GB1569061A - Sulphonation method and apparatus therefor - Google Patents
Sulphonation method and apparatus therefor Download PDFInfo
- Publication number
- GB1569061A GB1569061A GB701/78A GB70178A GB1569061A GB 1569061 A GB1569061 A GB 1569061A GB 701/78 A GB701/78 A GB 701/78A GB 70178 A GB70178 A GB 70178A GB 1569061 A GB1569061 A GB 1569061A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stage reaction
- liquid
- gas
- stream
- reaction tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 33
- 238000006243 chemical reaction Methods 0.000 claims description 163
- 239000007788 liquid Substances 0.000 claims description 89
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 83
- 239000007789 gas Substances 0.000 claims description 79
- 238000001816 cooling Methods 0.000 claims description 50
- 150000002894 organic compounds Chemical class 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 25
- 238000006277 sulfonation reaction Methods 0.000 claims description 23
- 239000000376 reactant Substances 0.000 claims description 22
- 239000007795 chemical reaction product Substances 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 239000011261 inert gas Substances 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 10
- 230000000630 rising effect Effects 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 239000011344 liquid material Substances 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 238000005670 sulfation reaction Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims 6
- 239000000110 cooling liquid Substances 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 2
- -1 carbon atoms ethylene oxide adducts Chemical class 0.000 claims 2
- 239000003701 inert diluent Substances 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 1
- 150000004996 alkyl benzenes Chemical group 0.000 claims 1
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- 239000007792 gaseous phase Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 230000000149 penetrating effect Effects 0.000 claims 1
- 239000000047 product Substances 0.000 description 17
- 239000000498 cooling water Substances 0.000 description 16
- 239000010408 film Substances 0.000 description 14
- 239000010409 thin film Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 5
- 239000011368 organic material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/02—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor of the thin-film type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/247—Suited for forming thin films
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B45/00—Formation or introduction of functional groups containing sulfur
- C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP373277A JPS5390219A (en) | 1977-01-17 | 1977-01-17 | Sulfonation process and its apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1569061A true GB1569061A (en) | 1980-06-11 |
Family
ID=11565418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB701/78A Expired GB1569061A (en) | 1977-01-17 | 1978-01-09 | Sulphonation method and apparatus therefor |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5390219A (cg-RX-API-DMAC7.html) |
| BE (1) | BE862913A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2800788A1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES465901A1 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2377379A1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1569061A (cg-RX-API-DMAC7.html) |
| IT (1) | IT1092741B (cg-RX-API-DMAC7.html) |
| NL (1) | NL7800554A (cg-RX-API-DMAC7.html) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2200574A (en) * | 1986-12-08 | 1988-08-10 | Atomic Energy Authority Uk | Chemical treatment of liquors |
| US4922008A (en) * | 1983-11-28 | 1990-05-01 | Ciba-Geigy Corporation | Process for the production of 4-nitrotoluene-2-sulfonic acid |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2900403B1 (fr) * | 2006-04-26 | 2008-07-11 | Rhodia Recherches & Tech | Procede de preparation de derives organiques oxysulfures et fluores |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE624038A (cg-RX-API-DMAC7.html) * | ||||
| JPS5214725A (en) * | 1975-07-21 | 1977-02-03 | Kao Corp | Method of sulfonation and its apparatus |
-
1977
- 1977-01-17 JP JP373277A patent/JPS5390219A/ja active Pending
-
1978
- 1978-01-09 GB GB701/78A patent/GB1569061A/en not_active Expired
- 1978-01-09 DE DE19782800788 patent/DE2800788A1/de not_active Withdrawn
- 1978-01-11 ES ES465901A patent/ES465901A1/es not_active Expired
- 1978-01-16 BE BE2056601A patent/BE862913A/xx not_active IP Right Cessation
- 1978-01-17 NL NL7800554A patent/NL7800554A/xx unknown
- 1978-01-17 IT IT19310/78A patent/IT1092741B/it active
- 1978-01-17 FR FR7801230A patent/FR2377379A1/fr active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4922008A (en) * | 1983-11-28 | 1990-05-01 | Ciba-Geigy Corporation | Process for the production of 4-nitrotoluene-2-sulfonic acid |
| GB2200574A (en) * | 1986-12-08 | 1988-08-10 | Atomic Energy Authority Uk | Chemical treatment of liquors |
| GB2200574B (en) * | 1986-12-08 | 1990-11-28 | Atomic Energy Authority Uk | Chemical treatment of liquors |
Also Published As
| Publication number | Publication date |
|---|---|
| ES465901A1 (es) | 1979-01-01 |
| FR2377379A1 (fr) | 1978-08-11 |
| IT7819310A0 (it) | 1978-01-17 |
| IT1092741B (it) | 1985-07-12 |
| BE862913A (fr) | 1978-05-16 |
| JPS5390219A (en) | 1978-08-08 |
| NL7800554A (nl) | 1978-07-19 |
| FR2377379B1 (cg-RX-API-DMAC7.html) | 1981-07-10 |
| DE2800788A1 (de) | 1978-07-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |