GB1514359A - Benzotriazole-and benzimidazole derivatives and their use as additives for functional fluids - Google Patents

Benzotriazole-and benzimidazole derivatives and their use as additives for functional fluids

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Publication number
GB1514359A
GB1514359A GB16754/76A GB1675476A GB1514359A GB 1514359 A GB1514359 A GB 1514359A GB 16754/76 A GB16754/76 A GB 16754/76A GB 1675476 A GB1675476 A GB 1675476A GB 1514359 A GB1514359 A GB 1514359A
Authority
GB
United Kingdom
Prior art keywords
group
carbon atoms
alkylene
formula
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16754/76A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Priority to GB16754/76A priority Critical patent/GB1514359A/en
Publication of GB1514359A publication Critical patent/GB1514359A/en
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/06—Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38—Heterocyclic nitrogen compounds
    • C10M133/44—Five-membered ring containing nitrogen and carbon only
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    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/10—Groups 5 or 15
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Lubricants (AREA)

Abstract

1514359 Benzotriazole and benzimidazole derivatives CIBA-GEIGY AG 1 April 1977 [24 April 1976] 16754/76 Heading C2C [Also in Division C5] Novel compounds of the formula wherein R 1 and R 2 are the same or different and each is hydrogen; an alkyl group having from 1 to 20 carbon atoms; an alkenyl group having from 2 to 20 carbon atoms; a group of formula R 3 O[(alkylene)O] x (alkylene)- wherein R 3 is hydrogen or an alkyl residue having from 1 to 20 carbon atoms, alkylene is a straight or branched chain alkylene group having 2 or 3 carbon atoms and x is 0, 1, 2, 3, or 4; a cyanoalkyl group having from 2 to 5 carbon atoms; an aryl group having from 6 to 10 carbon atoms; an aralkyl group having from 7 to 9 carbon atoms; or R 1 and R 2 together may form, with the nitrogen atom, a heterocyclic group; Y is a straight or branched alkylene group having from 1 to 6 carbon atoms, a 1,1-cycloalkylene group having from 5 to 12 carbon atoms, a carbonyl group, a sulphuryl group, an oxygen atom, or a sulphur atom; and Z is N or CR 4 wherein R 4 is hydrogen or a hydrocarbyl residue having from 1 to 8 carbon atoms, are prepared by reacting a compound of the formula with formaldehyde and an amine of the formula (R 1 )(R 2 )NH, preferably in a molar ratio of compound II: formaldehyde : amine of 1:2:2. The novel compounds may be used as metal passivators in functional fluids.
GB16754/76A 1977-04-01 1977-04-01 Benzotriazole-and benzimidazole derivatives and their use as additives for functional fluids Expired GB1514359A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB16754/76A GB1514359A (en) 1977-04-01 1977-04-01 Benzotriazole-and benzimidazole derivatives and their use as additives for functional fluids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB16754/76A GB1514359A (en) 1977-04-01 1977-04-01 Benzotriazole-and benzimidazole derivatives and their use as additives for functional fluids

Publications (1)

Publication Number Publication Date
GB1514359A true GB1514359A (en) 1978-06-14

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0088724A1 (en) * 1982-02-26 1983-09-14 Ciba-Geigy Ag Mixtures of benzotriazoles, process for their preparation and their use as metal passivators
US4522785A (en) * 1982-11-04 1985-06-11 The Sherwin-Williams Company Dialkylaminomethyl aromatic triazoles as corrosion inhibitors
US4880551A (en) * 1988-06-06 1989-11-14 R. T. Vanderbilt Company, Inc. Antioxidant synergists for lubricating compositions
US5076946A (en) * 1990-03-30 1991-12-31 Exxon Research And Engineering Company Alkylamine substituted benzotriazole containing lubricants having improved oxidation stability and rust inhibition (PNE-530)
US5211865A (en) * 1990-03-08 1993-05-18 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
US5232615A (en) * 1990-03-08 1993-08-03 Exxon Chemical Patents Inc. Heterocyclic nitrogen compound Mannich base derivatives of polyolefin-substituted amines for oleaginous compositions
US5271856A (en) * 1990-03-08 1993-12-21 Exxon Chemical Patents Inc. Heterocyclic nitrogen compound Mannich base derivatives of amino-substituted polymers for oleaginous compositions
US5273671A (en) * 1990-03-08 1993-12-28 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
EP0622444A1 (en) * 1992-08-18 1994-11-02 Ethyl Japan Corporation Lubricating oil composition for wet clutch or wet brake
EP0812833A1 (en) * 1996-06-10 1997-12-17 Armstrong World Industries, Inc. Water soluble triazole derivatives and their use as blowing inhibitor in chemical embossing processes
US6140379A (en) * 1998-12-07 2000-10-31 Armstrong World Industries, Inc. Chemically embossed metallocene polyethylene foam

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4683071A (en) * 1982-02-26 1987-07-28 Franz Regenass Benzotriazole mixtures, processes for producing them, and their use as metal passivators
EP0088724A1 (en) * 1982-02-26 1983-09-14 Ciba-Geigy Ag Mixtures of benzotriazoles, process for their preparation and their use as metal passivators
US4522785A (en) * 1982-11-04 1985-06-11 The Sherwin-Williams Company Dialkylaminomethyl aromatic triazoles as corrosion inhibitors
US4880551A (en) * 1988-06-06 1989-11-14 R. T. Vanderbilt Company, Inc. Antioxidant synergists for lubricating compositions
US5376152A (en) * 1990-03-08 1994-12-27 Exxon Chemical Patents Inc. Heterocyclic nitrogen compound mannich base derivatives of polyolefin-substituted amines for oleaginous compositions
US5211865A (en) * 1990-03-08 1993-05-18 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
US5232615A (en) * 1990-03-08 1993-08-03 Exxon Chemical Patents Inc. Heterocyclic nitrogen compound Mannich base derivatives of polyolefin-substituted amines for oleaginous compositions
US5271856A (en) * 1990-03-08 1993-12-21 Exxon Chemical Patents Inc. Heterocyclic nitrogen compound Mannich base derivatives of amino-substituted polymers for oleaginous compositions
US5273671A (en) * 1990-03-08 1993-12-28 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
US5076946A (en) * 1990-03-30 1991-12-31 Exxon Research And Engineering Company Alkylamine substituted benzotriazole containing lubricants having improved oxidation stability and rust inhibition (PNE-530)
EP0622444A1 (en) * 1992-08-18 1994-11-02 Ethyl Japan Corporation Lubricating oil composition for wet clutch or wet brake
EP0622444A4 (en) * 1992-08-18 1995-02-15 Ethyl Japan Corp Lubricating oil composition for wet clutch or wet brake.
EP0812833A1 (en) * 1996-06-10 1997-12-17 Armstrong World Industries, Inc. Water soluble triazole derivatives and their use as blowing inhibitor in chemical embossing processes
US5824721A (en) * 1996-06-10 1998-10-20 Armstrong World Industries, Inc. Water soluble triazole derivative embossing inhibitor and the use thereof
US6140379A (en) * 1998-12-07 2000-10-31 Armstrong World Industries, Inc. Chemically embossed metallocene polyethylene foam
US6187840B1 (en) 1998-12-07 2001-02-13 Armstrong World Industries, Inc. Chemically embossed metallocene polyethylene foam

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