GB1408819A - Process for emulsion-polymerization of butadiene - Google Patents
Process for emulsion-polymerization of butadieneInfo
- Publication number
- GB1408819A GB1408819A GB5026573A GB5026573A GB1408819A GB 1408819 A GB1408819 A GB 1408819A GB 5026573 A GB5026573 A GB 5026573A GB 5026573 A GB5026573 A GB 5026573A GB 1408819 A GB1408819 A GB 1408819A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butadiene
- stage
- polymerization
- emulsion
- gelfree
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1408819 Polymerizing dienes SOC ITALIANA RESINE SIR SpA 29 Oct 1973 [30 Nov 1972] 50265/73 Heading C3P Butadiene is polymerized in aqueous emulsion in the presence of emulsifier, dispersing agent, initiator and chain transfer agent wherein (a) in a first stage polymerization is carried out in a phase separate from polymer being formed, (b) in an intermediate stage, monomer is added incrementally in amounts such that immediately after each addition the conversion is at least 45% and (c) in a final stage the reaction is completed. The products are low viscosity, gelfree latices having solids contents above 40% and a number average particle size of at least 1800 A. They are suitable for producing ABS graft polymers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT3226972A IT974686B (en) | 1972-11-30 | 1972-11-30 | PROCEDURE FOR THE EMULSIONING POLYMERIZATION OF CO NJUGATED DENIS |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1408819A true GB1408819A (en) | 1975-10-08 |
Family
ID=11235076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5026573A Expired GB1408819A (en) | 1972-11-30 | 1973-10-29 | Process for emulsion-polymerization of butadiene |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS5222795B2 (en) |
CA (1) | CA1028081A (en) |
CH (1) | CH606122A5 (en) |
DE (1) | DE2359493A1 (en) |
ES (1) | ES420517A1 (en) |
FR (1) | FR2208915B1 (en) |
GB (1) | GB1408819A (en) |
IT (1) | IT974686B (en) |
NL (1) | NL170740C (en) |
YU (1) | YU35778B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107001515A (en) * | 2014-12-16 | 2017-08-01 | 株式会社Lg化学 | The acronitrile-butadiene-styrene graft copolymer of the preparation method of polydiene polymer, polydiene polymer prepared therefrom and the core shell structure comprising the polydiene polymer |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2724658B1 (en) * | 1994-09-16 | 1997-01-31 | Enichem Elastomeres France | PROCESS FOR THE PREPARATION OF (CO) POLYCHLOROPROPENE RUBBER. |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2763635A (en) * | 1951-08-27 | 1956-09-18 | Phillips Petroleum Co | Production of high conversion plasticized synthetic elastomers in aqueous emulsion |
US2761853A (en) * | 1951-09-27 | 1956-09-04 | Phillips Petroleum Co | Process for production of low viscosity high solids latex |
US3318831A (en) * | 1963-12-16 | 1967-05-09 | Copolymer Rubber & Chem Corp | Process for preparing high solids concentrated latex |
FR1444016A (en) * | 1964-05-04 | 1966-07-01 | Grace W R & Co | Process for the manufacture of latex of butadiene polymer and other conjugated dienes and latices thus obtained |
DE1720383A1 (en) * | 1967-05-08 | 1972-03-09 | Copolymer Rubber & Chem Corp | Process for making a synthetic rubbery polymer latex |
GB1379391A (en) * | 1971-03-10 | 1975-01-02 | Bp Chem Int Ltd | Polymerisation process |
-
1972
- 1972-11-30 IT IT3226972A patent/IT974686B/en active
-
1973
- 1973-10-29 GB GB5026573A patent/GB1408819A/en not_active Expired
- 1973-10-30 CA CA184,619A patent/CA1028081A/en not_active Expired
- 1973-11-02 CH CH1541673A patent/CH606122A5/xx not_active IP Right Cessation
- 1973-11-02 NL NL7315057A patent/NL170740C/en not_active IP Right Cessation
- 1973-11-13 ES ES420517A patent/ES420517A1/en not_active Expired
- 1973-11-26 YU YU305873A patent/YU35778B/en unknown
- 1973-11-27 FR FR7342231A patent/FR2208915B1/fr not_active Expired
- 1973-11-29 JP JP13398573A patent/JPS5222795B2/ja not_active Expired
- 1973-11-29 DE DE19732359493 patent/DE2359493A1/en not_active Ceased
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107001515A (en) * | 2014-12-16 | 2017-08-01 | 株式会社Lg化学 | The acronitrile-butadiene-styrene graft copolymer of the preparation method of polydiene polymer, polydiene polymer prepared therefrom and the core shell structure comprising the polydiene polymer |
EP3235841A4 (en) * | 2014-12-16 | 2017-12-20 | LG Chem, Ltd. | Method for preparing diene-based rubber polymer, diene-based rubber polymer prepared thereby, core-shell structured acrylonitrile-butadiene-styrene graft copolymer comprising same |
US10385154B2 (en) | 2014-12-16 | 2019-08-20 | Lg Chem, Ltd. | Method for preparing diene-based rubber polymer, diene-based rubber polymer prepared therefrom and acrylonitrile-butadiene-styrene graft copolymer of core-shell structure comprising the same |
CN107001515B (en) * | 2014-12-16 | 2019-10-01 | 株式会社Lg化学 | The acrylonitrile-butadiene-phenylethene grafted copolymer of polydiene polymer and preparation method thereof and nucleocapsid structure |
Also Published As
Publication number | Publication date |
---|---|
JPS4987784A (en) | 1974-08-22 |
IT974686B (en) | 1974-07-10 |
ES420517A1 (en) | 1976-04-01 |
YU35778B (en) | 1981-06-30 |
NL170740B (en) | 1982-07-16 |
NL7315057A (en) | 1974-06-04 |
CA1028081A (en) | 1978-03-14 |
NL170740C (en) | 1982-12-16 |
JPS5222795B2 (en) | 1977-06-20 |
YU305873A (en) | 1980-12-31 |
FR2208915A1 (en) | 1974-06-28 |
CH606122A5 (en) | 1978-10-31 |
FR2208915B1 (en) | 1978-03-17 |
DE2359493A1 (en) | 1974-07-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
435 | Patent endorsed 'licences of right' on the date specified (sect. 35/1949) | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19931028 |