GB1468142A - Process for the preparation of self-cross linking lacquers - Google Patents
Process for the preparation of self-cross linking lacquersInfo
- Publication number
- GB1468142A GB1468142A GB3852375A GB3852375A GB1468142A GB 1468142 A GB1468142 A GB 1468142A GB 3852375 A GB3852375 A GB 3852375A GB 3852375 A GB3852375 A GB 3852375A GB 1468142 A GB1468142 A GB 1468142A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- parts
- monomer
- salt
- theoretical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
1468142 Preparation of self cross-linking polymers LONZA Ltd 19 Sept 1975 38523/75 Addition to 1468141 Heading C3P A mixture of: (a) 30-70 parts by weight of a monomer or monomer mixture whose polymer has a theoretical Tg of less than 10‹ C.; (b) 30-70 parts by weight of a monomer or monomer mixture whose polymer has a theoretical Tg of more than 30‹ C.; (c) 0À5-5 parts by weight of a polymerizable carboxylic acid or a salt thereof; (d) 2-35 parts by weight of a di- or polyethylenically unsaturated monomer; and (e) 0À5-5 parts by weight of an alkali metal or ammonium salt of a polymerizable sulphonic acid is polymerized at 15-30‹ C. with a redox system comprising an alkali metal or ammonium persulphate, ascorbic acid and a ferrous salt at an initial pH of 3-4, at most 30% of the total monomer, together with the main amount of the persulphate being present initially and the remainder of the ingredients being so closed in that a preselected constant temperature (Œ1À5‹ C.) results. In the examples polymers are prepared from styrene, ethyl acrylate, methallyl sulphonate, butyl acrylate, octyl acrylate, acrylic acid, N-methylol acrylamide and as multi-unsaturated monomers, trimethylolpropane trimethacrylate, neopentyl glycol dimethacrylate and butanediol dimethacrylate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3852375A GB1468142A (en) | 1975-09-19 | 1975-09-19 | Process for the preparation of self-cross linking lacquers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3852375A GB1468142A (en) | 1975-09-19 | 1975-09-19 | Process for the preparation of self-cross linking lacquers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1468142A true GB1468142A (en) | 1977-03-23 |
Family
ID=10404047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3852375A Expired GB1468142A (en) | 1975-09-19 | 1975-09-19 | Process for the preparation of self-cross linking lacquers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1468142A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4278727A (en) * | 1977-10-20 | 1981-07-14 | Wacker-Chemie Gmbh | Alkai-soluble, water-resistant binders for non-woven materials |
-
1975
- 1975-09-19 GB GB3852375A patent/GB1468142A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4278727A (en) * | 1977-10-20 | 1981-07-14 | Wacker-Chemie Gmbh | Alkai-soluble, water-resistant binders for non-woven materials |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |