GB1545061A - Curable poly(alkylene)ether polyol-based resins having improved properties - Google Patents
Curable poly(alkylene)ether polyol-based resins having improved propertiesInfo
- Publication number
- GB1545061A GB1545061A GB9982/76A GB998276A GB1545061A GB 1545061 A GB1545061 A GB 1545061A GB 9982/76 A GB9982/76 A GB 9982/76A GB 998276 A GB998276 A GB 998276A GB 1545061 A GB1545061 A GB 1545061A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sealant
- adhesive
- aromatic
- cycloaliphatic
- initiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09J175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/067—Polyurethanes; Polyureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8038—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3225
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyurethanes Or Polyureas (AREA)
- Sealing Material Composition (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
To prepare a curable adhesive/sealant, an organic polyisocyanate whose isocyanate groups are bonded to aromatic or cycloaliphatic carbon atoms is reacted first with a polyalkylene ether polyol and then with an acrylic or methacrylic ester which has a hydroxyl or non-tertiary amino group in the molecule. The polyisocyanate used is preferably the reaction product of an aromatic or cycloaliphatic polyisocyanate and an aromatic or cycloaliphatic polyol or polyamine. Solvents which are coreactive in the later curing can be present. The storage-stable prepolymers have rigid and flexible segments. To adhere surfaces or seal off gaps between surfaces, the adhesive/sealant is introduced between the surfaces together with a free-radical initiator and allowed to cure. Curing can be anaerobic or by means of UV-irradiation, depending on the choice of initiator. The initiator can be added to the adhesive/sealant or applied separately to a surface. The cured adhesive/sealant is highly flexible and has excellent tensile and impact strength. Gaps more than 1 mm wide can be sealed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US55774075A | 1975-03-12 | 1975-03-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1545061A true GB1545061A (en) | 1979-05-02 |
Family
ID=24226697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9982/76A Expired GB1545061A (en) | 1975-03-12 | 1976-03-12 | Curable poly(alkylene)ether polyol-based resins having improved properties |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS51114436A (en) |
AU (1) | AU508482B2 (en) |
BR (1) | BR7601482A (en) |
CA (1) | CA1091384A (en) |
CH (1) | CH637685A5 (en) |
DE (1) | DE2610423C2 (en) |
ES (1) | ES446032A1 (en) |
FR (1) | FR2303835A1 (en) |
GB (1) | GB1545061A (en) |
IT (1) | IT1057983B (en) |
NL (1) | NL7602600A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2150938A (en) * | 1983-12-05 | 1985-07-10 | Tyndale Plains Hunter Limited | Hydrophilic polyurethane acrylate compositions |
GB2199040A (en) * | 1986-12-06 | 1988-06-29 | Smith & Nephew Ass | Adhesives, their preparation and use |
US4914173A (en) * | 1986-12-06 | 1990-04-03 | Smith And Nephew Associate Companies Plc | Adhesives, their preparation and use |
WO2000075253A1 (en) * | 1999-06-07 | 2000-12-14 | 3M Innovative Properties Company | Adhesive composition and optical disc using the same |
FR2938267A1 (en) * | 2008-11-07 | 2010-05-14 | Bostik Sa | Use of an adhesive composition made of polyurethane bicomponent in cryogenic application, preferably methane tanker carrying liquefied gases |
WO2010052671A1 (en) * | 2008-11-07 | 2010-05-14 | Bostik Sa | Use of a polyurethane adhesive composition for cryogenic applications |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4288479A (en) * | 1973-09-24 | 1981-09-08 | Design Cote Corp. | Radiation curable release coatings |
US4133723A (en) * | 1978-01-03 | 1979-01-09 | Lord Corporation | Actinic radiation-curable formulations from the reaction product of organic isocyanate, poly(alkylene oxide) polyol and an unsaturated addition-polymerizable monomeric compound having a single isocyanate-reactive hydrogen group |
US4425468A (en) * | 1981-12-31 | 1984-01-10 | Ppg Industries, Inc. | Polyurea-polyurethane acrylate polymer dispersions |
US4451627A (en) * | 1982-09-07 | 1984-05-29 | The Dow Chemical Company | Addition polymerizable urethane-based anaerobic adhesives made from tin (II) organoesters |
FR2579610B1 (en) * | 1985-03-28 | 1987-08-21 | Saint Gobain Vitrage | ADHESIVE LAYER USED IN THE MANUFACTURE OF SHEET WINDOWS AND SHEET WINDOWS COMPRISING SUCH A LAYER |
DE3544428A1 (en) * | 1985-12-16 | 1987-06-19 | Piestert Gerhard | Agent which cures in the absence of oxygen for bonding surfaces |
JPH0676578B2 (en) * | 1986-12-27 | 1994-09-28 | 東亞合成化学工業株式会社 | Anaerobic curable adhesive composition |
JPS6420283A (en) * | 1987-07-14 | 1989-01-24 | Toa Gosei Chem Ind | Adhesive composition |
DE4025776A1 (en) * | 1990-08-14 | 1992-02-20 | Thera Ges Fuer Patente | New curable prepolymers prepn. - from diol-or di:amino-terminated poly:tetra-hydro-furan with di:isocyanate and hydroxy-or amino-acrylate or with isocyanato-acrylate |
US5128434A (en) * | 1990-11-27 | 1992-07-07 | Bausch & Lomb Incorporated | Control of hard segment size in polyurethane formation |
JP3196269B2 (en) * | 1991-12-16 | 2001-08-06 | ジェイエスアール株式会社 | Liquid curable resin composition |
FR3090641B1 (en) * | 2018-12-19 | 2022-02-11 | Bostik Sa | (Meth)acrylic composition comprising a modified polyurethane |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3425988A (en) * | 1965-01-27 | 1969-02-04 | Loctite Corp | Polyurethane polyacrylate sealant compositions |
FR1495558A (en) * | 1966-08-08 | 1967-09-22 | Standard Products Co | Polyurethane, its preparation process and its use in tacky coating compositions |
GB1352063A (en) * | 1971-01-08 | 1974-05-15 | Ici Ltd | Polymerisable compositions and resins derived thererom |
US3873640A (en) * | 1972-04-21 | 1975-03-25 | Lord Corp | Adhesive bonding of polyvinyl chloride and other synthetic resin substrates |
IE39134B1 (en) * | 1972-05-16 | 1978-08-16 | Loctite Ltd | Improvements in or relating to photo-initiated optical |
DE2324832A1 (en) * | 1973-05-17 | 1974-12-12 | Langen & Co | AXIAL PISTON PUMP |
-
1976
- 1976-03-05 CA CA247,216A patent/CA1091384A/en not_active Expired
- 1976-03-11 AU AU11826/76A patent/AU508482B2/en not_active Expired
- 1976-03-11 CH CH300776A patent/CH637685A5/en not_active IP Right Cessation
- 1976-03-11 BR BR7601482A patent/BR7601482A/en unknown
- 1976-03-12 FR FR7607153A patent/FR2303835A1/en active Granted
- 1976-03-12 JP JP51026993A patent/JPS51114436A/en active Granted
- 1976-03-12 ES ES446032A patent/ES446032A1/en not_active Expired
- 1976-03-12 IT IT48551/76A patent/IT1057983B/en active
- 1976-03-12 GB GB9982/76A patent/GB1545061A/en not_active Expired
- 1976-03-12 NL NL7602600A patent/NL7602600A/en not_active Application Discontinuation
- 1976-03-12 DE DE2610423A patent/DE2610423C2/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2150938A (en) * | 1983-12-05 | 1985-07-10 | Tyndale Plains Hunter Limited | Hydrophilic polyurethane acrylate compositions |
GB2199040A (en) * | 1986-12-06 | 1988-06-29 | Smith & Nephew Ass | Adhesives, their preparation and use |
GB2199040B (en) * | 1986-12-06 | 1990-01-24 | Smith & Nephew Ass | Adhesives, their preparation and use |
US4914173A (en) * | 1986-12-06 | 1990-04-03 | Smith And Nephew Associate Companies Plc | Adhesives, their preparation and use |
WO2000075253A1 (en) * | 1999-06-07 | 2000-12-14 | 3M Innovative Properties Company | Adhesive composition and optical disc using the same |
FR2938267A1 (en) * | 2008-11-07 | 2010-05-14 | Bostik Sa | Use of an adhesive composition made of polyurethane bicomponent in cryogenic application, preferably methane tanker carrying liquefied gases |
WO2010052671A1 (en) * | 2008-11-07 | 2010-05-14 | Bostik Sa | Use of a polyurethane adhesive composition for cryogenic applications |
Also Published As
Publication number | Publication date |
---|---|
BR7601482A (en) | 1976-09-14 |
DE2610423C2 (en) | 1986-09-11 |
AU508482B2 (en) | 1980-03-20 |
IT1057983B (en) | 1982-03-30 |
NL7602600A (en) | 1976-09-14 |
FR2303835B1 (en) | 1981-10-09 |
ES446032A1 (en) | 1977-06-01 |
JPS61365B2 (en) | 1986-01-08 |
DE2610423A1 (en) | 1976-09-16 |
CH637685A5 (en) | 1983-08-15 |
CA1091384A (en) | 1980-12-09 |
AU1182676A (en) | 1977-09-15 |
JPS51114436A (en) | 1976-10-08 |
FR2303835A1 (en) | 1976-10-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19960311 |