GB1393042A - Process for preparing compounds containing ethylene groups - Google Patents

Process for preparing compounds containing ethylene groups

Info

Publication number
GB1393042A
GB1393042A GB3098973A GB3098973A GB1393042A GB 1393042 A GB1393042 A GB 1393042A GB 3098973 A GB3098973 A GB 3098973A GB 3098973 A GB3098973 A GB 3098973A GB 1393042 A GB1393042 A GB 1393042A
Authority
GB
United Kingdom
Prior art keywords
group
formula
groups
aldehyde
june
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3098973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB1393042A publication Critical patent/GB1393042A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/247—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by splitting of cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/32—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/34—Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/91—Dibenzofurans; Hydrogenated dibenzofurans
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D327/00—Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
    • C07D327/02—Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms one oxygen atom and one sulfur atom
    • C07D327/06—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/46—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings substituted on the ring sulfur atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1393042 Olefinically unsaturated compounds CIBA-GEIGY AG 29 June 1973 [30 June 1972] 30989/73 Addition to 1393041 Heading C2C [Also in Division C5] A compound of Formula (1) in which A and A 1 , which may be the same or different, are phenyl, naphthyl, diphenylyl, 2- phenyl- 1 ,2,3-triazol-4-yl or pyridyl, optionally substituted by a non-chromophoric substituent, and D is a 4,4<SP>1</SP>-diphenylylene group, a 1,5- or 2,6-naphthylene group or a 9,10-dihydrophenanthrene or a dibenzofuran group bonded to the ethylene groups in the 2,7-position, are prepared by reacting a sulphonic salt of Formula (IV) in which the groups B, which are the same or different, are C 4 -C 7 polymethylene groups optionally containing a hetero atom and/or a C 1 -C 4 alkyl substituent, M is an anion and n is 1 or 2, with an aldehyde ACHO and/or an aldehyde A 1 CHO in the presence of a strong base and of a strongly polar, protic or aprotic water-miscible solvent to give a diepoxide of Formula (VII) and reducing this in known manner. The salt of general Formula IV may be prepared by treating a compound of Formula (II ) X-CH 2 -D-Cu 2 -X 1 in which X is a halogen atom, a hydroxy group or a group -OOCX 1 in which X is a hydrocarbon group in a strongly acid medium and in a molar ratio of at least 1 : 2 with 1 or 2 organic sulphides of general Formula III The products are stated to be useful as optical brightening agents.
GB3098973A 1972-06-30 1973-06-29 Process for preparing compounds containing ethylene groups Expired GB1393042A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH985372A CH583668A5 (en) 1972-06-30 1972-06-30

Publications (1)

Publication Number Publication Date
GB1393042A true GB1393042A (en) 1975-05-07

Family

ID=4356385

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3098973A Expired GB1393042A (en) 1972-06-30 1973-06-29 Process for preparing compounds containing ethylene groups

Country Status (5)

Country Link
JP (1) JPS5833264B2 (en)
CH (1) CH583668A5 (en)
DE (1) DE2332098C2 (en)
FR (1) FR2190827B1 (en)
GB (1) GB1393042A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015164677A1 (en) 2014-04-23 2015-10-29 Gregory Van Buskirk Cleaning formulations for chemically sensitive individuals: compositions and methods
WO2016115408A1 (en) 2015-01-14 2016-07-21 Gregory Van Buskirk Improved fabric treatment method for stain release

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03146749A (en) * 1989-11-02 1991-06-21 Nobuyuki Mori Card
JPH0655765U (en) * 1992-06-12 1994-08-02 研一 三谷 Wedding reception table and invitation
JPH0732770A (en) * 1993-07-23 1995-02-03 Toshihiro Watanabe Bride and groom introduction sheet for wedding reception
US6020508A (en) * 1997-05-16 2000-02-01 National Starch And Chemical Investment Holding Corporation Radiation- or thermally-initiated cationically-curable epoxide compounds and compositions made from those compounds
EP3050887B1 (en) 2015-01-29 2017-06-28 Samsung Electronics Co., Ltd. Fused polycyclic heteroaromatic compound, organic thin film including compound and electronic device including organic thin film

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3455967A (en) * 1965-09-23 1969-07-15 Dow Chemical Co Synthesis of aromatic epoxides from benzylic sulfonium salts
US3442912A (en) * 1965-09-23 1969-05-06 Dow Chemical Co Synthesis of aromatic epoxides from trialkylsulfonium salts
CH500145A (en) * 1967-07-14 1970-12-15 Ciba Geigy Ag Process for the preparation of aromatic compounds containing ethylene double bonds
GB1300839A (en) * 1970-08-26 1972-12-20 Shell Int Research Preparation of sulphonium halides

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015164677A1 (en) 2014-04-23 2015-10-29 Gregory Van Buskirk Cleaning formulations for chemically sensitive individuals: compositions and methods
WO2016115408A1 (en) 2015-01-14 2016-07-21 Gregory Van Buskirk Improved fabric treatment method for stain release

Also Published As

Publication number Publication date
DE2332098A1 (en) 1974-01-03
CH583668A5 (en) 1977-01-14
DE2332098C2 (en) 1983-06-01
JPS5833264B2 (en) 1983-07-19
FR2190827B1 (en) 1976-06-18
FR2190827A1 (en) 1974-02-01
JPS4958119A (en) 1974-06-05

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees