, the fuel in the second fuel-containing component is a high energy fuel having an adiabatic flame temperature of at least about 3,300 F if burned with a stoichiometric amount of air. The second fuel-containing component may also include air supplied from line 114 via valve 138.

Figure 4 shows a modification of the furnace of Figure 3 in which a portion of the final combustion effluent of the furnace can be mixed as recycle gases with either the first mixture of fuel and air or the second fuel containing component, or both, to control temperatures in the furnace and improve the thermal efficiency of the furnace. The recycle gases help to control temperatures in the system by diluting the fuel-air mixtures with which they are mixed. Such use of these gases also may improve the thermal efficiency of the system by conserving heat values within the system which would otherwise be lost to the atmosphere. The furnace of Figure 4 is identical to the furnace of Figure 3 with the addition of line 184 for drawing off and re cycling a portion of the final combustion effluent between heat exchangers 172 and 178.

The recycle gases in line 184 are typically substantially inert since it is usually prefer able to operate a furnace with no more air in excess of the stoichiometric amount for the total amount of fuel supplied to the furnace than is actually necessary to insure complete combustion of all that fuel, although these recycle gases may contain some oxygen avail able for combustion. The recycle gases in line 184 are also typically at a temperature above ambient temperature. A portion of the recycle gases in line 184 may be supplied to line 118 via valve 186 and mixed with the first mix ture of fuel and air in line 118. Alternatively or in addition, a further portion of the recycle gases in line 184 may be supplied to line 140 via valve 188 and mixed with the second fuel containing component in line 140.

Although in the particular embodiment shown in Figure 4 the recycle gases are with drawn between heat exchanges 172 and 178, it will be understood that these gases can be withdrawn at any point (e.g., ahead of heat exchanger 172 or after heat exchanger 178).

Similarly, although the recycle gases are mixed with the first mixture and with the second fuel-containing component after tiie fuel and air have been mixed, it will be under stood that these three components can be mixed in any order. Alternativsly, any one or more of these components can be supplied to the furnace separately and mixed in the furnace (e.g., in initial mixing zones 122 in the case of the gases comprising the first mix ture or in second mixing and combustion zone 130 in the case of the gases comprising tkie second fuel-containing component).

It is to be understood that the embodiments shown and described herein are illustrative of the principles of this invention only and that various modifications may be implemented by those skilled in the art without departing from the scope and spirit of the invention. For example, although heat exchange to steam is employed in the furnace systems shown in Figures 3 and 4, heat exchange to any other medium (e.g., air) may alternatively be employed, or the furnace may comprise a pipe still with the heat being transferred directly to a fluid being processed in the still.

Attention is drawn to our Application No.

53876/76 (Serial No. 1571810), which describes and claims a method of combusting nitrogen-containing fuel while suppressing formation of oxides of nitrogen from said nitrogen contained in the fuel, comprising: forming a first mixture of said fuel and an amount of air substantially less than the amount needed for complete combustion of all the combustible components in said fuel but sufficient to support substantial combustion and said fuel; combusting said first mixture in a first combustion zone in the presence of a catalyst, having an operating temperature below a temperature that would result in any substantial formation of oxides of nitrogen or other fixed nitrogen compounds from atmospheric nitrogen present in said mixture, to form a first effluent;; admixing said first effluent with an additional amount of air at least sufficient for complete combustion of all combustible components remaining in said first effluent to form a second mixture; -and combusting said second mixture in second combustion zone below a temperature that would result in any substantial formation of oxides of nitrogen from atmospheric nitrogen.

WHAT WE CLAIM IS: 1. A method of combusting carbonaceous fuel, which comprises the steps of providing a first mixture of carbonaceous fuel and air; passing the first mixture to a catalyst for combustion of at least a portion thereof under essentially adiabatic conditions, the catalyst operating at a temperature substantially above the "instantaneous auto-ignition temperature" (as defined herein) of the first mixture but below a temperaalre effecting substantial formation of nitrogen oxides, to obtain a first gaseous effluent; providing a second carbonaceous fuel-containing component comprising a high energy fuel, differing at least in proportions from the first mixture, the fuel in the fuel-containing component having a potential adiabatic flame temperature of at least about 3,30G-v upon vuning with a stoichiometric amount of air; and admixing the first effluent

**WARNING** end of DESC field may overlap start of CLMS **.

Claims

**WARNING** start of CLMS field may overlap end of DESC **.

that supplied via line 110 or it may be a different fuel. In any event, the fuel in the second fuel-containing component is a high energy fuel having an adiabatic flame temperature of at least about 3,300 F if burned with a stoichiometric amount of air. The second fuel-containing component may also include air supplied from line 114 via valve 138.

Figure 4 shows a modification of the furnace of Figure 3 in which a portion of the final combustion effluent of the furnace can be mixed as recycle gases with either the first mixture of fuel and air or the second fuel containing component, or both, to control temperatures in the furnace and improve the thermal efficiency of the furnace. The recycle gases help to control temperatures in the system by diluting the fuel-air mixtures with which they are mixed. Such use of these gases also may improve the thermal efficiency of the system by conserving heat values within the system which would otherwise be lost to the atmosphere. The furnace of Figure 4 is identical to the furnace of Figure 3 with the addition of line 184 for drawing off and re cycling a portion of the final combustion effluent between heat exchangers 172 and 178.

The recycle gases in line 184 are typically substantially inert since it is usually prefer able to operate a furnace with no more air in excess of the stoichiometric amount for the total amount of fuel supplied to the furnace than is actually necessary to insure complete combustion of all that fuel, although these recycle gases may contain some oxygen avail able for combustion. The recycle gases in line

184 are also typically at a temperature above ambient temperature. A portion of the recycle gases in line 184 may be supplied to line 118 via valve 186 and mixed with the first mix ture of fuel and air in line 118. Alternatively or in addition, a further portion of the recycle gases in line 184 may be supplied to line 140 via valve 188 and mixed with the second fuel containing component in line 140.

Although in the particular embodiment shown in Figure 4 the recycle gases are with drawn between heat exchanges 172 and 178, it will be understood that these gases can be withdrawn at any point (e.g., ahead of heat exchanger 172 or after heat exchanger 178).

Similarly, although the recycle gases are mixed with the first mixture and with the second fuel-containing component after tiie fuel and air have been mixed, it will be under stood that these three components can be mixed in any order. Alternativsly, any one or more of these components can be supplied to the furnace separately and mixed in the furnace (e.g., in initial mixing zones 122 in the case of the gases comprising the first mix ture or in second mixing and combustion zone

130 in the case of the gases comprising tkie second fuel-containing component).

It is to be understood that the embodiments shown and described herein are illustrative of the principles of this invention only and that various modifications may be implemented by those skilled in the art without departing from the scope and spirit of the invention. For example, although heat exchange to steam is employed in the furnace systems shown in Figures 3 and 4, heat exchange to any other medium (e.g., air) may alternatively be employed, or the furnace may comprise a pipe still with the heat being transferred directly to a fluid being processed in the still.

Attention is drawn to our Application No.

53876/76 (Serial No. 1571810), which describes and claims a method of combusting nitrogen-containing fuel while suppressing formation of oxides of nitrogen from said nitrogen contained in the fuel, comprising: forming a first mixture of said fuel and an amount of air substantially less than the amount needed for complete combustion of all the combustible components in said fuel but sufficient to support substantial combustion and said fuel; combusting said first mixture in a first combustion zone in the presence of a catalyst, having an operating temperature below a temperature that would result in any substantial formation of oxides of nitrogen or other fixed nitrogen compounds from atmospheric nitrogen present in said mixture, to form a first effluent;; admixing said first effluent with an additional amount of air at least sufficient for complete combustion of all combustible components remaining in said first effluent to form a second mixture; -and combusting said second mixture in second combustion zone below a temperature that would result in any substantial formation of oxides of nitrogen from atmospheric nitrogen.

WHAT WE CLAIM IS: 1. A method of combusting carbonaceous fuel, which comprises the steps of providing a first mixture of carbonaceous fuel and air; passing the first mixture to a catalyst for combustion of at least a portion thereof under essentially adiabatic conditions, the catalyst operating at a temperature substantially above the "instantaneous auto-ignition temperature" (as defined herein) of the first mixture but below a temperaalre effecting substantial formation of nitrogen oxides, to obtain a first gaseous effluent; providing a second carbonaceous fuel-containing component comprising a high energy fuel, differing at least in proportions from the first mixture, the fuel in the fuel-containing component having a potential adiabatic flame temperature of at least about 3,30G-v upon vuning with a stoichiometric amount of air; and admixing the first effluent

and the fuel-containing component in proportions such as to form a second mixture having a temperature at least sufficient to sustain homogeneous cwmbination of the second mixture and an ad.abatic flame temperature substantially above the temperature of the first effluent but below about 3,700 F., thereby homogeneously combusting the second mixture to produce a utilizable second gaseous effluent
2. A method according to claim 1, wherein the fuel in the second carbonaceous fuelcontaining component is different from the fuel used in providing the first mixture.
3. A method according to claim 1 or 2, wherein the first mixture entering the catalyst has an adiabatic flame temperature in the range of from about 1,700"F to about 3,200 F.
4. A method according to any of claims

1 to 3, wherein the temperature of the second mixture upon mixing is at least about 1,700 F.
5. A method according to claim 4, wherein the temperature of the second mixture upon mixing is at least about 2,0000 F.
6. A method according to any of claims

1 to 5, wherein the adiabatic flame temperature of the second mixture is in the range of from about 1,7000 to about 3,7000F.
7. A method according to claim 6, wherein the adiabatic flame temperature of the second mixture is in the range of from about 2,5000 to about 3,3000 F.
8. A method according to any of claims

1 to 7, further comprising the steps of con verting a portion of the thermal energy in the second gaseous effluent to work, thereby at least partially exhausting the heat content of the second gaseous effluent.
9. A method according to claim 8, wherein a portion of the resulting second gaseous effluent is mixed with the first effluent and the fuel-containing component to form the second mixture.
10. A method according to any of claims

1 to 7, further comprising the step of withdrawing at least a portion of the thermal energy from the second gaseous effluent by transfer of heat therefrom, thereby at least partially exhausting the heat content of the second gaseous effluent.
11. A method according to claim 10, wherein a portion of the resulting second gaseous effluent is mixed with the first effluent and the fuel-containing component to form the second mixture.
12. A method according to any of claims

1 to 7, wherein the carbonaceous fuel in the first mixture and the carbonaceous fuel in the fuel-containing component are combusted to provide a motive fluid for a gas turbine, the method further comprising the step of supplying the second gaseous effluent as a motive fluid to drive the turbine.
13. A method according to any of claims 1 to 7, wherein the carbonaceous fuel in the first mixture and the carbonaceous fuel in the fuel-containing component are combusted to provide heat for the generation of steam, the method further comprising the step of transferring heat from the second gaseous effluent to a liquid water condensate to generate steam.
14. A method according to any of claims 1 to 13, wherein the carbonaceous fuel in the fuel-containing component is a fuel inconvenient or unsuitable for combustion in the presence of the catalyst and is selected from substantially sulfur-contaminated fuels, fuels yielding combustion products with substantial ash content, and high-boiling fuels difficult to vaporize with admix with air prior to contacting the catalyst
15. A method of combusting carbonaceous fuel, substantially as hereinbefore described with reference to any of Figures 1 to 4 of the accompanying drawings.
16. Apparatus for combusting carbonaceous fuel to produce a hot gaseous effluent, comprising means for forming a first mixture of a first carbonaceous fuel and air; a combustion chamber arranged to receive the first mixture and including extending thereacross a catalyst body having gas flow passageways therethrough for combustion of the first mixture in the presence of the catalyst under essentially adiabatic conditions to produce a first gaseous effluent; means for supplying a second fuel-containing component comprising a high energy fuel, differing at least in proportions from the first mixture; and means for mixing and thereby homogeneously combusting a second mixture formed of the first gaseous effluent and the second fuel-containing component to produce a second gaseous effluent.
17. An apparatus according to claim 16, further comprising means for cooling a portion of the second gaseous effluent and for mixing it with the first gaseous effluent and the fuel-containing component to form the second mixture for homogeneous combustion thereof.
18. An apparatus according to claim 16 or 17, further comprising a gas turbine, and means for supplying the second gaseous effluent to the turbine as a motive fluid.
19. Apparatus for combusting carbonaceous fuel, substantially as hereinbefore described with reference to, and as shown in, any of Figures 1 to 4 of the accompanying drawings.