GB1427390A - Substituted benzoyloxy benzoic acid phenyl esters and nematic liquid crystal compoitions containing them - Google Patents

Substituted benzoyloxy benzoic acid phenyl esters and nematic liquid crystal compoitions containing them

Info

Publication number
GB1427390A
GB1427390A GB3959173A GB3959173A GB1427390A GB 1427390 A GB1427390 A GB 1427390A GB 3959173 A GB3959173 A GB 3959173A GB 3959173 A GB3959173 A GB 3959173A GB 1427390 A GB1427390 A GB 1427390A
Authority
GB
United Kingdom
Prior art keywords
alkoxy
alkyl
liquid crystal
nematic
atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3959173A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19722240864 external-priority patent/DE2240864C3/en
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Publication of GB1427390A publication Critical patent/GB1427390A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/008Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with tri- or tetrahalomethyl compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/20Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
    • C09K19/2007Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Crystal Substances (AREA)

Abstract

1427390 Liquid crystal compositions MERCK PATENT GmbH 15 Aug 1973 [19 Aug 1972] 39591/73 Heading C4X [Also in Division C2] A modified nematic liquid crystal mixture comprises at least one known nematic compound together with 1 to 35% by wt. of at least one ester of the formula wherein R 1 and R 2 are alkyl or alkoxy radicals which may be substituted by alkoxy radicals, the radicals R 1 and R 2 each containing up to 10 C atoms, X is CN or NO 2 and Y is H or the same as X. Specified known nematic compounds and ionizing and homotropically orienting additives are those of the following respective formulµ X is a halogen atom, and R 3 and R 4 are alkyl, alkoxy or acyloxy containing up to 18 C atoms, Z is R 5 or R 5 is C 6 -C 18 alkyl or C 4 -C 18 alkoxy or acyloxy, R 6 is alkyl, alkoxy or acyloxy containing up to 18 C atoms, and n is 0 or 1. The esters of Formula I are preferably added in such an amount to the known nematic compounds that they form eutectic mixtures therewith. Cholesteric materials may be present in up to 10% by weight. Examples are given in which specific nematic mixtures are prepared. The esters of Formula I generally have negative dielectric anisotropy which may predominate even in a mixture with components of positive anisotropy, and the mixtures are useful in electrooptic dynamic scattering display devices.
GB3959173A 1972-08-19 1973-08-15 Substituted benzoyloxy benzoic acid phenyl esters and nematic liquid crystal compoitions containing them Expired GB1427390A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19722240864 DE2240864C3 (en) 1972-08-19 Phenol carboxylic acid esters, their production and their use to influence the electro-optical properties of nematic phases

Publications (1)

Publication Number Publication Date
GB1427390A true GB1427390A (en) 1976-03-10

Family

ID=5854003

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3959173A Expired GB1427390A (en) 1972-08-19 1973-08-15 Substituted benzoyloxy benzoic acid phenyl esters and nematic liquid crystal compoitions containing them

Country Status (11)

Country Link
JP (1) JPS594467B2 (en)
AT (1) AT330858B (en)
BE (1) BE803714A (en)
CH (1) CH582229A5 (en)
DD (1) DD107153A5 (en)
FR (1) FR2196200B1 (en)
GB (1) GB1427390A (en)
IL (1) IL42937A0 (en)
IT (1) IT998364B (en)
NL (1) NL7311312A (en)
SU (1) SU482049A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5683682A (en) * 1989-11-15 1997-11-04 Robertet S.A. Derivatives of aromatic benzoates as inhibitors of esterase-producing micro-organisms

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1068110B (en) * 1976-08-13 1985-03-21 Montedison Spa PROCESS FOR THE PREPARATION OF HYDROXIBENZOIC ALDEHYDES 2
FR2419966A1 (en) * 1978-03-17 1979-10-12 Thomson Csf DIESTER TYPE LIQUID CRYSTAL WITH A SMECTIC PHASE, AT LOW DIELECTRIC ISOTROPY FREQUENCY, AND DISPLAY DEVICE USING THIS CRYSTAL
US4279770A (en) * 1978-09-20 1981-07-21 Chisso Corporation Liquid crystal 2,3-dicyano-hydroquinone derivatives
JPS5633360U (en) * 1979-08-22 1981-04-01
JPS5638378A (en) * 1979-09-05 1981-04-13 Matsushita Electric Ind Co Ltd Dynamic scattering type liquid crystal display
JPS5841834A (en) * 1981-09-07 1983-03-11 Sumitomo Chem Co Ltd Preparation of hydroxybenzaldehyde
DE102011108708A1 (en) 2010-09-25 2012-03-29 Merck Patent Gmbh Liquid crystal displays and liquid crystal media with homeotropic alignment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5683682A (en) * 1989-11-15 1997-11-04 Robertet S.A. Derivatives of aromatic benzoates as inhibitors of esterase-producing micro-organisms

Also Published As

Publication number Publication date
FR2196200B1 (en) 1977-02-25
CH582229A5 (en) 1976-11-30
DE2240864B2 (en) 1976-09-30
AT330858B (en) 1976-07-26
IL42937A0 (en) 1973-11-28
ATA703873A (en) 1975-10-15
NL7311312A (en) 1974-02-21
BE803714A (en) 1974-02-18
DD107153A5 (en) 1974-07-12
SU482049A3 (en) 1975-08-25
IT998364B (en) 1976-01-20
JPS4958089A (en) 1974-06-05
DE2240864A1 (en) 1974-02-28
JPS594467B2 (en) 1984-01-30
FR2196200A1 (en) 1974-03-15

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee