GB1380675A - N-acylaminomethyl-phosphonates and their use as flame-proofing agents - Google Patents
N-acylaminomethyl-phosphonates and their use as flame-proofing agentsInfo
- Publication number
- GB1380675A GB1380675A GB1789573A GB1789573A GB1380675A GB 1380675 A GB1380675 A GB 1380675A GB 1789573 A GB1789573 A GB 1789573A GB 1789573 A GB1789573 A GB 1789573A GB 1380675 A GB1380675 A GB 1380675A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- formula
- methyl
- compounds
- optionally substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052739 hydrogen Inorganic materials 0.000 abstract 6
- 239000001257 hydrogen Substances 0.000 abstract 6
- 150000002431 hydrogen Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000005843 halogen group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- -1 dimethylamino, diethylamino, acetoxy Chemical group 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Toxicology (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
Abstract
1380675 N-Acylaminomethylphosphonic acid derivatives BAYER AG 13 April 1973 [13 April 1972] 17895/73 Heading C2P [Also in Division D1] Compounds of Formula I: where R is hydrogen, methyl, (C 1-4 alkoxy) carbonyl or a radical of formula R1 is hydrogen or methyl, R 2 is hydrogen, C 1-4 alkyl optionally substituted by one or more OH groups and/or halogen atoms, or C 3-4 alkenyl, and R 3 and R 4 are hydrogen, alkali metal, alkaline earth metal, ammonium or C 1-4 alkyl optionally substituted by one or more halogen atoms, or together with the adjacent oxygen atoms and the phosphorus atom form a 5- to 7-membered ring, which compounds are used as flame-proofing agents, are prepared by reacting a compound of Formula II: where R<SP>1</SP> is hydrogen, methyl, (C 1-4 alkoxy)- carbonyl or -CO-N(R 2 )-CH 2 X and X is halogen, OH, dimethylamino, diethylamino, acetoxy or propionyloxy with an ester of Formula III: where R 3 , R 4 and R 5 are C 1-4 alkyl, optionally substituted by one or more halogen atoms or R 3 and R 4 together with the adjacent oxygen atoms and the phosphorus atom form a 5- to 7- membered ring, and optionally hydrolysing the ester formed to give the free acid and neutralizing to form the salts. Compounds of Formula I, in which, when R, R 1 and R 2 are all hydrogen, R 3 and R 4 are not both unsubstituted alkyl are claimed per se.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722217746 DE2217746A1 (en) | 1972-04-13 | 1972-04-13 | N-ACYLAMINO-METHYL-PHOSPHONATE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1380675A true GB1380675A (en) | 1975-01-15 |
Family
ID=5841797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1789573A Expired GB1380675A (en) | 1972-04-13 | 1973-04-13 | N-acylaminomethyl-phosphonates and their use as flame-proofing agents |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS499891A (en) |
| BE (1) | BE798178A (en) |
| DE (1) | DE2217746A1 (en) |
| FR (1) | FR2180102B1 (en) |
| GB (1) | GB1380675A (en) |
| IT (1) | IT980150B (en) |
| NL (1) | NL7305151A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4774349A (en) * | 1985-11-13 | 1988-09-27 | Rohm Gmbh Chemische Fabrik | Method of preparing N-methylphosphonic acid diesters of acrylic and methacrylic acid amines from methylol |
| US5429674A (en) * | 1994-09-12 | 1995-07-04 | Ppg Industries, Inc. | N-acyl aminomethylene phosphonates and their use in waterborne coating compositions |
| WO2007006648A1 (en) * | 2005-07-08 | 2007-01-18 | Ciba Specialty Chemicals Holding Inc. | (meth)acrylamide phosphorus monomer composition |
| US7452487B2 (en) * | 2004-02-24 | 2008-11-18 | Uni-Chemical Co., Ltd. | Phosphorus-acid-group-containing (meth) acrylamide, its polymer and use thereof, and their production methods |
| CN109232785A (en) * | 2018-08-06 | 2019-01-18 | 台启龙 | Flame-retardant polypropelene acid esters lotion and preparation method thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3210775A1 (en) * | 1982-03-24 | 1983-09-29 | Hoechst Ag, 6230 Frankfurt | 2-ACRYLAMIDO-2-METHYL-PROPANPHOSPHONIC ACID AND ITS SALTS, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR THE PRODUCTION OF COPOLYMERS |
| DE3540216C2 (en) * | 1985-11-13 | 1994-06-16 | Roehm Gmbh | Process for the preparation of N-methylphosphonic diesters of acrylic or methacrylic acid amides from methylol compounds |
| FR2891548B1 (en) * | 2005-10-05 | 2010-08-27 | Solvay | AQUEOUS DISPERSION COMPRISING AT LEAST ONE POLYMER OF VINYLIDENE CHLORIDE AND AT LEAST ONE COPOLYMER |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU464305B2 (en) * | 1971-03-29 | 1975-08-05 | Hooker Chemicals & Plastics Corporation | N-phosphonomethyl acrylamides |
-
1972
- 1972-04-13 DE DE19722217746 patent/DE2217746A1/en active Pending
-
1973
- 1973-04-09 JP JP3963273A patent/JPS499891A/ja active Pending
- 1973-04-11 IT IT4935173A patent/IT980150B/en active
- 1973-04-12 NL NL7305151A patent/NL7305151A/xx unknown
- 1973-04-13 FR FR7313545A patent/FR2180102B1/fr not_active Expired
- 1973-04-13 GB GB1789573A patent/GB1380675A/en not_active Expired
- 1973-04-13 BE BE129977A patent/BE798178A/en unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4774349A (en) * | 1985-11-13 | 1988-09-27 | Rohm Gmbh Chemische Fabrik | Method of preparing N-methylphosphonic acid diesters of acrylic and methacrylic acid amines from methylol |
| US5429674A (en) * | 1994-09-12 | 1995-07-04 | Ppg Industries, Inc. | N-acyl aminomethylene phosphonates and their use in waterborne coating compositions |
| WO1996008518A1 (en) * | 1994-09-12 | 1996-03-21 | Ppg Industries, Inc. | N-acyl aminomethylene phosphonates and their use in waterborne coating compositions |
| US7452487B2 (en) * | 2004-02-24 | 2008-11-18 | Uni-Chemical Co., Ltd. | Phosphorus-acid-group-containing (meth) acrylamide, its polymer and use thereof, and their production methods |
| WO2007006648A1 (en) * | 2005-07-08 | 2007-01-18 | Ciba Specialty Chemicals Holding Inc. | (meth)acrylamide phosphorus monomer composition |
| CN101218267B (en) * | 2005-07-08 | 2011-07-13 | 西巴特殊化学品控股有限公司 | (Meth)acrylamide phosphorus monomer compositions |
| US8105689B2 (en) | 2005-07-08 | 2012-01-31 | Basf Se | Adhesive, coating or film composition applied to a surface |
| CN109232785A (en) * | 2018-08-06 | 2019-01-18 | 台启龙 | Flame-retardant polypropelene acid esters lotion and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| IT980150B (en) | 1974-09-30 |
| DE2217746A1 (en) | 1973-10-25 |
| NL7305151A (en) | 1973-10-16 |
| BE798178A (en) | 1973-10-15 |
| FR2180102A1 (en) | 1973-11-23 |
| FR2180102B1 (en) | 1976-11-12 |
| JPS499891A (en) | 1974-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 48R | Reference inserted (sect. 8/1949) | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |