GB1530023A - Continuous polymerisation of vinyl aromatic monomers - Google Patents
Continuous polymerisation of vinyl aromatic monomersInfo
- Publication number
- GB1530023A GB1530023A GB1192776A GB1192776A GB1530023A GB 1530023 A GB1530023 A GB 1530023A GB 1192776 A GB1192776 A GB 1192776A GB 1192776 A GB1192776 A GB 1192776A GB 1530023 A GB1530023 A GB 1530023A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zone
- reaction vessel
- effluent
- vinyl aromatic
- vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1530023 Continuous polymerization of elastomers/vinyl aromatic mixtures UNITED STERLING CORP Ltd 11 March 1977 [24 March 1976] 11927/76 Heading C3P Toughened polymers are produced by (a) providing in a first zone, a feed mixture comprising a solution of an elastomeric polymer in a monomer which is a vinyl aromatic or vinylidene aromatic monomer; (b) passing effluent from said first zone continuously into a first reaction vessel; (c) continuously withdrawing effluent from the first reaction vessel and subjecting it to further polymerization in at least one downstream reaction vessel and recovering the toughened polymer from the last reaction vessel by devolatilization of unreacted monomer and volatile solvent, if any; and also (d) continuously withdrawing effluent from said first reaction vessel and recycling it to the said first reaction zone so as to control the solids content of the effluent of said first zone to at least 1À5 times the solids content of said feed mixture in (a), but not more than 45 wt. per cent. In preferred embodiments the first zone is a prereaction vessel or a mixing vessel, and the reactors are tubular and provided with agitators.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1192776A GB1530023A (en) | 1976-03-24 | 1976-03-24 | Continuous polymerisation of vinyl aromatic monomers |
BE176098A BE852854A (en) | 1976-03-24 | 1977-03-24 | CONTINUOUS PRODUCTION OF HARDENED POLYMERS AND POLYMERS THUS OBTAINED |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1192776A GB1530023A (en) | 1976-03-24 | 1976-03-24 | Continuous polymerisation of vinyl aromatic monomers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1530023A true GB1530023A (en) | 1978-10-25 |
Family
ID=9995209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1192776A Expired GB1530023A (en) | 1976-03-24 | 1976-03-24 | Continuous polymerisation of vinyl aromatic monomers |
Country Status (2)
Country | Link |
---|---|
BE (1) | BE852854A (en) |
GB (1) | GB1530023A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0021617A1 (en) * | 1979-06-01 | 1981-01-07 | Mobil Oil Corporation | A continuous process for the preparation of rubber modified polymers |
EP0254304A2 (en) * | 1986-07-25 | 1988-01-27 | Dainippon Ink And Chemicals, Inc. | Process for producing high impact styrene resin by continuous bulk polymerization |
CN114100543A (en) * | 2021-12-07 | 2022-03-01 | 万华化学(四川)有限公司 | Vinyl polymer and continuous bulk polymerization method and reaction device thereof |
-
1976
- 1976-03-24 GB GB1192776A patent/GB1530023A/en not_active Expired
-
1977
- 1977-03-24 BE BE176098A patent/BE852854A/en not_active IP Right Cessation
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0021617A1 (en) * | 1979-06-01 | 1981-01-07 | Mobil Oil Corporation | A continuous process for the preparation of rubber modified polymers |
EP0254304A2 (en) * | 1986-07-25 | 1988-01-27 | Dainippon Ink And Chemicals, Inc. | Process for producing high impact styrene resin by continuous bulk polymerization |
EP0254304A3 (en) * | 1986-07-25 | 1989-11-23 | Dainippon Ink And Chemicals, Inc. | Process for producing high impact styrene resin by continuous bulk polymerization |
US4952627A (en) * | 1986-07-25 | 1990-08-28 | Dainippon Ink And Chemicals, Inc. | Process for producing high impact styrene resin by continuous bulk polymerization |
CN114100543A (en) * | 2021-12-07 | 2022-03-01 | 万华化学(四川)有限公司 | Vinyl polymer and continuous bulk polymerization method and reaction device thereof |
Also Published As
Publication number | Publication date |
---|---|
BE852854A (en) | 1977-09-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |