GB1429471A - Process for the production of phthalic acids - Google Patents
Process for the production of phthalic acidsInfo
- Publication number
- GB1429471A GB1429471A GB5149971A GB5149971A GB1429471A GB 1429471 A GB1429471 A GB 1429471A GB 5149971 A GB5149971 A GB 5149971A GB 5149971 A GB5149971 A GB 5149971A GB 1429471 A GB1429471 A GB 1429471A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stage
- acid
- solvent
- oxidation
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000003022 phthalic acids Chemical class 0.000 title 1
- 230000003647 oxidation Effects 0.000 abstract 6
- 238000007254 oxidation reaction Methods 0.000 abstract 6
- 239000002904 solvent Substances 0.000 abstract 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229940011182 cobalt acetate Drugs 0.000 abstract 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 150000002531 isophthalic acids Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003504 terephthalic acids Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10251470A | 1970-12-29 | 1970-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1429471A true GB1429471A (en) | 1976-03-24 |
Family
ID=22290267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5149971A Expired GB1429471A (en) | 1970-12-29 | 1971-11-05 | Process for the production of phthalic acids |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE776267A (enExample) |
| DE (1) | DE2158279A1 (enExample) |
| FR (1) | FR2120749A5 (enExample) |
| GB (1) | GB1429471A (enExample) |
| IT (1) | IT945355B (enExample) |
| NL (1) | NL7116938A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005051881A1 (en) * | 2003-11-14 | 2005-06-09 | Bp Corporation North America Inc. | Staged countercurrent catalytic oxidation of disubstituted bemzene |
| CN109369369A (zh) * | 2018-12-18 | 2019-02-22 | 华东理工大学 | 间苯二甲酸的制备方法 |
| CN109485557A (zh) * | 2018-12-18 | 2019-03-19 | 华东理工大学 | 一种间苯二甲酸的制备工艺 |
| CN109503369A (zh) * | 2018-12-18 | 2019-03-22 | 华东理工大学 | 一种间苯二甲酸的制备方法 |
-
1971
- 1971-11-05 GB GB5149971A patent/GB1429471A/en not_active Expired
- 1971-11-24 DE DE19712158279 patent/DE2158279A1/de active Pending
- 1971-12-03 FR FR7143493A patent/FR2120749A5/fr not_active Expired
- 1971-12-06 BE BE776267A patent/BE776267A/xx unknown
- 1971-12-09 IT IT5463271A patent/IT945355B/it active
- 1971-12-09 NL NL7116938A patent/NL7116938A/xx unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005051881A1 (en) * | 2003-11-14 | 2005-06-09 | Bp Corporation North America Inc. | Staged countercurrent catalytic oxidation of disubstituted bemzene |
| RU2374219C2 (ru) * | 2003-11-14 | 2009-11-27 | Бп Корпорейшн Норт Америка Инк. | Ступенчатое противоточное каталитическое окисление дизамещенного бензола |
| CN109369369A (zh) * | 2018-12-18 | 2019-02-22 | 华东理工大学 | 间苯二甲酸的制备方法 |
| CN109485557A (zh) * | 2018-12-18 | 2019-03-19 | 华东理工大学 | 一种间苯二甲酸的制备工艺 |
| CN109503369A (zh) * | 2018-12-18 | 2019-03-22 | 华东理工大学 | 一种间苯二甲酸的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE776267A (fr) | 1972-06-06 |
| FR2120749A5 (enExample) | 1972-08-18 |
| NL7116938A (enExample) | 1972-07-03 |
| DE2158279A1 (de) | 1972-07-06 |
| IT945355B (it) | 1973-05-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |