GB1462854A - Organic peroxidic compounds useful for the polymerisation or dopolymerisation of unsaturated esters - Google Patents
Organic peroxidic compounds useful for the polymerisation or dopolymerisation of unsaturated estersInfo
- Publication number
- GB1462854A GB1462854A GB3468676A GB3468676A GB1462854A GB 1462854 A GB1462854 A GB 1462854A GB 3468676 A GB3468676 A GB 3468676A GB 3468676 A GB3468676 A GB 3468676A GB 1462854 A GB1462854 A GB 1462854A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dihydroperoxy
- acid
- group
- branched
- plus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/20—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms
- C07C409/22—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms having two —O—O— groups bound to the carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/02—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1462854 Aldehyde- or ketone-peroxide derivatives AKZO NV 21 Dec 1973 [22 Dec 1972] 34686/76 Divided out of 1462853 Heading C2C An organic peroxidic compound having the formula wherein R 1 , R 2 , R 3 and R 4 may be the same or different and each represents a branched or unbranched alkyl group, if desired substituted by hydroxy, alkoxy, alkoxycarbonyl or halogen; an aryl group which may be substituted by alkyl, hydroxyl alkoxy or halogen or an arakyl group wherein the aryl part may be substituted by alkyl, hydroxy, alkoxy or halogen or wherein one or more of R 1 plus R 2 ; R 3 plus R 4 or R 1 plus R 4 may form a branched or unbranched alkylene group or wherein R 1 together with R 2 and R 3 may form a branched or unbranched alkylidene group is prepared by reacting carbonyl compounds of the formula with an aqueous solution of hydrogen peroxide in an organic solvent in which both the carbonyl compounds and the product peroxidic compound are soluble in the presence of an acid catalyst in an amount of 0À2 to 200 mg. equivalent per mole of carbonyl groups, removing water by distillation and, if desired, subsequently removing the acid catalyst. Many compounds which may be prepared by said method are listed. In the examples 3,6-diethyl-3,6-dihydroperoxy - 4,5 - dioxoctane; bis - (5 - methyl- 3 - hydroperoxyheptyl - 3,3<SP>1</SP> - peroxide); 7,10 - dihydroperoxy - 8,9 - dioxadecane, 12,15 - dihydroperoxy - 13,14 - dioxahexacosane or 2,7 - dimethyl - 3,6 - dihydroperoxy - 4,5- dioxaoctane is prepared by reacting diethyl ketone, ethyl isoamylketone, heptanal, dodecanal or isobutyraldehyde in benzene, diisobutylphthalate toluene or n-butyl acetate in the presence of an aqueous solution of hydrogen peroxide and p-toluene sulphonic acid, sulphuric acid or a strong acid ion exchanger and in some cases, after the distillation of water, the acid is removed by the addition of base or by filtration and the product further purified.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3468676A GB1462854A (en) | 1972-12-22 | 1973-12-21 | Organic peroxidic compounds useful for the polymerisation or dopolymerisation of unsaturated esters |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5939572A GB1462853A (en) | 1972-12-22 | 1972-12-22 | Polymerisation or copolymerisation of unsaturated esters |
GB3468676A GB1462854A (en) | 1972-12-22 | 1973-12-21 | Organic peroxidic compounds useful for the polymerisation or dopolymerisation of unsaturated esters |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1462854A true GB1462854A (en) | 1977-01-26 |
Family
ID=26262397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3468676A Expired GB1462854A (en) | 1972-12-22 | 1973-12-21 | Organic peroxidic compounds useful for the polymerisation or dopolymerisation of unsaturated esters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1462854A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2445341A1 (en) * | 1978-12-29 | 1980-07-25 | Montedison Spa | |
WO2004076405A1 (en) * | 2003-02-28 | 2004-09-10 | Degussa Initiators Gmbh & Co. Kg | Method for the production of trimeric ketone peroxide solutions |
-
1973
- 1973-12-21 GB GB3468676A patent/GB1462854A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2445341A1 (en) * | 1978-12-29 | 1980-07-25 | Montedison Spa | |
WO2004076405A1 (en) * | 2003-02-28 | 2004-09-10 | Degussa Initiators Gmbh & Co. Kg | Method for the production of trimeric ketone peroxide solutions |
US7247754B2 (en) | 2003-02-28 | 2007-07-24 | Degussa Initiators Gmbh & Co. Kg. | Method for the production of trimeric ketone peroxide solutions |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |