GB1415636A - Process for the preparation of methyl or ethyl esters of acrylic or methacrylic acid - Google Patents

Process for the preparation of methyl or ethyl esters of acrylic or methacrylic acid

Info

Publication number
GB1415636A
GB1415636A GB1896774A GB1896774A GB1415636A GB 1415636 A GB1415636 A GB 1415636A GB 1896774 A GB1896774 A GB 1896774A GB 1896774 A GB1896774 A GB 1896774A GB 1415636 A GB1415636 A GB 1415636A
Authority
GB
United Kingdom
Prior art keywords
value
methyl
oxygen
acrylic
methacrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1896774A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societa Italiana Resine SpA SIR
Original Assignee
Societa Italiana Resine SpA SIR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societa Italiana Resine SpA SIR filed Critical Societa Italiana Resine SpA SIR
Publication of GB1415636A publication Critical patent/GB1415636A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Medicinal Preparation (AREA)

Abstract

1415636 Methyl and ethyl acrylates and methacrylates SOC ITALIANA RESINE SIR SpA 30 April 1974 [11 May 1973] 18967/74 Heading C2C Methyl or ethyl esters of acrylic or methacrylic acid are prepared by reacting acrolein or methacrolein with oxygen or gases containing free oxygen and methanol or ethanol in the gas phase and in the presence of a catalyst having the general formula or or where Me denotes a chromium, manganese, iron, cobalt, nickel, copper, zinc, silver, cadmium, gold, mercury, sodium, barium, calcium, cerium, bismuth, thorium, uranium, lead, antimony, tin, phosphorus or boron atom, a has a value of from 6 to 12, b has a value of from 1 to 6, c has a value of from 0 to 5, d has a value of from 1 to 6, x has a value of from 20À5 to 58À5, y has a value of from 21 to 61À5, and z has a value of from 23À5 to 76À5. The catalysts may be used supported for example on silica, alumina, magnesia, titania or ziroonia, and may be used in fixed, moving or fluid bed. Inert gaseous diluents (e.g. nitrogen, carbon dioxide or steam) may be present. If the amount of alcohol is less than that required to form ester, a mixture of free acid and ester may be obtained. A gas mixture containing acrolein or methacrolein obtained by the catalytic oxidation of propylene or isobutene may be used with alcohol, and possible oxygen, added.
GB1896774A 1973-05-11 1974-04-30 Process for the preparation of methyl or ethyl esters of acrylic or methacrylic acid Expired GB1415636A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT23967/73A IT987284B (en) 1973-05-11 1973-05-11 PROCEDURE FOR THE PREPARATION OF THE ESTERS OF ACRYLIC OR METHACRYLIC ACIDS

Publications (1)

Publication Number Publication Date
GB1415636A true GB1415636A (en) 1975-11-26

Family

ID=11211197

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1896774A Expired GB1415636A (en) 1973-05-11 1974-04-30 Process for the preparation of methyl or ethyl esters of acrylic or methacrylic acid

Country Status (11)

Country Link
JP (1) JPS5315053B2 (en)
AU (1) AU475581B2 (en)
BR (1) BR7403847D0 (en)
DE (1) DE2422796C2 (en)
FR (1) FR2228764B1 (en)
GB (1) GB1415636A (en)
IT (1) IT987284B (en)
NL (1) NL7406308A (en)
NO (1) NO142747C (en)
SE (1) SE410445B (en)
YU (1) YU36146B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2210664A1 (en) * 2007-10-26 2010-07-28 Asahi Kasei Chemicals Corporation Composite particle-loaded article, method for producing the composite particle-loaded article, and method for producing compound using the composite particle-loaded article as chemical synthesis catalyst

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19712820A1 (en) * 1997-03-26 1998-10-01 Basf Ag Burning moderators for gas-generating mixtures
CN114605250B (en) * 2020-12-09 2023-02-28 中国科学院大连化学物理研究所 V-based high-entropy phosphate and method for synthesizing acrylic acid and acrylic ester
CN116328825A (en) * 2023-02-22 2023-06-27 中国科学院青岛生物能源与过程研究所 Catalyst, preparation method thereof and method for preparing methyl 3-methoxypropionate by using catalyst to catalyze methanol and methyl acetate
CN117861685B (en) * 2024-03-13 2024-05-10 山东三维化学集团股份有限公司 Supported gold-based multi-phase catalyst and preparation method and application thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3644509A (en) * 1969-02-03 1972-02-22 Celanese Corp Oxidation of unsaturated aldehydes to the corresponding acids
DE2025992B2 (en) * 1969-06-20 1973-03-01 PROCESS FOR THE MANUFACTURING OF ESTER ALPHA, BETA-OLEFINIC UNSATURIZED ALIPHATIC CARBONIC ACIDS
US3725472A (en) * 1969-08-05 1973-04-03 Daicel Ltd Process for preparing {60 ,{62 -unsaturated carboxylic acids
US3925464A (en) * 1971-12-14 1975-12-09 Asahi Glass Co Ltd Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2210664A1 (en) * 2007-10-26 2010-07-28 Asahi Kasei Chemicals Corporation Composite particle-loaded article, method for producing the composite particle-loaded article, and method for producing compound using the composite particle-loaded article as chemical synthesis catalyst
EP2210664A4 (en) * 2007-10-26 2011-12-21 Asahi Kasei Chemicals Corp Composite particle-loaded article, method for producing the composite particle-loaded article, and method for producing compound using the composite particle-loaded article as chemical synthesis catalyst
EP2500093A1 (en) * 2007-10-26 2012-09-19 Asahi Kasei Chemicals Corporation Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
US8450235B2 (en) 2007-10-26 2013-05-28 Asahi Kasei Chemicals Corporation Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis

Also Published As

Publication number Publication date
JPS5315053B2 (en) 1978-05-22
DE2422796C2 (en) 1982-12-09
BR7403847D0 (en) 1974-12-24
AU475581B2 (en) 1976-08-26
FR2228764A1 (en) 1974-12-06
FR2228764B1 (en) 1976-06-25
NO142747C (en) 1980-10-08
SE410445B (en) 1979-10-15
NO142747B (en) 1980-06-30
NO741672L (en) 1974-11-12
DE2422796A1 (en) 1974-12-05
YU128374A (en) 1981-06-30
AU6859474A (en) 1975-11-06
IT987284B (en) 1975-02-20
YU36146B (en) 1982-02-25
JPS5030826A (en) 1975-03-27
NL7406308A (en) 1974-11-13

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Legal Events

Date Code Title Description
PS Patent sealed
746 Register noted 'licences of right' (sect. 46/1977)
PCNP Patent ceased through non-payment of renewal fee