GB1398126A - Demetalation of a hydrocarbon charge stock - Google Patents

Demetalation of a hydrocarbon charge stock

Info

Publication number
GB1398126A
GB1398126A GB2630972A GB2630972A GB1398126A GB 1398126 A GB1398126 A GB 1398126A GB 2630972 A GB2630972 A GB 2630972A GB 2630972 A GB2630972 A GB 2630972A GB 1398126 A GB1398126 A GB 1398126A
Authority
GB
United Kingdom
Prior art keywords
manganese
solvent
nodule
reagent
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2630972A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1398126A publication Critical patent/GB1398126A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/04—Manganese marine modules

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1398126 Manganese module demetalation MOBIL OIL CORP 6 June 1972 [22 July 1971] 26309/72 Heading C1A [Also in Divisions B1 and C5] Manganese nodule (i.e. aquetic stalagmite comprising MnO 2 and Fe 2 O 3 ) is treated, prior to use as catalyst in the demetalation of a metalcontaining hydrocarbon charge stock, to remove therefrom, selectively with respect to the iron oxide component thereof, at least 25 weight per cent of the manganese dioxide component thereof, for example by converting the manganese dioxide to a manganese compound soluble in a solvent in which iron oxide (or any iron compound formed concomitantly with the manganese compound) is substantially insoluble and, simultaneously or serially, leaching the nodule with such a solvent to dissolve and remove the manganese compound. A reagent capable of reducing manganese of the manganese dioxide component to the divalent state may be used in converting the manganese diode to the solventsoluble compound and the solvent may be an aqueous solvent; for example, the nodule may be treated either serially with carbon monoxide (reagent) and an aqueous alkaline solution (solvent), for instance a solution containing ammonium hydroxide and ammonium carbonate (see Example 1), or with sodium chloride (reagent) dissolved in an acid medium having a pH greater than 3 (solvent), for instance aqueous actic acid (see Example 2), or serially with sulphur dioxide (reagent) and water (solvent) (see Example 3). Prior to use as catalyst, the treated nodule may be sulphided using hydrogen sulphide.
GB2630972A 1971-07-22 1972-06-06 Demetalation of a hydrocarbon charge stock Expired GB1398126A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US16535371A 1971-07-22 1971-07-22

Publications (1)

Publication Number Publication Date
GB1398126A true GB1398126A (en) 1975-06-18

Family

ID=22598550

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2630972A Expired GB1398126A (en) 1971-07-22 1972-06-06 Demetalation of a hydrocarbon charge stock

Country Status (7)

Country Link
US (1) US3772185A (en)
JP (1) JPS5526908B1 (en)
DE (1) DE2235954A1 (en)
FR (1) FR2146443A1 (en)
GB (1) GB1398126A (en)
IT (1) IT963249B (en)
NL (1) NL7210076A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2161465A (en) * 1984-07-12 1986-01-15 Nat Res Dev Obtaining aqueous solution from insoluble metal oxide

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4045331A (en) * 1975-10-23 1977-08-30 Union Oil Company Of California Demetallization and desulfurization of petroleum feed-stocks with manganese on alumina catalysts
US4303497A (en) * 1978-09-25 1981-12-01 Mobil Oil Corporation Desulfurization, demetalation and denitrogenation of coal
US4263172A (en) * 1979-08-13 1981-04-21 Phillips Petroleum Company Cracking catalysts
US4310410A (en) * 1979-08-13 1982-01-12 Phillips Petroleum Company Cracking process
US4329221A (en) * 1980-09-12 1982-05-11 Mobil Oil Corporation Upgrading of hydrocarbon feedstock
US4486298A (en) * 1981-05-28 1984-12-04 Mobil Oil Corporation Adsorptive demetalation of heavy petroleum residua
US4437981A (en) 1982-11-22 1984-03-20 Ashland Oil, Inc. Immobilization and neutralization of contaminants in crude oil
US4585751A (en) * 1985-06-24 1986-04-29 Phillips Petroleum Company Hydrotreating catalysts
US20080000809A1 (en) * 2006-06-30 2008-01-03 Hua Wang Membrane method of removing oil-soluble metals from hydrocarbons
CN101574647B (en) * 2009-04-23 2011-06-01 中国海洋石油总公司 Preparation method of ultra-deep absorption desulfurization and denitrogenation agent for hydrocracking tail oil

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1937488A (en) * 1932-10-01 1933-11-28 Intermetal Corp Manganese dioxide
US2778777A (en) * 1954-02-16 1957-01-22 Texas Co Removal of metal components from petroleum oils
US3509041A (en) * 1966-11-28 1970-04-28 Mobil Oil Corp Manganese silicate-containing minerals and their use in hydrocarbon conversions
US3471285A (en) * 1967-03-27 1969-10-07 Dow Chemical Co Process for the selective recovery of manganese and iron from ores

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2161465A (en) * 1984-07-12 1986-01-15 Nat Res Dev Obtaining aqueous solution from insoluble metal oxide

Also Published As

Publication number Publication date
JPS5526908B1 (en) 1980-07-16
DE2235954A1 (en) 1973-02-01
IT963249B (en) 1974-01-10
US3772185A (en) 1973-11-13
NL7210076A (en) 1973-01-24
FR2146443A1 (en) 1973-03-02

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee