GB1305779A - - Google Patents

Info

Publication number
GB1305779A
GB1305779A GB3915270A GB3915270A GB1305779A GB 1305779 A GB1305779 A GB 1305779A GB 3915270 A GB3915270 A GB 3915270A GB 3915270 A GB3915270 A GB 3915270A GB 1305779 A GB1305779 A GB 1305779A
Authority
GB
United Kingdom
Prior art keywords
polymerization
bulk
monomers
dimers
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3915270A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1305779A publication Critical patent/GB1305779A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

1305779 Graft polymerization process FOSTER GRANT CO Inc 13 Aug 1970 [15 Aug 1969] 39152/70 Heading C3G An ABS polymer is prepared by (a) bulk polymerizing a mixture containing at least one vinyl aromatic monomer, at least one monomer selected from acrylonitrile and methacrylonitrile and at least one rubber; (b) adding 0À20 to 1À0%, based on the weight of monomers and rubber, of unsaturated alpha-methylstyrene dimers to the polymerization mixture, at least 0À125% of which dimers is added after 2 to 15% by weight of the monomers has been converted to polymer and the remainder, if any, is subsequently added in one or more increments; and (c) continuing bulk polymerization until substantially all of the monomer has been polymerized, or continuing bulk polymerization until 20 to 50% of the monomers has been polymerized and completing the polymerization in aqueous suspension. In the example, the dimers are added in three increments during bulk prepolymerization of a mixture of styrene, acrylonitrile, butadiene-styrene rubber and polybutadiene and polymerization is completed in suspension.
GB3915270A 1969-08-15 1970-08-13 Expired GB1305779A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US85063969A 1969-08-15 1969-08-15

Publications (1)

Publication Number Publication Date
GB1305779A true GB1305779A (en) 1973-02-07

Family

ID=25308723

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3915270A Expired GB1305779A (en) 1969-08-15 1970-08-13

Country Status (7)

Country Link
JP (1) JPS4912908B1 (en)
BE (1) BE754865A (en)
CA (1) CA930892A (en)
DE (1) DE2040123A1 (en)
FR (1) FR2057970A5 (en)
GB (1) GB1305779A (en)
NL (1) NL7012039A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5270387A (en) * 1990-01-02 1993-12-14 The Dow Chemical Company High heat styrenic copolymer blends having improved tensile properties

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5270387A (en) * 1990-01-02 1993-12-14 The Dow Chemical Company High heat styrenic copolymer blends having improved tensile properties

Also Published As

Publication number Publication date
CA930892A (en) 1973-07-24
DE2040123A1 (en) 1971-02-25
BE754865A (en) 1971-02-15
FR2057970A5 (en) 1971-05-21
NL7012039A (en) 1971-02-17
JPS4912908B1 (en) 1974-03-28

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee