GB1411249A - Epoxy compositions - Google Patents

Epoxy compositions

Info

Publication number
GB1411249A
GB1411249A GB5791572A GB5791572A GB1411249A GB 1411249 A GB1411249 A GB 1411249A GB 5791572 A GB5791572 A GB 5791572A GB 5791572 A GB5791572 A GB 5791572A GB 1411249 A GB1411249 A GB 1411249A
Authority
GB
United Kingdom
Prior art keywords
reacted
acid
thiodiethanol
epon
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5791572A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
PPG Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Inc filed Critical PPG Industries Inc
Publication of GB1411249A publication Critical patent/GB1411249A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4064Curing agents not provided for by the groups C08G59/42 - C08G59/66 sulfur containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4071Curing agents not provided for by the groups C08G59/42 - C08G59/66 phosphorus containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443Polyepoxides
    • C09D5/4434Polyepoxides characterised by the nature of the epoxy binder
    • C09D5/4442Binder characterised by functional groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Molecular Biology (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)

Abstract

1411249 Water-dispersible ternary sulphonium epoxy resins PPG INDUSTRIES Inc 15 Dec 1972 [20 Dec 1971] 57915/72 Heading C3B Novel ungelled water-dispersible epoxy resins having in the resin molecule an average of more than one 1,2-epoxy group and at least 0.05% by weight of chemically bound sulphur, at least 1% of which is in the form of ternary sulphonium base salt groups, are prepared by reacting appropriate epoxy resins with organic sulphides in the presence of an acid, the sulphide reacting with available epoxy groups. The acid is preferably lactic acid and the final product also preferably contains oxyalkylene groups and chemically bound boron. The boron may be introduced simultaneously with the sulphur and preferably in the form of quaternary ammonium borate groups, while the oxyalkylene groups may be introduced by direct oxyalkylation of the epoxy resin starting material or by reaction with oxyalkylated monoalcohols. In Examples (1) a reaction product of "Epon 836 " (a diglycidyl ether of bisphenol A) and bisphenol A is reacted with polypropylene glycol and subsequently with thiodiethanol and lactic acid; (2) Epon is reacted with thiodiethanol and lactic acid; (3) a reaction product of Epon and a monobutylether of a polyalkylene glycol is reacted with thiodiethanol and boric acid; (4)Eponis reacted with thiodiethanol and phosphoric acid and the product subsequently reacted with a monobutyl ether of a polyalkylene glycol and (5) Epon is reacted with diethyl sulphide, lactic acid and a monobutyl ether of a polyalkylene glycol. Uses.-The resulting products may be diluted with water and optionally further compounded with a surfactant and/or ground with titanium oxide and carbon black to provide electrodeposition baths for coating panels of aluminium, steel or zinc phosphated steel.
GB5791572A 1971-12-20 1972-12-15 Epoxy compositions Expired GB1411249A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US21014171A 1971-12-20 1971-12-20

Publications (1)

Publication Number Publication Date
GB1411249A true GB1411249A (en) 1975-10-22

Family

ID=22781737

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5791572A Expired GB1411249A (en) 1971-12-20 1972-12-15 Epoxy compositions

Country Status (1)

Country Link
GB (1) GB1411249A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5405701A (en) * 1992-04-15 1995-04-11 Kansai Paint Co., Ltd. Resin composition for aqueous coating containing glycidyl amines
US5407748A (en) * 1992-10-09 1995-04-18 Kansai Paint Co., Ltd. Resin composition for aqueous paint
CN112457721A (en) * 2020-12-03 2021-03-09 上海瑞君电泳涂料有限公司 Color paste for epoxy electrophoretic coating, electrophoretic coating and preparation process thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5405701A (en) * 1992-04-15 1995-04-11 Kansai Paint Co., Ltd. Resin composition for aqueous coating containing glycidyl amines
US5407748A (en) * 1992-10-09 1995-04-18 Kansai Paint Co., Ltd. Resin composition for aqueous paint
CN112457721A (en) * 2020-12-03 2021-03-09 上海瑞君电泳涂料有限公司 Color paste for epoxy electrophoretic coating, electrophoretic coating and preparation process thereof
CN112457721B (en) * 2020-12-03 2023-02-03 上海瑞君电泳涂料有限公司 Color paste for epoxy electrophoretic coating, electrophoretic coating and preparation process thereof

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19921214