GB1571106A - Ore flotation process for the recovery of fluoride minerals and rare earth carbonates - Google Patents
Ore flotation process for the recovery of fluoride minerals and rare earth carbonates Download PDFInfo
- Publication number
- GB1571106A GB1571106A GB29736/76A GB2973676A GB1571106A GB 1571106 A GB1571106 A GB 1571106A GB 29736/76 A GB29736/76 A GB 29736/76A GB 2973676 A GB2973676 A GB 2973676A GB 1571106 A GB1571106 A GB 1571106A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fluoride
- process according
- ore
- flotation
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005188 flotation Methods 0.000 title claims description 36
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title claims description 23
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims description 17
- 239000011707 mineral Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 14
- 238000011084 recovery Methods 0.000 title claims description 11
- -1 rare earth carbonates Chemical class 0.000 title claims description 10
- 229910052761 rare earth metal Inorganic materials 0.000 title claims description 10
- 229920000642 polymer Polymers 0.000 claims description 20
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 13
- 239000010428 baryte Substances 0.000 claims description 13
- 229910052601 baryte Inorganic materials 0.000 claims description 13
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 9
- 230000000994 depressogenic effect Effects 0.000 claims description 9
- 239000010436 fluorite Substances 0.000 claims description 9
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 claims description 7
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 claims description 5
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 5
- 229910052590 monazite Inorganic materials 0.000 claims description 5
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000012141 concentrate Substances 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 9
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 8
- 239000005642 Oleic acid Substances 0.000 description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- 229920001732 Lignosulfonate Polymers 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920001353 Dextrin Polymers 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000004676 glycans Chemical class 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 239000005017 polysaccharide Substances 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- 239000004375 Dextrin Substances 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229910021532 Calcite Inorganic materials 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000017343 Quebracho blanco Nutrition 0.000 description 1
- 241000065615 Schinopsis balansae Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000004029 environmental poison Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/06—Depressants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB29736/76A GB1571106A (en) | 1976-07-16 | 1976-07-16 | Ore flotation process for the recovery of fluoride minerals and rare earth carbonates |
| US05/815,025 US4157296A (en) | 1976-07-16 | 1977-07-11 | Flotation process for fluoride minerals |
| IT25769/77A IT1084339B (it) | 1976-07-16 | 1977-07-14 | Procedimento perfezionato di flottazione. |
| DE19772731824 DE2731824A1 (de) | 1976-07-16 | 1977-07-14 | Verfahren zur flotation von erzen |
| SU772510152A SU731884A3 (ru) | 1976-07-16 | 1977-07-15 | Способ обогащени руд, содержащих пол рные несульфидные минералы |
| FR7721918A FR2358200A1 (fr) | 1976-07-16 | 1977-07-18 | Procede de flottation utilisant comme depresseur un polymere d'acide sulfonique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB29736/76A GB1571106A (en) | 1976-07-16 | 1976-07-16 | Ore flotation process for the recovery of fluoride minerals and rare earth carbonates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1571106A true GB1571106A (en) | 1980-07-09 |
Family
ID=10296333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB29736/76A Expired GB1571106A (en) | 1976-07-16 | 1976-07-16 | Ore flotation process for the recovery of fluoride minerals and rare earth carbonates |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4157296A (enExample) |
| DE (1) | DE2731824A1 (enExample) |
| FR (1) | FR2358200A1 (enExample) |
| GB (1) | GB1571106A (enExample) |
| IT (1) | IT1084339B (enExample) |
| SU (1) | SU731884A3 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4363724A (en) * | 1980-08-26 | 1982-12-14 | Alcolac, Inc. | Use of C8-34 alpha olefin sulfonates to improve and enhance the flotation and collection process used for barite |
| ZA899462B (en) * | 1988-12-19 | 1990-09-26 | Wimmera Ind Minerals Proprieta | Improving the quality of heavy mineral concentrates |
| CN101703966B (zh) * | 2009-12-08 | 2011-11-02 | 湖南省铸万有实业有限公司 | 萤石矿碳酸盐抑制剂及其制备方法 |
| CN109985731B (zh) * | 2019-04-10 | 2020-10-30 | 中南大学 | 一种具有缓释转化功能的高镁硫化矿物浮选抑制剂及其应用 |
| CN115254440B (zh) * | 2022-08-09 | 2024-06-28 | 东北大学 | 可得然胶在萤石矿浮选中作为抑制剂的应用及其应用方法 |
| CN115625031B (zh) * | 2022-11-03 | 2025-04-29 | 东北大学 | 一种氢基矿相转化回收含铁稀土多金属矿中铁和稀土的方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE839181C (de) * | 1944-04-30 | 1952-05-15 | Erz U Kohle Flotation G M B H | Verfahren zur Aufbereitung nichtmetallischer Mineralien nach dem Schwimmverfahren |
| US2407651A (en) * | 1944-11-01 | 1946-09-17 | Nasa | Concentrating fluorspar by froth flotation |
| US2647629A (en) * | 1950-08-25 | 1953-08-04 | Atomic Energy Commission | Flotation of uranium |
| US2740522A (en) * | 1953-04-07 | 1956-04-03 | American Cyanamid Co | Flotation of ores using addition polymers as depressants |
| DE1002702B (de) * | 1955-12-29 | 1957-02-21 | Basf Ag | Verfahren zur Schaumschwimmaufbereitung, insbesondere von Steinkohle |
| US3138550A (en) * | 1960-11-28 | 1964-06-23 | Union Carbide Corp | Froth flotation process employing polymeric flocculants |
| NL128438C (enExample) * | 1962-02-05 | |||
| US3259569A (en) * | 1963-10-08 | 1966-07-05 | Charles P Priesing | Flocculation of sewage having controlled solids concentrations |
| US3617572A (en) * | 1969-11-03 | 1971-11-02 | Hercules Inc | Flocculation and settling of inorganic particles in a salt solution |
| GB1355091A (en) * | 1971-07-30 | 1974-05-30 | Chem Y | Flotation process |
| DE2144024A1 (de) * | 1971-09-02 | 1973-03-08 | Hercules Inc | Verfahren zum ausflocken und absetzen von ueberwiegend anorganischen, in salzloesungen suspendierten teilchen |
| US3860513A (en) * | 1972-01-20 | 1975-01-14 | Porter Hart | Method of recovering mineral values from ore |
-
1976
- 1976-07-16 GB GB29736/76A patent/GB1571106A/en not_active Expired
-
1977
- 1977-07-11 US US05/815,025 patent/US4157296A/en not_active Expired - Lifetime
- 1977-07-14 DE DE19772731824 patent/DE2731824A1/de not_active Withdrawn
- 1977-07-14 IT IT25769/77A patent/IT1084339B/it active
- 1977-07-15 SU SU772510152A patent/SU731884A3/ru active
- 1977-07-18 FR FR7721918A patent/FR2358200A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2358200B1 (enExample) | 1981-11-20 |
| SU731884A3 (ru) | 1980-04-30 |
| IT1084339B (it) | 1985-05-25 |
| FR2358200A1 (fr) | 1978-02-10 |
| US4157296A (en) | 1979-06-05 |
| DE2731824A1 (de) | 1978-01-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |