GB1442117A - Dehydrochlorination of 1,2-dichloroethane - Google Patents
Dehydrochlorination of 1,2-dichloroethaneInfo
- Publication number
- GB1442117A GB1442117A GB367175A GB367175A GB1442117A GB 1442117 A GB1442117 A GB 1442117A GB 367175 A GB367175 A GB 367175A GB 367175 A GB367175 A GB 367175A GB 1442117 A GB1442117 A GB 1442117A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dichloroethane
- vinyl chloride
- ethane
- dehydrochlorination
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 title abstract 3
- 238000007033 dehydrochlorination reaction Methods 0.000 title abstract 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 abstract 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910001510 metal chloride Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/04—Chloro-alkenes
- C07C21/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1442117 Vinyl chloride production LUMMUS CO 28 Jan 1975 [30 Jan 1974] 3671/75 Heading C2C Vinyl chloride is produced by the dehydrochlorination of 1,2-dichloroethane by direct contact with a molten salt containing a multivalent metal chloride in its higher and lower valence state in the presence of ethane in a weight ratio of ethane to dichloroethane of 0À01-0À15 : 1. Suitable metals are Cu, Cr, Co, Fe and Mn but Cu is particularly preferred optionally with the oxychloride present also. The reaction is usually conducted at 700- 1200‹ F. in the presence of inhibitor for the dehydrochlorination of vinyl chloride, e.g. trichloroethylene. In an example a feed containing mainly 1,2-dichloroethane (78À3 mole per cent) trichloroethylene (11À1%) and ethane (9À4%) gives vinyl chloride with a selectivity of 90À4 mole per cent and dichloroethane conversion of 80 mole per cent.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43798574A | 1974-01-30 | 1974-01-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1442117A true GB1442117A (en) | 1976-07-07 |
Family
ID=23738752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB367175A Expired GB1442117A (en) | 1974-01-30 | 1975-01-28 | Dehydrochlorination of 1,2-dichloroethane |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS598244B2 (en) |
| AR (1) | AR203062A1 (en) |
| BE (1) | BE824948A (en) |
| BR (1) | BR7500570A (en) |
| CA (1) | CA1043359A (en) |
| DE (1) | DE2502335A1 (en) |
| ES (1) | ES434238A1 (en) |
| FR (1) | FR2259075B1 (en) |
| GB (1) | GB1442117A (en) |
| IT (1) | IT1031224B (en) |
| NL (1) | NL7501027A (en) |
| SE (1) | SE7500942L (en) |
| TR (1) | TR18490A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0015665A1 (en) * | 1979-03-02 | 1980-09-17 | Imperial Chemical Industries Plc | Manufacture of vinyl chloride |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0350936U (en) * | 1989-09-26 | 1991-05-17 | ||
| FR2897482B1 (en) | 2006-02-10 | 2010-10-29 | Cogema | DEVICE FOR TRANSPORTING ELECTRICITY WITH HIGH CURRENT AND HIGH FREQUENCY |
-
1975
- 1975-01-21 DE DE19752502335 patent/DE2502335A1/en not_active Withdrawn
- 1975-01-27 TR TR1849075A patent/TR18490A/en unknown
- 1975-01-28 JP JP1105975A patent/JPS598244B2/en not_active Expired
- 1975-01-28 GB GB367175A patent/GB1442117A/en not_active Expired
- 1975-01-28 IT IT1967675A patent/IT1031224B/en active
- 1975-01-29 NL NL7501027A patent/NL7501027A/en not_active Application Discontinuation
- 1975-01-29 BR BR7500570A patent/BR7500570A/en unknown
- 1975-01-29 CA CA218,969A patent/CA1043359A/en not_active Expired
- 1975-01-29 AR AR25745675A patent/AR203062A1/en active
- 1975-01-29 ES ES434238A patent/ES434238A1/en not_active Expired
- 1975-01-29 SE SE7500942A patent/SE7500942L/xx not_active Application Discontinuation
- 1975-01-29 BE BE152854A patent/BE824948A/en not_active IP Right Cessation
- 1975-01-30 FR FR7502963A patent/FR2259075B1/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0015665A1 (en) * | 1979-03-02 | 1980-09-17 | Imperial Chemical Industries Plc | Manufacture of vinyl chloride |
Also Published As
| Publication number | Publication date |
|---|---|
| AR203062A1 (en) | 1975-08-08 |
| BE824948A (en) | 1975-05-15 |
| ES434238A1 (en) | 1976-12-16 |
| IT1031224B (en) | 1979-04-30 |
| JPS50106908A (en) | 1975-08-22 |
| TR18490A (en) | 1977-02-24 |
| FR2259075B1 (en) | 1978-06-23 |
| NL7501027A (en) | 1975-08-01 |
| FR2259075A1 (en) | 1975-08-22 |
| SE7500942L (en) | 1975-07-31 |
| BR7500570A (en) | 1975-11-11 |
| JPS598244B2 (en) | 1984-02-23 |
| DE2502335A1 (en) | 1975-07-31 |
| CA1043359A (en) | 1978-11-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |