GB1436713A - Process for producing halogenated organotin compounds - Google Patents
Process for producing halogenated organotin compoundsInfo
- Publication number
- GB1436713A GB1436713A GB2055473A GB2055473A GB1436713A GB 1436713 A GB1436713 A GB 1436713A GB 2055473 A GB2055473 A GB 2055473A GB 2055473 A GB2055473 A GB 2055473A GB 1436713 A GB1436713 A GB 1436713A
- Authority
- GB
- United Kingdom
- Prior art keywords
- component
- chloride
- alkyl
- iodine
- bromine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 239000000306 component Substances 0.000 abstract 5
- 229910052794 bromium Inorganic materials 0.000 abstract 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 3
- 229910052740 iodine Inorganic materials 0.000 abstract 3
- 239000011630 iodine Substances 0.000 abstract 3
- -1 phosphorus compound Chemical class 0.000 abstract 3
- 125000006545 (C1-C9) alkyl group Chemical group 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 abstract 1
- GTLWADFFABIGAE-UHFFFAOYSA-N 1-chloroethylbenzene Chemical class CC(Cl)C1=CC=CC=C1 GTLWADFFABIGAE-UHFFFAOYSA-N 0.000 abstract 1
- CNDHHGUSRIZDSL-UHFFFAOYSA-N 1-chlorooctane Chemical group CCCCCCCCCl CNDHHGUSRIZDSL-UHFFFAOYSA-N 0.000 abstract 1
- WLVCBAMXYMWGLJ-UHFFFAOYSA-N 3-(chloromethyl)heptane Chemical compound CCCCC(CC)CCl WLVCBAMXYMWGLJ-UHFFFAOYSA-N 0.000 abstract 1
- NPDACUSDTOMAMK-UHFFFAOYSA-N 4-Chlorotoluene Chemical compound CC1=CC=C(Cl)C=C1 NPDACUSDTOMAMK-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- UNFUYWDGSFDHCW-UHFFFAOYSA-N monochlorocyclohexane Chemical compound ClC1CCCCC1 UNFUYWDGSFDHCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1436713 Preparing organotin halides SUMITOMO CHEMICAL CO Ltd and KYODO CHEMICAL CO Ltd 30 April 1973 [28 April 1972 3 Aug 1972] 20554/73 Heading C2J Organotin halides of general formula where R is C 1-18 alkyl, cycloalkyl, phenyl optionally substituted by C 1-9 alkyl or halogen, benzyl optionally substituted by C 1-9 alkyl, or C 2-18 alkenyl, X is Cl or Br and m is 1, 2 or 3 are prepared by reacting RX with metallic tin in the presence of, as a first component, (1) a mixture of (a) a phosphorus compound with (b) a primary, secondary or tertiary amine, an organic or inorganic quaternary ammonium salt, an N-containing heterocycle, an acid amide, guanidine compound, or dithiocarbamic acid, or (2) a nitrogen-containing phosphorus compound, together with, as a second component, bromine, iodine or compounds thereof which can evolve bromine or iodine under the reaction conditions (the second component not however being necessary when such an iodine or bromine precursor is used as the first component) and as a third component, a cyclic or linear ether, a ketone, alcohol, ester, thioalcohol or thioether. The reaction is usually effected at 130-230‹ C. for 3-20 hours and in a mole ratio of RX to tin of from 1À5 : 1 to 5 : 1. In the examples, RX is n-octyl chloride and bromide, n-butyl chloride and bromide, cyclohexyl chloride, 2-ethylhexyl chloride, benzyl and methylbenzyl chlorides, chlorobenzene and p-chlorotoluene. Reference has been directed by the Comptroller to Specification 1,053,996.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP47043129A JPS5220977B2 (en) | 1972-04-28 | 1972-04-28 | |
| JP7810972A JPS525483B2 (en) | 1972-08-03 | 1972-08-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1436713A true GB1436713A (en) | 1976-05-26 |
Family
ID=26382878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2055473A Expired GB1436713A (en) | 1972-04-28 | 1973-04-30 | Process for producing halogenated organotin compounds |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2321402C2 (en) |
| FR (1) | FR2182231B1 (en) |
| GB (1) | GB1436713A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114736236A (en) * | 2022-03-21 | 2022-07-12 | 中国科学院福建物质结构研究所 | Polynuclear cyclic organotin-oxygen-sulfur cluster compound and preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU85384A1 (en) * | 1984-05-28 | 1986-02-18 | Tessenderlo Chem Nv | TIN RECOVERY PROCESS |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD79015A (en) * | ||||
| GB1053996A (en) * | 1963-04-18 | 1900-01-01 | ||
| FR1393779A (en) * | 1963-04-18 | 1965-03-26 | Nitto Chemical Industry Co Ltd | Process for the preparation of alkyltin halides |
| US3340283A (en) * | 1964-05-20 | 1967-09-05 | M & T Chemicals Inc | Preparation of organotin-trihalides |
-
1973
- 1973-04-27 FR FR7315556A patent/FR2182231B1/fr not_active Expired
- 1973-04-27 DE DE2321402A patent/DE2321402C2/en not_active Expired
- 1973-04-30 GB GB2055473A patent/GB1436713A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114736236A (en) * | 2022-03-21 | 2022-07-12 | 中国科学院福建物质结构研究所 | Polynuclear cyclic organotin-oxygen-sulfur cluster compound and preparation method and application thereof |
| CN114736236B (en) * | 2022-03-21 | 2023-09-29 | 中国科学院福建物质结构研究所 | Polynuclear annular organotin oxygen sulfur cluster compound and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2321402C2 (en) | 1983-01-05 |
| FR2182231A1 (en) | 1973-12-07 |
| DE2321402A1 (en) | 1973-11-15 |
| FR2182231B1 (en) | 1977-04-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |