GB1516047A - Polymeric laminate film and method of preparing it - Google Patents

Polymeric laminate film and method of preparing it

Info

Publication number
GB1516047A
GB1516047A GB2119876A GB2119876A GB1516047A GB 1516047 A GB1516047 A GB 1516047A GB 2119876 A GB2119876 A GB 2119876A GB 2119876 A GB2119876 A GB 2119876A GB 1516047 A GB1516047 A GB 1516047A
Authority
GB
United Kingdom
Prior art keywords
cross
layer
linked
polymer
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2119876A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co filed Critical WR Grace and Co
Publication of GB1516047A publication Critical patent/GB1516047A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/04—After-treatment of articles without altering their shape; Apparatus therefor by wave energy or particle radiation, e.g. for curing or vulcanising preformed articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/72—Cured, e.g. vulcanised, cross-linked
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2329/00—Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
    • B32B2329/04—Polyvinylalcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2331/00—Polyvinylesters
    • B32B2331/04—Polymers of vinyl acetate, e.g. PVA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y10T428/3192—Next to vinyl or vinylidene chloride polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer

Abstract

1516047 Laminated films W R GRACE & CO 21 May 1976 [22 May 1975] 21198/76 Heading B5N A polymeric laminated film comprising at least two cross-linked polymeric layers, one of which is cross-linked to a greater extent than the other may be made by irradiating a laminate film comprising at least a layer (1) of a polymer which has undergone cross-linking and (2) a layer of an irradiation cross-linkable polymer. A preferred film comprises at least two crosslinked alpha-monoolefin polymer layers, at least one such layer, e.g. of polyethylene or ethylenevinyl acetate copolymer being cross-linked to a greater extent than any other, and, intermediate two such layers a barrier layer of a vinylidene chloride polymer or an ethylenevinyl alcohol copolymer, the lesser cross-linked layer being preferably a blend of polybutene-1 with an ethylene-propylene copolymer. Extrusion techniques may be used on the formation of the film which may be tubular and may also be stretched.
GB2119876A 1975-05-22 1976-05-21 Polymeric laminate film and method of preparing it Expired GB1516047A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05580103 US4044187B1 (en) 1975-05-22 1975-05-22 Film laminates having a reirradiated layer

Publications (1)

Publication Number Publication Date
GB1516047A true GB1516047A (en) 1978-06-28

Family

ID=24319712

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2119876A Expired GB1516047A (en) 1975-05-22 1976-05-21 Polymeric laminate film and method of preparing it

Country Status (14)

Country Link
US (1) US4044187B1 (en)
JP (1) JPS51143086A (en)
BE (1) BE842039A (en)
CA (1) CA1069426A (en)
CH (1) CH615114A5 (en)
DE (1) DE2622185C2 (en)
DK (1) DK150795C (en)
ES (1) ES448091A1 (en)
FI (1) FI65576C (en)
FR (1) FR2311661A1 (en)
GB (1) GB1516047A (en)
NL (1) NL186439C (en)
NO (1) NO145873C (en)
SE (1) SE431181B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2506667A1 (en) * 1981-05-29 1982-12-03 Grace W R Ltd MULTI-LAYERED SHRINK AND THERMOPLASTIC PACKAGING FILM, SOLDER-FREE TUBE, RECEPTACLE FORMED THEREOF AND METHOD FOR IMPROVING THE HANDLING AND THERMAL SEAL CHARACTERISTICS OF SUCH A FILM
GB2137931A (en) * 1983-04-07 1984-10-17 Grace W R & Co Laminated Packaging Film Heat-Shrinkable After Forming, and Method for the Preparation Thereof

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Publication number Priority date Publication date Assignee Title
US4140167A (en) * 1976-08-20 1979-02-20 The Firestone Tire & Rubber Company Sealant laminates
US4318763A (en) * 1976-12-22 1982-03-09 W. R. Grace & Co. Sealing cross-linked thermoplastic materials
US4225373A (en) * 1976-12-22 1980-09-30 W. R. Grace & Co. Sealing cross-linked thermoplastic materials
JPS5841862B2 (en) * 1977-01-08 1983-09-14 テルモ株式会社 medical equipment
JPS5456672A (en) * 1977-10-14 1979-05-07 Toray Ind Inc High polymer tube having modified inner surface
US4178401A (en) * 1978-01-09 1979-12-11 W. R. Grace & Co. Packaging film comprising a blended self-welding layer
US4194039A (en) * 1978-04-17 1980-03-18 W. R. Grace & Co. Multi-layer polyolefin shrink film
US4170664A (en) * 1978-07-13 1979-10-09 Exxon Research & Engineering Co. Resilient radiation-curable automotive body components
US4239826A (en) * 1978-12-28 1980-12-16 American Can Company Multi-layer barrier film
US4254169A (en) * 1978-12-28 1981-03-03 American Can Company Multi-layer barrier film
US4355721A (en) * 1979-05-11 1982-10-26 American Can Company Package for food products
DE2925205A1 (en) * 1979-06-22 1981-02-05 Bayer Ag STEAM-STEELABLE, SEALABLE FILMS
CA1145272A (en) * 1979-11-28 1983-04-26 Jerker Skarelius Gaseous diffusion resistant article and method utilizing same
US4352702A (en) * 1980-09-22 1982-10-05 W. R. Grace & Co. Method of making a thermoplastic receptacle having improved high temperature seal
DE3047181A1 (en) * 1980-12-15 1982-06-16 Hoechst Ag, 6000 Frankfurt PLASTIC PIPE WITH OXYGEN-COATING
JPS5882752A (en) * 1981-11-11 1983-05-18 呉羽化学工業株式会社 Heat-shrinkable film
DE3277609D1 (en) * 1982-01-07 1987-12-17 Fresenius Ag Preservation bag
GB2130789B (en) * 1982-10-20 1986-05-14 Canon Kk Bonding colour separation filters
US4501780A (en) * 1982-12-15 1985-02-26 W. R. Grace & Co., Cryovac Div. Tubular film having sealing layer of propylene ethylene random copolymer
US4551380A (en) * 1984-05-10 1985-11-05 W. R. Grace & Co., Cryovac Div. Oriented heat-sealable multilayer packaging film
US4643943A (en) * 1984-05-30 1987-02-17 W. R. Grace & Co., Cryovac Div. Multi-layer polyolefin shrink film
US4514465A (en) * 1984-05-30 1985-04-30 W. R. Grace & Co., Cryovac Div. Storm window film comprising at least five layers
US4997690A (en) * 1984-12-03 1991-03-05 Viskase Corporation Irradiated multilayer film for primal meat packaging
US4865780A (en) * 1984-12-03 1989-09-12 Viskase Corporation Process for producing irradiated multilayer film for primal meat packaging
CA1341599C (en) * 1984-12-03 2010-03-02 Stanley Lustig Irradiated multilayer film for primal meat packaging
US7052753B1 (en) 1985-05-16 2006-05-30 Pechiney Emballage Flexible Europe Multiple layer polymeric films and process for making them
US4894107A (en) 1985-05-16 1990-01-16 American National Can Company Process for making multiple layer polymeric films
US4892603A (en) * 1985-06-14 1990-01-09 Viskase Corporation Irradiated multilayer film for primal meat packaging
US4685090A (en) * 1985-11-27 1987-08-04 Raychem Corporation Tubular article
US4863768A (en) * 1986-06-19 1989-09-05 Asahi Kasei Kogyo Kabushiki Kaisha Heat shrinkable cylindrical laminated film
FR2605930B1 (en) * 1986-10-31 1989-04-28 Conservatome PROCESS FOR TREATING COMPLEX HEAT SHRINKABLE FILMS IN POLYMERS, ESPECIALLY FOR PACKAGING OBJECTS
US4911963A (en) * 1987-08-31 1990-03-27 Viskase Corporation Multilayer film containing amorphous nylon
US5077109A (en) * 1987-08-31 1991-12-31 Viskase Corporation Oriented multilayer film and process for making same
US5284687A (en) * 1987-12-31 1994-02-08 American National Can Company Coextrustion apparatus, methods, and related films and packages
US4944972A (en) * 1987-12-31 1990-07-31 American National Can Company Coextrusion apparatus, methods, and related films and packages
US5061534A (en) * 1988-04-22 1991-10-29 American National Can Company High oxygen barrier film
US5053259A (en) * 1988-08-23 1991-10-01 Viskase Corporation Amorphous nylon copolymer and copolyamide films and blends
CA2003882C (en) * 1988-12-19 1997-01-07 Edwin Rogers Smith Heat shrinkable very low density polyethylene terpolymer film
US4954197A (en) * 1989-03-30 1990-09-04 Xerox Corporation Process for assembling smaller arrays together to form a longer array
US5491009A (en) * 1990-08-03 1996-02-13 W. R. Grace & Co.-Conn. Amorphous nylon composition and films
SE511766C2 (en) † 1998-03-23 1999-11-22 Wirsbo Bruks Ab Plastic multilayer tubes and their use
US20030079333A1 (en) * 2001-10-29 2003-05-01 Guthrie Joseph D. Process for making a metal-polymer composite having an irradiated polymer coating
US20040175464A1 (en) * 2003-03-07 2004-09-09 Blemberg Robert J. Multilayer structures, packages, and methods of making multilayer structures
US20040175466A1 (en) * 2003-03-07 2004-09-09 Douglas Michael J. Multilayer barrier structures, methods of making the same and packages made therefrom
US8741433B2 (en) * 2004-12-10 2014-06-03 Curwood, Inc. Packaging films comprising nylon blend compositions
US8293062B2 (en) * 2007-05-17 2012-10-23 Macro Engineering and Technology, Inc. Shrink film with individual layer irradiation
BRPI0910499A2 (en) * 2008-07-15 2020-08-18 Dow Global Technologies Inc. film and perforated film
CA3014699C (en) 2016-02-15 2023-01-17 Macro Technology Inc. Multilayer barrier film

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BE549387A (en) * 1955-07-08
US3022543A (en) * 1958-02-07 1962-02-27 Grace W R & Co Method of producing film having improved shrink energy
BE617992A (en) * 1961-05-24
US3821182A (en) * 1961-12-05 1974-06-28 Grace W R & Co Method for preparing of film of a vinylidene chloride polymer
NL290654A (en) * 1962-03-27 1900-01-01
US3644161A (en) * 1967-11-13 1972-02-22 Scm Corp Process for curing air-inhibited resins by radiation
US3741253A (en) * 1971-03-30 1973-06-26 Grace W R & Co Laminates of ethylene vinyl acetate polymers and polymers of vinylidene chloride
GB1392212A (en) * 1971-04-02 1975-04-30 Raychem Corp Involutely heat-recoverable articles
US3891008A (en) * 1973-12-26 1975-06-24 Grace W R & Co Multi-layer thermoplastic film and method of making same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2506667A1 (en) * 1981-05-29 1982-12-03 Grace W R Ltd MULTI-LAYERED SHRINK AND THERMOPLASTIC PACKAGING FILM, SOLDER-FREE TUBE, RECEPTACLE FORMED THEREOF AND METHOD FOR IMPROVING THE HANDLING AND THERMAL SEAL CHARACTERISTICS OF SUCH A FILM
GB2137931A (en) * 1983-04-07 1984-10-17 Grace W R & Co Laminated Packaging Film Heat-Shrinkable After Forming, and Method for the Preparation Thereof

Also Published As

Publication number Publication date
DK150795B (en) 1987-06-22
BE842039A (en) 1976-09-16
AU500418B2 (en) 1979-05-24
FI65576C (en) 1984-06-11
DK150795C (en) 1988-01-04
NO145873B (en) 1982-03-08
US4044187B1 (en) 1991-04-30
FR2311661B1 (en) 1982-06-18
NO761712L (en) 1976-11-23
NL186439C (en) 1990-12-03
AU1414276A (en) 1977-12-22
CA1069426A (en) 1980-01-08
FI761443A (en) 1976-11-23
NL7605388A (en) 1976-11-24
ES448091A1 (en) 1977-07-01
SE431181B (en) 1984-01-23
NL186439B (en) 1990-07-02
NO145873C (en) 1982-06-16
SE7605757L (en) 1976-11-23
DK222976A (en) 1976-11-23
FI65576B (en) 1984-02-29
DE2622185C2 (en) 1984-04-12
CH615114A5 (en) 1980-01-15
FR2311661A1 (en) 1976-12-17
US4044187A (en) 1977-08-23
JPS6147859B2 (en) 1986-10-21
JPS51143086A (en) 1976-12-09
DE2622185A1 (en) 1976-12-09

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PE20 Patent expired after termination of 20 years

Effective date: 19960520