GB1494209A - Hydrolysis and gelation of organic silicates - Google Patents
Hydrolysis and gelation of organic silicatesInfo
- Publication number
- GB1494209A GB1494209A GB5122474A GB5122474A GB1494209A GB 1494209 A GB1494209 A GB 1494209A GB 5122474 A GB5122474 A GB 5122474A GB 5122474 A GB5122474 A GB 5122474A GB 1494209 A GB1494209 A GB 1494209A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixed
- vol
- per cent
- tributyltin
- diacetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/02—Polysilicates
Abstract
1494209 Silica gel ZIRCONAL PROCESSES Ltd 12 Nov 1975 [26 Nov 1974] 51224/74 Headings C1A and C1J [Also in Division C3] Organic silicates may be hydrolysed by contacting them with water under neutral conditions in the presence of an organotin compound wherein n is 1,2 or 3, R is alkyl or aryl, and X is an alkoxy, carboxylate or R 3 SnO- group. The product may be mixed with a refractory powder and shaped-for this use dibutyltin dilaurate or diacetate is preferred-or mixed with zinc dust to give a paint-for this bis(tributyltin)oxide is preferred, alone or with dibutyltin dialaurate. In examples 'Ethyl Silicate 40' or propyl or isopropyl orthosilicate is mixed with approximately 2-42 vol. per cent of bis(tripropyltin) or (tributyltin)oxide, or dibutyltin dilaurate or diacetate, 0-70 vol. per cent of water and 10, 20 or 150 vol. per cent of aqueous ethanol, based on the volume of silicate. The products are mixed with the aluminosilicate Molochite (2 gm./ml.) to give a slurry, used to build a ceramic shell by the stucco method (Example IX).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5122474A GB1494209A (en) | 1975-11-12 | 1975-11-12 | Hydrolysis and gelation of organic silicates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5122474A GB1494209A (en) | 1975-11-12 | 1975-11-12 | Hydrolysis and gelation of organic silicates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1494209A true GB1494209A (en) | 1977-12-07 |
Family
ID=10459124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5122474A Expired GB1494209A (en) | 1975-11-12 | 1975-11-12 | Hydrolysis and gelation of organic silicates |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1494209A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2393039A1 (en) * | 1976-08-26 | 1978-12-29 | Ameron Inc | SILOXANE-TIN COATING |
US4731264A (en) * | 1986-10-03 | 1988-03-15 | Ppg Industries, Inc. | Sol-gel compositions containing silane and alumina |
US4753827A (en) * | 1986-10-03 | 1988-06-28 | Ppg Industries, Inc. | Abrasion-resistant organosiloxane/metal oxide coating |
US4754012A (en) * | 1986-10-03 | 1988-06-28 | Ppg Industries, Inc. | Multi-component sol-gel protective coating composition |
US4799963A (en) * | 1986-10-03 | 1989-01-24 | Ppg Industries, Inc. | Optically transparent UV-protective coatings |
US4814017A (en) * | 1986-10-03 | 1989-03-21 | Ppg Industries, Inc. | Aqueous organoalkoxysilane/metal oxide sol-gel compositions |
US5401579A (en) * | 1987-12-16 | 1995-03-28 | Ppg Industries, Inc. | Siloxane organic hybrid polymers |
US6180248B1 (en) | 1987-12-16 | 2001-01-30 | Ppg Industries Ohio, Inc. | Siloxane organic hybrid polymers |
US6264859B1 (en) | 1986-10-03 | 2001-07-24 | Ppg Industries Ohio, Inc. | Optically transparent UV-protective coatings |
-
1975
- 1975-11-12 GB GB5122474A patent/GB1494209A/en not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2393039A1 (en) * | 1976-08-26 | 1978-12-29 | Ameron Inc | SILOXANE-TIN COATING |
US4731264A (en) * | 1986-10-03 | 1988-03-15 | Ppg Industries, Inc. | Sol-gel compositions containing silane and alumina |
US4753827A (en) * | 1986-10-03 | 1988-06-28 | Ppg Industries, Inc. | Abrasion-resistant organosiloxane/metal oxide coating |
US4754012A (en) * | 1986-10-03 | 1988-06-28 | Ppg Industries, Inc. | Multi-component sol-gel protective coating composition |
US4799963A (en) * | 1986-10-03 | 1989-01-24 | Ppg Industries, Inc. | Optically transparent UV-protective coatings |
US4814017A (en) * | 1986-10-03 | 1989-03-21 | Ppg Industries, Inc. | Aqueous organoalkoxysilane/metal oxide sol-gel compositions |
US6264859B1 (en) | 1986-10-03 | 2001-07-24 | Ppg Industries Ohio, Inc. | Optically transparent UV-protective coatings |
US6355189B1 (en) | 1986-10-03 | 2002-03-12 | Ppg Industries Ohio, Inc. | Optically transparent UV-protective coatings |
US5401579A (en) * | 1987-12-16 | 1995-03-28 | Ppg Industries, Inc. | Siloxane organic hybrid polymers |
US6180248B1 (en) | 1987-12-16 | 2001-01-30 | Ppg Industries Ohio, Inc. | Siloxane organic hybrid polymers |
US6469119B2 (en) | 1987-12-16 | 2002-10-22 | Ppg Industries Ohio, Inc. | Siloxane organic hybrid polymers |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |