GB1496378A - Process for the oxidation of primary allylic and benzylic alcohols - Google Patents

Process for the oxidation of primary allylic and benzylic alcohols

Info

Publication number
GB1496378A
GB1496378A GB4751975A GB4751975A GB1496378A GB 1496378 A GB1496378 A GB 1496378A GB 4751975 A GB4751975 A GB 4751975A GB 4751975 A GB4751975 A GB 4751975A GB 1496378 A GB1496378 A GB 1496378A
Authority
GB
United Kingdom
Prior art keywords
primary
alcohol
alcohols
oppenauer oxidation
allylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4751975A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SCM Corp
Original Assignee
SCM Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SCM Corp filed Critical SCM Corp
Publication of GB1496378A publication Critical patent/GB1496378A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups

Abstract

1496378 Oppenauer oxidation of primary alcohols SCM CORP 18 Nov 1975 [30 May 1975] 47519/75 Heading C2C The invention relates to an Oppenauer oxidation of primary alcohols selected from primary allylic alcohols substituted in at least the 2- position with a hydrocarbon radical; in which the allylic double bond is acyclic, exocyclic or endocyclic; and primary benzylic alcohols; to the corresponding aldehyde, in the presence of an Oppenauer oxidation catalyst and hydrogen acceptor under Oppenauer oxidation conditions, which comprises utilizing furfural as the hydrogen acceptor and forming a reaction product mixture containing the aldehyde corresponding to the primary alcohol, and as a by-product, furfuryl alcohol. Preferably the action is carried out with a molar ratio of furfural to primary alcohol in the range of 10 to 1 to 1 to 10. Examples of primary alcohol are perillyl alcohol, benzyl alcohol, methallyl alcohol, 2,6- dimethyl-2,7-octadiene-1-ol.
GB4751975A 1975-05-30 1975-11-18 Process for the oxidation of primary allylic and benzylic alcohols Expired GB1496378A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US58211375A 1975-05-30 1975-05-30

Publications (1)

Publication Number Publication Date
GB1496378A true GB1496378A (en) 1977-12-30

Family

ID=24327903

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4751975A Expired GB1496378A (en) 1975-05-30 1975-11-18 Process for the oxidation of primary allylic and benzylic alcohols

Country Status (2)

Country Link
CA (1) CA1067505A (en)
GB (1) GB1496378A (en)

Also Published As

Publication number Publication date
CA1067505A (en) 1979-12-04

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee