GB1434232A - Method of producing cellulose pulp by means of oxygen gas delignification - Google Patents
Method of producing cellulose pulp by means of oxygen gas delignificationInfo
- Publication number
- GB1434232A GB1434232A GB3194173A GB3194173A GB1434232A GB 1434232 A GB1434232 A GB 1434232A GB 3194173 A GB3194173 A GB 3194173A GB 3194173 A GB3194173 A GB 3194173A GB 1434232 A GB1434232 A GB 1434232A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pretreatment
- digestion
- alkali
- acid
- lignocellulosic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/26—Multistage processes
- D21C3/263—Multistage processes at least one stage being in presence of oxygen
Landscapes
- Paper (AREA)
Abstract
1434232 Producing cellulose pulp MO OCH DOMSJO AB 4 July 1973 [5 July 1972] 31941/73 Heading D2W A method of producing cellulose pulp comprises pretreating a lignocellulosic material with a liquor containing an alkali at 60-200‹C until 1-30% by weight of the dry weight of the lignocellulosic material has passed into solution, and then digesting the lignocellulosic material with oxygen in the presence of an alkali containing aqueous solution at 100- 180‹C and an oxygen partial pressure of 3-200 bars, the pH being maintained at 6-9 during the major part of the oxygen digestion. The Dre-treatment may be carried out at a pH of 7-14 and a pressure of 1-20 bars, and may be a continuous or a discontinuous process, the alkali being added in one or more batches or added continuously. The alkali material may may be sodium hydroxide, sodium carbonate and/or sodium bicarbonate, and the corresponding compounds of calcium and magnesium may also be present. Sodium carbonate and bicarbonate for use in the pretreatment may be obtained by combustion of the waste liquors from either the pretreatment or the digestion, and absorption of carbon dioxide produced in the digestion. The pretreatment liquor may contain waste liquors from both steps, and may also contain waste sulphide liquor from other cooking processes. To produce a low bernicellulose content in the final product, the pretreatment may be combined with an acid pre-hydrolysis which may be a separate step or achieved by allowing the pH to fall temporarily in the pretreatment. Air may be removed during the pretreatment, and a surface tension reducing agent, a peroxide brightener, a reducing agent such as dithionite and/or hydridoborate, and metal complexing agent may be added, the latter during or after the pretreatment. Suitable complexing agents are polyphosphates, aminocarboxylic acids, ethylenediamine tetraacetic acid, nitrilotriacetic acid, diethylenetriamine pentaacetic acid, gluconic acid, saccharic acid and ethylenediamine. The product of the pretreatment may be drained or washed with waste liquor from the digestion step, roll pressed and peg shredded before passing to the digestion. The alkali used in the digestion may be sodium carbonate and/or sodium bicarbonate, optionally replenished with sodium hydroxide. The carbon dioxide pressure may be 0.2 to 5 bars and excess carbon dioxide may be removed by venting, cooling or absorption in sodium carbonate solution, optionally containing sodium hydroxide. A surface tension reducing agent, a foam prevention agent and an inhibitor against carbohydrate decomposition may be present during the digestion. The digestion may be carried out with the lignocellulosic material immersed in or sprayed with the solution. Alternatively, the lignocellulosic material may be impregnated with the solution, drained, and then contacted with the oxygen. Suitable lignocellulosic materials are sawdust, wood shavings, wood chips (e.g. birch chips) straw and bagasse. The wood chips may be split in a shredder.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE7208879A SE373896B (en) | 1972-07-05 | 1972-07-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1434232A true GB1434232A (en) | 1976-05-05 |
Family
ID=20275256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3194173A Expired GB1434232A (en) | 1972-07-05 | 1973-07-04 | Method of producing cellulose pulp by means of oxygen gas delignification |
Country Status (11)
Country | Link |
---|---|
AT (1) | AT328286B (en) |
BR (1) | BR7304978D0 (en) |
CA (1) | CA1018707A (en) |
CH (1) | CH583333A5 (en) |
FI (1) | FI55061C (en) |
FR (1) | FR2190974B1 (en) |
GB (1) | GB1434232A (en) |
IT (1) | IT996577B (en) |
NO (1) | NO140535C (en) |
SE (1) | SE373896B (en) |
ZA (1) | ZA734384B (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU591508B2 (en) * | 1985-08-05 | 1989-12-07 | Interox Societe Anonyme | Process for the delignification of cellulosic substances |
AU591509B2 (en) * | 1985-08-05 | 1989-12-07 | Interox Societe Anonyme | Process for the delignification of cellulosic substances |
WO2000047812A1 (en) * | 1999-02-15 | 2000-08-17 | Kiram Ab | Process for oxygen pulping of lignocellulosic material and recovery of pulping chemicals |
WO2001059204A1 (en) * | 2000-02-14 | 2001-08-16 | Kiram Ab | Process for oxygen pulping of lignocellulosic material and recovery of pulping chemicals |
WO2006127880A2 (en) * | 2005-05-24 | 2006-11-30 | International Paper Company | Modified kraft fibers |
US7520958B2 (en) | 2005-05-24 | 2009-04-21 | International Paper Company | Modified kraft fibers |
US7771565B2 (en) | 2006-02-21 | 2010-08-10 | Packaging Corporation Of America | Method of pre-treating woodchips prior to mechanical pulping |
US8715969B2 (en) | 2008-11-20 | 2014-05-06 | E I Du Pont De Nemours And Company | Delignification of biomass with sequential base treatment |
CN108166089A (en) * | 2017-12-28 | 2018-06-15 | 潍坊友容实业有限公司 | A kind of method that false indigo using salt-soda soil plantation prepares regenerated cellulose |
CN108360277A (en) * | 2017-12-28 | 2018-08-03 | 潍坊友容实业有限公司 | A kind of false indigo using salt-soda soil plantation extracts the process of cellulose |
CN112852900A (en) * | 2019-11-27 | 2021-05-28 | 中国石油天然气股份有限公司 | Pretreatment method and enzymolysis method of lignocellulose raw material |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2282500A1 (en) * | 1974-08-20 | 1976-03-19 | Grp Europ De Cellulose | Paper pulp is de-lignified by heating with alkali - followed by oxidation with oxidising liquid and pressurised oxygen |
IT1209352B (en) * | 1980-09-22 | 1989-07-16 | Nardi Franco | PROCESS FOR THE PRODUCTION OF CHEMICAL CELLULOSE AND / OR PAPER PASTES, AS WELL AS THE PLANT AND ITS COMPONENTS FOR THE IMPLEMENTATION OF THE INDICATED PROCESS |
US8440052B2 (en) * | 2006-01-25 | 2013-05-14 | Nalco Company | Method and arrangement for feeding chemicals into a pulp process stream |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE335053B (en) * | 1969-05-13 | 1971-05-10 | Mo Och Domsjoe Ab | |
CA895756A (en) * | 1970-04-03 | 1972-03-21 | Macmillan Bloedel Limited | Two-stage soda-oxygen pulping |
SE343092B (en) * | 1970-06-22 | 1972-02-28 | Mo Och Domsjoe Ab |
-
1972
- 1972-07-05 SE SE7208879A patent/SE373896B/xx unknown
-
1973
- 1973-06-07 FI FI1861/73A patent/FI55061C/en active
- 1973-06-18 NO NO2523/73A patent/NO140535C/en unknown
- 1973-06-27 ZA ZA734384A patent/ZA734384B/en unknown
- 1973-07-03 CA CA175,525A patent/CA1018707A/en not_active Expired
- 1973-07-04 GB GB3194173A patent/GB1434232A/en not_active Expired
- 1973-07-04 BR BR4978/73A patent/BR7304978D0/en unknown
- 1973-07-04 CH CH974473A patent/CH583333A5/xx not_active IP Right Cessation
- 1973-07-04 FR FR7324595A patent/FR2190974B1/fr not_active Expired
- 1973-07-04 IT IT68986/73A patent/IT996577B/en active
- 1973-07-04 AT AT591173A patent/AT328286B/en active
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU591509B2 (en) * | 1985-08-05 | 1989-12-07 | Interox Societe Anonyme | Process for the delignification of cellulosic substances |
AU591508B2 (en) * | 1985-08-05 | 1989-12-07 | Interox Societe Anonyme | Process for the delignification of cellulosic substances |
WO2000047812A1 (en) * | 1999-02-15 | 2000-08-17 | Kiram Ab | Process for oxygen pulping of lignocellulosic material and recovery of pulping chemicals |
US6770168B1 (en) | 1999-02-15 | 2004-08-03 | Kiram Ab | Process for oxygen pulping of lignocellulosic material and recorvery of pulping chemicals |
WO2001059204A1 (en) * | 2000-02-14 | 2001-08-16 | Kiram Ab | Process for oxygen pulping of lignocellulosic material and recovery of pulping chemicals |
US8328983B2 (en) | 2005-05-24 | 2012-12-11 | International Paper Company | Modified kraft fibers |
WO2006127880A2 (en) * | 2005-05-24 | 2006-11-30 | International Paper Company | Modified kraft fibers |
WO2006127880A3 (en) * | 2005-05-24 | 2007-03-08 | Int Paper Co | Modified kraft fibers |
US7520958B2 (en) | 2005-05-24 | 2009-04-21 | International Paper Company | Modified kraft fibers |
US8182650B2 (en) | 2005-05-24 | 2012-05-22 | International Paper Company | Modified Kraft fibers |
US7771565B2 (en) | 2006-02-21 | 2010-08-10 | Packaging Corporation Of America | Method of pre-treating woodchips prior to mechanical pulping |
US8715969B2 (en) | 2008-11-20 | 2014-05-06 | E I Du Pont De Nemours And Company | Delignification of biomass with sequential base treatment |
CN108166089A (en) * | 2017-12-28 | 2018-06-15 | 潍坊友容实业有限公司 | A kind of method that false indigo using salt-soda soil plantation prepares regenerated cellulose |
CN108360277A (en) * | 2017-12-28 | 2018-08-03 | 潍坊友容实业有限公司 | A kind of false indigo using salt-soda soil plantation extracts the process of cellulose |
CN108360277B (en) * | 2017-12-28 | 2019-12-31 | 潍坊友容实业有限公司 | Process method for extracting cellulose by utilizing amorpha fruticosa planted in saline-alkali soil |
CN108166089B (en) * | 2017-12-28 | 2020-07-07 | 潍坊友容实业有限公司 | Method for preparing regenerated cellulose by utilizing amorpha fruticosa planted in saline-alkali soil |
CN112852900A (en) * | 2019-11-27 | 2021-05-28 | 中国石油天然气股份有限公司 | Pretreatment method and enzymolysis method of lignocellulose raw material |
Also Published As
Publication number | Publication date |
---|---|
FR2190974A1 (en) | 1974-02-01 |
SE373896B (en) | 1975-02-17 |
ZA734384B (en) | 1974-06-26 |
DE2333742A1 (en) | 1974-01-24 |
AT328286B (en) | 1976-03-10 |
CH583333A5 (en) | 1976-12-31 |
NO140535C (en) | 1979-09-19 |
DE2333742B2 (en) | 1975-11-27 |
CA1018707A (en) | 1977-10-11 |
FI55061B (en) | 1979-01-31 |
NO140535B (en) | 1979-06-11 |
FI55061C (en) | 1979-05-10 |
ATA591173A (en) | 1975-05-15 |
IT996577B (en) | 1975-12-10 |
BR7304978D0 (en) | 1974-09-05 |
FR2190974B1 (en) | 1975-08-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |