GB1485708A - Electrolytic cell membranes - Google Patents

Electrolytic cell membranes

Info

Publication number
GB1485708A
GB1485708A GB42310/75A GB4231075A GB1485708A GB 1485708 A GB1485708 A GB 1485708A GB 42310/75 A GB42310/75 A GB 42310/75A GB 4231075 A GB4231075 A GB 4231075A GB 1485708 A GB1485708 A GB 1485708A
Authority
GB
United Kingdom
Prior art keywords
membrane
electrolytic cell
groups
oct
sulphonyl groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB42310/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Diamond Shamrock Corp
Original Assignee
Diamond Shamrock Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Diamond Shamrock Corp filed Critical Diamond Shamrock Corp
Publication of GB1485708A publication Critical patent/GB1485708A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2287After-treatment
    • C08J5/2293After-treatment of fluorine-containing membranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08J2371/12Polyphenylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

1485708 Cation exchange membranes DIAMOND SHAMROCK CORP 15 Oct 1975 [16 Oct 1974] 42310/75 Heading C3P [Also in Divisions B5 and C7] Cation exchange membranes for use in an electrolytic cell are obtained by surface treatment of a membrane comprising a fluorine-containing polymer having pendant sulphonyl groups with an ethylene diamine to convert the sulphonyl groups to a depth of 5-75 microns to the form on one side only, the remaining sulphonyl groups being converted to -SO 3 R where R is H, Na or K and R<SP>1</SP> is R or -SO 2 -. The membrane is preferably formed from a copolymer of tetrafluoroethylene and CF 2 = CFYfSO 2 F where Yf is a bivalent C 2 -C 8 perfluorinated radical. After treatment on one side with ethylene diamine, the membrane is further treated with alkali metal hydroxide to hydrolyse other -SO 2 F groups to -SO 3 R. The membrane is used in the electrolysis of brine with the treated surface facing the cathode.
GB42310/75A 1974-10-16 1975-10-15 Electrolytic cell membranes Expired GB1485708A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US51514574A 1974-10-16 1974-10-16

Publications (1)

Publication Number Publication Date
GB1485708A true GB1485708A (en) 1977-09-14

Family

ID=24050146

Family Applications (1)

Application Number Title Priority Date Filing Date
GB42310/75A Expired GB1485708A (en) 1974-10-16 1975-10-15 Electrolytic cell membranes

Country Status (20)

Country Link
JP (1) JPS5164495A (en)
AR (1) AR218606A1 (en)
AT (1) AT340447B (en)
BE (1) BE834517A (en)
BR (1) BR7506694A (en)
CS (1) CS193528B2 (en)
DD (1) DD121033A5 (en)
DE (1) DE2546194A1 (en)
FI (1) FI752858A (en)
FR (1) FR2288161A1 (en)
GB (1) GB1485708A (en)
HU (1) HU173979B (en)
IL (1) IL48306A (en)
IN (1) IN143622B (en)
IT (1) IT1047770B (en)
NL (1) NL7512112A (en)
PL (1) PL95782B1 (en)
RO (1) RO69556A (en)
SE (1) SE419453B (en)
ZA (1) ZA756520B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2302693B (en) * 1995-06-26 1999-03-10 Tokuyama Corp Fluorine-containing resin molded articles

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1166581B (en) * 1979-01-17 1987-05-05 Oronzio De Nora Impianti CATIONIC MEMBRANES BASED ON STYRENE DIVINYLBENZENE AND 2- OR 4-VINYLPYRIDINE OR ACRYLIC ACID SULPHONATED COPOLYMERS, PROCEDURE FOR THEIR PREPARATION AND USE IN ELECTROLYSIS CELLS
JPS5785826A (en) * 1980-11-17 1982-05-28 Japan Atom Energy Res Inst Cation exchange membrane
JP3307891B2 (en) * 1998-12-22 2002-07-24 株式会社豊田中央研究所 High heat-resistant polymer electrolyte and electrochemical device using the same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2437395C3 (en) * 1973-10-15 1979-02-08 E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) Film made from fluorine-containing polymers with side chains containing sulfonyl groups
US3969285A (en) * 1973-12-17 1976-07-13 E. I. Du Pont De Nemours And Company Heat-treated fluorocarbon sulfonylamine cation permselectivity
US4037148A (en) * 1975-08-15 1977-07-19 General Electric Company Ballast control device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2302693B (en) * 1995-06-26 1999-03-10 Tokuyama Corp Fluorine-containing resin molded articles

Also Published As

Publication number Publication date
ATA786775A (en) 1977-04-15
FR2288161B1 (en) 1978-04-07
BE834517A (en) 1976-04-15
DD121033A5 (en) 1976-07-12
RO69556A (en) 1980-08-15
DE2546194A1 (en) 1976-04-29
IT1047770B (en) 1980-10-20
IL48306A (en) 1978-09-29
AU8565675A (en) 1977-04-07
FR2288161A1 (en) 1976-05-14
AR218606A1 (en) 1980-06-30
ZA756520B (en) 1977-05-25
SE7511537L (en) 1976-04-20
HU173979B (en) 1979-10-28
IL48306A0 (en) 1975-12-31
NL7512112A (en) 1976-04-21
SE419453B (en) 1981-08-03
CS193528B2 (en) 1979-10-31
IN143622B (en) 1978-01-07
BR7506694A (en) 1976-08-17
FI752858A (en) 1976-04-17
AT340447B (en) 1977-12-12
PL95782B1 (en) 1977-11-30
JPS5164495A (en) 1976-06-03

Similar Documents

Publication Publication Date Title
GB1522877A (en) Process for producing alkali metal hydroxide by electrolysis
EG11807A (en) Composite cation exchange membrane and use thereof in electrolysis of an alkali metal halide
FR2333824A1 (en) CATION EXCHANGER FLUORINE MEMBRANE AND ITS APPLICATION FOR THE ELECTROLYSIS OF AN ALKALINE METAL HALOGENIDE
CA1133668B (en) Films of fluorinated polymer containing sulfonyl groups
ES8403983A1 (en) Preparing alkali metal hydroxide by water splitting and hydrolysis.
GB2094835B (en) Process for electrolyzing water
GB1421547A (en) Electrlysis cell and method
JPS55138086A (en) Preparation of hydrogen
ES419772A1 (en) Process for electrolyzing aqueous sodium or potassium ion solutions
FI752858A (en)
KR900016501A (en) Method for producing alkali metal dichromate and chromic acid by electrolysis
JPS5447877A (en) Electrolyzing method for alkali metal chloride
FR2288162B1 (en)
GB1557812A (en) Process and cell for the electrolytic production of hydroxide using ion exchange membranes
GB1468942A (en) Process and apparatus for electrolysis
JPS56108888A (en) Manufacture of alkali hydroxide and chlorine
SU799373A1 (en) METHOD FOR GETTING PERFLUORATED ION-EXCHANGE MEMBRANE
IT1056147B (en) Cation exchange membrane of fluoro polymer - with sulphonyl gps. modified by amination, for electrolysis of alkali chlorides
KR830002061A (en) Electrolytic method of alkali chloride
JPS5665989A (en) Electrolysis method of alkali metal halogenide
SU882192A1 (en) METHOD OF OBTAINING ION-EXCHANGE MEMBRANE
JPS57198278A (en) Production of hydrogen
JPS5662976A (en) Electrolyzing method of aqueous alkali chloride solution

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee