GB1513234A - Process for preparing 3-perfluoroalkyl-1,2-epoxypropanes - Google Patents

Process for preparing 3-perfluoroalkyl-1,2-epoxypropanes

Info

Publication number
GB1513234A
GB1513234A GB1886477A GB1886477A GB1513234A GB 1513234 A GB1513234 A GB 1513234A GB 1886477 A GB1886477 A GB 1886477A GB 1886477 A GB1886477 A GB 1886477A GB 1513234 A GB1513234 A GB 1513234A
Authority
GB
United Kingdom
Prior art keywords
perfluoroalkyl
epoxypropanes
iodopropanol
alkyl
chlorides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1886477A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daikin Industries Ltd
Original Assignee
Daikin Industries Ltd
Daikin Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daikin Industries Ltd, Daikin Kogyo Co Ltd filed Critical Daikin Industries Ltd
Publication of GB1513234A publication Critical patent/GB1513234A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/08Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals

Abstract

1513234 3 - Perfluoroalkyl - 1,2 - epoxypropanes DAIKAN KOGYO CO Ltd 5 May 1977 [6 May 1976] 18864/77 Heading C2C 3 - Perfluoroalkyl - 1,2 - epoxypropanes are prepared by reacting 3-perfluoroalkyl-2-iodopropanol-1 with an alkali metal hydroxide in an aqueous medium in the presence of a quaternary ammonium compound. The most preferred catalysts are C 10 -C 20 alkyl or alkenyl-tri(C 1-3 alkyl)ammonium hydroxides or chlorides and tri(C 2-3 alkyl)benzylammonium hydroxides or chlorides, used in an amount of 0À0001-0À15 mole per mole of the iodopropanol. Usually 1-2 equivalents of NaOH or KOH per mole of iodopropanol are used as a 0À1-30 wt.% aqueous solution, and a temperature of 60- 100‹ C. is adopted. In the Examples (CF 3 ) CF(CF 2 ) 6 CH 2 CH-o-CH 2 is prepared.
GB1886477A 1976-05-06 1977-05-05 Process for preparing 3-perfluoroalkyl-1,2-epoxypropanes Expired GB1513234A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5186376A JPS5922712B2 (en) 1976-05-06 1976-05-06 Method for producing 3-perfluoroalkyl-1,2-epoxypropane

Publications (1)

Publication Number Publication Date
GB1513234A true GB1513234A (en) 1978-06-07

Family

ID=12898696

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1886477A Expired GB1513234A (en) 1976-05-06 1977-05-05 Process for preparing 3-perfluoroalkyl-1,2-epoxypropanes

Country Status (2)

Country Link
JP (1) JPS5922712B2 (en)
GB (1) GB1513234A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0244717A2 (en) * 1986-05-07 1987-11-11 Bayer Ag Process for the preparation of 2,3-epoxyamides

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0244717A2 (en) * 1986-05-07 1987-11-11 Bayer Ag Process for the preparation of 2,3-epoxyamides
EP0244717A3 (en) * 1986-05-07 1989-05-10 Bayer Ag Process for the preparation of 2,3-epoxyamides

Also Published As

Publication number Publication date
JPS52136107A (en) 1977-11-14
JPS5922712B2 (en) 1984-05-28

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19940505