GB1484036A - Storage-stable moulding compositions for the manufacture of light-stable tracking-resistant plastics - Google Patents

Storage-stable moulding compositions for the manufacture of light-stable tracking-resistant plastics

Info

Publication number
GB1484036A
GB1484036A GB47848/74A GB4784874A GB1484036A GB 1484036 A GB1484036 A GB 1484036A GB 47848/74 A GB47848/74 A GB 47848/74A GB 4784874 A GB4784874 A GB 4784874A GB 1484036 A GB1484036 A GB 1484036A
Authority
GB
United Kingdom
Prior art keywords
aliphatic
adduct
moulding compositions
stable
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB47848/74A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB1484036A publication Critical patent/GB1484036A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
    • C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3236—Heterocylic compounds
    • C08G59/3245—Heterocylic compounds containing only nitrogen as a heteroatom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Organic Insulating Materials (AREA)

Abstract

1484036 Epoxy resin moulding compositions CIBA-GEIGY AG 5 Nov 1974 [6 Nov 1973] 47848/74 Heading C3B Storage stable moulding compositions contain : (A) an adduct containing epoxy groups, of a triglycidyl compound (in which X is an alkylene radical to form a 5- or 6-membered heterocycle and R is H or C 1-4 alkyl) and an organic compound (II) containing at least 2 active hydrogen atoms; (B) as curing agent, an adduct, containing amino groups, of a cycloaliphatic, aliphatic-cycloaliphatic, aromatic or heterocyclic polyamine and a polyglyoidyl compound; and (C) a mineral or organic, pulverulent or fibrous filler. (A) and (B) each soften at 45-120‹ C. and melt 5-30‹ C. above the softening point. The compositions may additionally contain a lubricant. (I) are described and claimed in Specification 1,380,602. (II) may be an aromatic-, C 2-10 aliphatic-cycloaliphaticaliphatic-, heterocyclic - aliphatic - primary amine; a mono- or bi-nuclear hydantoin or dihydrouracil; a dialcohol; a mono- or polynuclear dihydric phenol; or a dicarboxylic acid. A typical resin adduct is prepared by reacting cyclohexylamine with 3,3<SP>1</SP>-(2-glycidoxypropylene) - bis - (1 - glycidyl - 5,5 - dimethylhydantoin). Examples of curing agents are adducts of (a) 4,4<SP>1</SP> - diamino - dicyclohexylmethane and a diglycidyl ether of bisphenol-A; (b) 4,41-diamino - 3,3<SP>1</SP> - dimethyldicyclohexylmethane and the diglycidyl ester of 1,2-cyclohexanedicarboxylic acid. (A) and (B) may be prepared by reaction at 50-200‹ C. A catalyst may be present in preparing (A). Uses.-Electrical insulation.
GB47848/74A 1973-11-06 1974-11-05 Storage-stable moulding compositions for the manufacture of light-stable tracking-resistant plastics Expired GB1484036A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1559973A CH587305A5 (en) 1973-11-06 1973-11-06

Publications (1)

Publication Number Publication Date
GB1484036A true GB1484036A (en) 1977-08-24

Family

ID=4410439

Family Applications (1)

Application Number Title Priority Date Filing Date
GB47848/74A Expired GB1484036A (en) 1973-11-06 1974-11-05 Storage-stable moulding compositions for the manufacture of light-stable tracking-resistant plastics

Country Status (8)

Country Link
US (1) US3963667A (en)
JP (1) JPS5075699A (en)
CA (1) CA1039884A (en)
CH (1) CH587305A5 (en)
DE (1) DE2452265C2 (en)
ES (1) ES431635A1 (en)
FR (1) FR2249925B1 (en)
GB (1) GB1484036A (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH635604A5 (en) * 1978-06-22 1983-04-15 Ciba Geigy Ag MIXTURE BASED ON A HARDENABLE EPOXY RESIN, A HARDENER DAFUER AND A HARDENING ACCELERATOR.
CH637149A5 (en) * 1978-09-18 1983-07-15 Ciba Geigy Ag EPOXY RESIN MOLDS AND THEIR USE FOR THE PRODUCTION OF MOLDED BODIES.
US4228294A (en) * 1978-10-10 1980-10-14 Ppg Industries, Inc. Esters of imidazolidinedione-based diepoxides and coating compositions containing same
US4210744A (en) * 1978-12-11 1980-07-01 Ciba-Geigy Corporation Adducts containing epoxide groups, from hydantoin trisepoxides and binuclear hydantoins
US4221891A (en) * 1979-05-21 1980-09-09 Ppg Industries, Inc. Esters of imidazolidinedione-based triepoxides and coating compositions containing same
US4581422A (en) * 1985-05-06 1986-04-08 Texaco, Inc. Epoxy resin composition containing a curing agent which is a reaction product of cyanoguanidine, formaldehyde and an amine
US4581421A (en) * 1985-05-06 1986-04-08 Texaco, Inc. Epoxy resin composition containing a curing agent which is a reaction product of imidazole and an aldehyde
US4581423A (en) * 1985-05-06 1986-04-08 Texaco, Inc. Epoxy resin composition containing a curing agent which is a reaction product of hydantoins, formaldehyde and an amine
US4684678A (en) * 1985-05-30 1987-08-04 Minnesota Mining And Manufacturing Company Epoxy resin curing agent, process, and composition
US4691021A (en) * 1985-09-09 1987-09-01 The Dow Chemical Company Aminoalkyl hydantoins and glycidyl derivatives thereof
US4939227A (en) * 1989-05-15 1990-07-03 Shell Oil Company Novel thermoplastic polymers
JPH03236105A (en) * 1990-02-09 1991-10-22 Kazuyoshi Uematsu Sealing agent for insulation and rust prevention of conductor
DE59208804D1 (en) * 1991-04-04 1997-09-25 Ciba Geigy Ag Adducts from epoxides and amines
CN107501525B (en) * 2017-08-30 2020-06-09 本源精化环保科技有限公司 N, N' -alkylated diamino dicyclohexyl methane curing agent and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH500247A (en) * 1968-04-17 1970-12-15 Ciba Geigy Ag Process for the preparation of new adducts containing epoxy groups from polyepoxy compounds and binuclear N-heterocyclic compounds
CH547306A (en) * 1969-12-19 1974-03-29 Ciba Geigy Ag Process for the preparation of new, dinuclear N-HETEROCYCLIC POLYGLYCIDYL COMPOUNDS.

Also Published As

Publication number Publication date
CH587305A5 (en) 1977-04-29
ES431635A1 (en) 1976-11-01
FR2249925B1 (en) 1976-10-22
DE2452265C2 (en) 1984-05-24
CA1039884A (en) 1978-10-03
US3963667A (en) 1976-06-15
FR2249925A1 (en) 1975-05-30
JPS5075699A (en) 1975-06-20
DE2452265A1 (en) 1975-05-07

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee