GB1398970A - Production of chroman-3-ol and its derivatives by a cyclization process - Google Patents

Production of chroman-3-ol and its derivatives by a cyclization process

Info

Publication number
GB1398970A
GB1398970A GB1924271A GB1924271A GB1398970A GB 1398970 A GB1398970 A GB 1398970A GB 1924271 A GB1924271 A GB 1924271A GB 1924271 A GB1924271 A GB 1924271A GB 1398970 A GB1398970 A GB 1398970A
Authority
GB
United Kingdom
Prior art keywords
ortho
group
chroman
derivatives
substituents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1924271A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Solutions UK Ltd
Original Assignee
Albright and Wilson Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albright and Wilson Ltd filed Critical Albright and Wilson Ltd
Priority to GB1924271A priority Critical patent/GB1398970A/en
Publication of GB1398970A publication Critical patent/GB1398970A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D311/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/58Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

1398970 Chroman-3-ol and derivatives ALBRIGHT & WILSON Ltd 5 June 1972 [7 June 1971] 19242/71 Heading C2C Chroman-3-ol and derivatives thereof are produced by the oxidation of an allyl ether of formula or derivative thereof containing one or more substituents in the aromatic nucleus, with the proviso that there is at least one position ortho to the -OCH 2 -CH=CH 2 group unsubstituted, no substituent causing polymerization and/or degradation of the molecule under the conditions of the oxidation, no substituents resulting in an overall electronic withdrawal from both ortho positions and no sterically hindering group being adjacent to an ortho group when said ortho position is the only unsubstituted ortho position, by reaction with a thallium III salt in a strong acid solution. Exemplified acids are sulphuric, nitric, fluoroboric, perchloric, and trifluoroacetic acids, the thallium III salt preferably having the same anion as the acid employed. Preferable substituents in the aromatic nucleus are one of a halogen atom, or a phenyl, phenoxy, benzyl, benzyloxy, acetyl or acetoxy group, or one or two alkyl or alkoxy groups.
GB1924271A 1971-06-07 1971-06-07 Production of chroman-3-ol and its derivatives by a cyclization process Expired GB1398970A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1924271A GB1398970A (en) 1971-06-07 1971-06-07 Production of chroman-3-ol and its derivatives by a cyclization process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1924271A GB1398970A (en) 1971-06-07 1971-06-07 Production of chroman-3-ol and its derivatives by a cyclization process

Publications (1)

Publication Number Publication Date
GB1398970A true GB1398970A (en) 1975-06-25

Family

ID=10126094

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1924271A Expired GB1398970A (en) 1971-06-07 1971-06-07 Production of chroman-3-ol and its derivatives by a cyclization process

Country Status (1)

Country Link
GB (1) GB1398970A (en)

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees