GB1405212A - Process for catalysing h-d exchange using anchored homogeneous- type catalysts - Google Patents
Process for catalysing h-d exchange using anchored homogeneous- type catalystsInfo
- Publication number
- GB1405212A GB1405212A GB3405173A GB3405173A GB1405212A GB 1405212 A GB1405212 A GB 1405212A GB 3405173 A GB3405173 A GB 3405173A GB 3405173 A GB3405173 A GB 3405173A GB 1405212 A GB1405212 A GB 1405212A
- Authority
- GB
- United Kingdom
- Prior art keywords
- exchange
- july
- hydrogen
- ligands
- rhodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 abstract 2
- 229910052805 deuterium Inorganic materials 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- SNCDMPOGDGKVAL-UHFFFAOYSA-N ethene rhodium Chemical compound [Rh].C=C.C=C SNCDMPOGDGKVAL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
- B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA147,481A CA978926A (en) | 1972-07-19 | 1972-07-19 | Anchored homogeneous-type catalysts for h-d exchange |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1405212A true GB1405212A (en) | 1975-09-24 |
Family
ID=4093882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3405173A Expired GB1405212A (en) | 1972-07-19 | 1973-07-17 | Process for catalysing h-d exchange using anchored homogeneous- type catalysts |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3900557A (enExample) |
| JP (1) | JPS4979994A (enExample) |
| AU (1) | AU467636B2 (enExample) |
| CA (1) | CA978926A (enExample) |
| DE (1) | DE2336342A1 (enExample) |
| FR (1) | FR2192867B1 (enExample) |
| GB (1) | GB1405212A (enExample) |
| IL (1) | IL42752A (enExample) |
| IT (1) | IT991791B (enExample) |
| NL (1) | NL7309982A (enExample) |
| SE (1) | SE379939B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000153A (en) * | 1977-06-16 | 1979-01-04 | Brintzinger H | Cyclopentadienyl-metal-carbonyl compounds bound to polymers and derivatives therefrom processes for their preparation and their use as catalysts |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4098727A (en) * | 1970-07-23 | 1978-07-04 | Mobil Oil Corporation | Insoluble polymers having functional groups containing chemically bonded Group VIII metal |
| US4045493A (en) * | 1975-02-03 | 1977-08-30 | Standard Oil Company (Indiana) | Hydroformylation of olefins |
| US4228035A (en) * | 1976-05-03 | 1980-10-14 | California Institute Of Technology | Irradiated polymer supported metal catalyst |
| US4062883A (en) * | 1976-08-06 | 1977-12-13 | The United States Of America As Represented By The Secretary Of The Navy | Polymer-bound metallocarborane catalyst product and process |
| US4179403A (en) * | 1977-12-19 | 1979-12-18 | Shell Oil Company | Resin-ligand-metal complex compositions |
| US4179402A (en) * | 1978-05-15 | 1979-12-18 | Shell Oil Company | Resin-metal-ligand composition |
| US4284835A (en) * | 1979-07-05 | 1981-08-18 | Shell Oil Company | Hydrogenation process |
| US4421865A (en) * | 1981-06-08 | 1983-12-20 | Standard Oil Company (Sohio) | Selective hydrogen-deuterium interchange using ion exchange resins |
| US4384981A (en) * | 1981-08-24 | 1983-05-24 | Occidental Research Corporation | Hydrogenation process utilizing novel catalyst |
| US4386013A (en) * | 1981-08-24 | 1983-05-31 | Occidental Research Corporation | Hydroformylation process utilizing novel catalyst |
| US4526884A (en) * | 1982-12-27 | 1985-07-02 | The Standard Oil Company | Ruthenium containing catalyst composition useful for process for the demerization of acrylic compounds |
| US4506030A (en) * | 1984-02-17 | 1985-03-19 | The Board Of Regents, University Of Texas System | Catalysts for hydrogenation of aromatic compounds |
| US4915929A (en) * | 1988-01-25 | 1990-04-10 | Iowa State University Research Foundation, Inc. | Isotopic separation of D2 O from H2 O using ruthenium adsorbent |
| US6794522B2 (en) | 2001-03-22 | 2004-09-21 | The Regents Of The University Of California | Process for preparing a deuterated or tritiated compound |
| US20060258875A1 (en) * | 2005-05-10 | 2006-11-16 | Clementine Reyes | Methods for manufacturing supported nanocatalysts and methods for using supported nanocatalysts |
| US8097229B2 (en) * | 2006-01-17 | 2012-01-17 | Headwaters Technology Innovation, Llc | Methods for manufacturing functionalized inorganic oxides and polymers incorporating same |
| US8778223B2 (en) | 2011-05-24 | 2014-07-15 | Lc Vision, Llc | Liquid crystals having cyclohexyl core structures and fluorinated tails |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1277737A (en) * | 1968-09-30 | 1972-06-14 | British Petroleum Co | Modified polymers |
| US3681021A (en) * | 1970-03-31 | 1972-08-01 | Mobil Oil Corp | Production of heavy water employing a group viii catalyst |
| US3789112A (en) * | 1970-10-28 | 1974-01-29 | Gulf Research Development Co | Process for obtaining deuterium from hydrogen-containing components and the production of heavy water therefrom |
-
1972
- 1972-07-19 CA CA147,481A patent/CA978926A/en not_active Expired
-
1973
- 1973-07-16 SE SE7309926A patent/SE379939B/xx unknown
- 1973-07-16 US US379272A patent/US3900557A/en not_active Expired - Lifetime
- 1973-07-16 IL IL42752A patent/IL42752A/en unknown
- 1973-07-17 FR FR7326833A patent/FR2192867B1/fr not_active Expired
- 1973-07-17 GB GB3405173A patent/GB1405212A/en not_active Expired
- 1973-07-17 DE DE19732336342 patent/DE2336342A1/de active Pending
- 1973-07-18 IT IT69150/73A patent/IT991791B/it active
- 1973-07-18 JP JP48080390A patent/JPS4979994A/ja active Pending
- 1973-07-18 NL NL7309982A patent/NL7309982A/xx unknown
- 1973-07-19 AU AU58306/73A patent/AU467636B2/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000153A (en) * | 1977-06-16 | 1979-01-04 | Brintzinger H | Cyclopentadienyl-metal-carbonyl compounds bound to polymers and derivatives therefrom processes for their preparation and their use as catalysts |
| GB2000153B (en) * | 1977-06-16 | 1982-11-24 | Brintzinger H | Cyclopentadienyl-metal compounds and processes for their preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2336342A1 (de) | 1974-02-07 |
| CA978926A (en) | 1975-12-02 |
| FR2192867B1 (enExample) | 1978-08-11 |
| US3900557A (en) | 1975-08-19 |
| IL42752A (en) | 1976-02-29 |
| AU467636B2 (en) | 1975-12-04 |
| AU5830673A (en) | 1975-01-23 |
| SE379939B (enExample) | 1975-10-27 |
| JPS4979994A (enExample) | 1974-08-01 |
| FR2192867A1 (enExample) | 1974-02-15 |
| IT991791B (it) | 1975-08-30 |
| IL42752A0 (en) | 1973-11-28 |
| NL7309982A (enExample) | 1974-01-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |