GB1388871A - Cleaning and treating compositions - Google Patents
Cleaning and treating compositionsInfo
- Publication number
- GB1388871A GB1388871A GB1065572A GB1065572A GB1388871A GB 1388871 A GB1388871 A GB 1388871A GB 1065572 A GB1065572 A GB 1065572A GB 1065572 A GB1065572 A GB 1065572A GB 1388871 A GB1388871 A GB 1388871A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- composition
- zinc
- substrate
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
1388871 Cleaning compositions for waterproofing textiles MINNESOTA MINING & MFG CO 7 March 1972 [8 March 1971] 10655/72 Heading C5D [Also in Division D1] A water-dilutable, alkaline cleaning and treating composition which is capable of removing soil and stains from a substrate and imparting water repellancy to the substrate, and which is stable while enclosed within a container, comprises, in an aqueous medium: (a) at least one detergent which is water-dispersable at concentrations of at least 0À1 weight per cent, (b) at least one water-dispersable organic acid or salt thereof, which is free of fluorinated aliphatic radicals and which forms hydrophobic, water-insoluble zinc and zirconium salts below pH 8, (c) at least one water-dispersible Lewis base capable of only temporarily maintaining the composition at or above pH 8 when the composition is exposed to the atmosphere under conditions of use, and (d) at least one zinc or zirconium co-ordination complex which is waterdispersible at or above pH 8 and which provides sufficient zinc or zirconium ions below pH 8 to combine substantially all of the acidic radicals present in the composition. The composition may further contain an oil repellancy and soil resistance imparting component (e) which is at least one fluorochemical compound which is water-dispersible at or above pH 8 but not water-dispersible below pH 8, which is capable of imparting water and oil repellancy and soil resistance to a substrate, and which has the general formula (R<SP>f</SP>) a -X-(A) b , where R<SP>f</SP> represents a fluoroaliphatic radical, X represents a linking group which is less electro-negative than a -CF 2 - group, A represents an acid group, and a and b are each integers of 1 or more, the acid or its zinc or zirconium salts being water-insoluble below pH 8, and additionally a binder. The composition may be used in a process which comprises the steps of (i) contacting a substrate with the composition; (ii) allowing removal of the soil and stains to be effected; (iii) allowing the pH of the composition to fall below 8, and (iv) drying the substrate. On exposure of the composition to the atmosphere, the Lewis base gradually loses its ability to maintain the composition at or above pH 8, e.g. by evaporation. The preferred Lewis bases are ammonia, morpholine and volatile alkylamines. Preferably the Lewis base is used in conjunction with a water-dispersible salt, e.g. ammonium carbonate which, together with the Lewis base, forms a buffer system. The ligand in the coordination complex may be ammonia, morpholine or an amino acid, e.g. alanine or glycine. The co-ordination complex and the buffer system may be prepared in a single medium, e.g. by mixing ammonium carbonate, concentrated ammonia, zinc oxide and water. The waterdispersible organic acid or its salt may be a fatty acid (1-8 C) or a carboxyl-bearing polymer, e.g. derived from a styrene-maleic anhydride copolymer. The detergent may be anionic or nonionic. The exemplified detergents are ammonium dodecanoxy-polyethyleneoxyethyl sulphate, sodium xylene sulphonate, an ammonium salt of a sulphate ester of an alkylphenoxy poly-(ethyleneoxy) ethanol, sodium lauryl sulphate and a copolymer of hydrophobic polyoxypropylene and hydrophilic polyoxyethylene (M.W. 8750). The exemplified fluorochemical compounds are perfluoroalkyl sulphonamido-N-alkyl-N-alkyl carboxylates or zinc salts thereof, monoperfluoroalkyl sulphonamido N-alkyl-N-alkyl mono- or di-hydrogen phosphate, perfluoroalkyl amido-N-alkyl carboxylates, perfluoro alkyl carboxylates and an ammonium salt thereof. Exemplified binders include gelatin and casein but polyvinyl pyrrolidone and polyvinyl alcohol may be used. The compositions may be used for cleaning and treating textile substrates, e.g. nylon or acrylic carpets and upholstery, and also non-textile substrates, e.g. metal, ceramic or plastered surfaces.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4032774A GB1388872A (en) | 1971-03-08 | 1972-03-07 | Cleaning and treating compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12214371A | 1971-03-08 | 1971-03-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1388871A true GB1388871A (en) | 1975-03-26 |
Family
ID=22400921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1065572A Expired GB1388871A (en) | 1971-03-08 | 1972-03-07 | Cleaning and treating compositions |
Country Status (11)
Country | Link |
---|---|
BE (1) | BE780315A (en) |
CA (1) | CA995411A (en) |
CH (1) | CH540382A (en) |
DE (1) | DE2211623A1 (en) |
DK (1) | DK143763C (en) |
FR (1) | FR2128692B1 (en) |
GB (1) | GB1388871A (en) |
IT (1) | IT952154B (en) |
NL (1) | NL169612C (en) |
SE (1) | SE411361B (en) |
ZA (1) | ZA721516B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2951474A1 (en) * | 1978-12-20 | 1980-07-10 | Minnesota Mining & Mfg | ANTISTATIC MIXTURE AND THEIR USE |
US7737097B2 (en) | 2003-06-27 | 2010-06-15 | Lam Research Corporation | Method for removing contamination from a substrate and for making a cleaning solution |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE30337E (en) | 1978-11-27 | 1980-07-15 | Minnesota Mining And Manufacturing Company | Textile treatment composition |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1478041A (en) * | 1965-05-17 | 1967-04-21 | Colgate Palmolive Co | Method of treating articles for household use |
-
1972
- 1972-02-28 NL NLAANVRAGE7202574,A patent/NL169612C/en not_active IP Right Cessation
- 1972-02-28 DK DK90872A patent/DK143763C/en not_active IP Right Cessation
- 1972-02-29 SE SE7202487A patent/SE411361B/en unknown
- 1972-03-07 DE DE19722211623 patent/DE2211623A1/en active Granted
- 1972-03-07 BE BE780315A patent/BE780315A/en not_active IP Right Cessation
- 1972-03-07 GB GB1065572A patent/GB1388871A/en not_active Expired
- 1972-03-07 CH CH334072A patent/CH540382A/en not_active IP Right Cessation
- 1972-03-07 ZA ZA721516A patent/ZA721516B/en unknown
- 1972-03-07 IT IT48829/72A patent/IT952154B/en active
- 1972-03-07 CA CA136,460A patent/CA995411A/en not_active Expired
- 1972-03-07 FR FR7207839A patent/FR2128692B1/fr not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2951474A1 (en) * | 1978-12-20 | 1980-07-10 | Minnesota Mining & Mfg | ANTISTATIC MIXTURE AND THEIR USE |
US7737097B2 (en) | 2003-06-27 | 2010-06-15 | Lam Research Corporation | Method for removing contamination from a substrate and for making a cleaning solution |
Also Published As
Publication number | Publication date |
---|---|
NL169612C (en) | 1982-08-02 |
BE780315A (en) | 1972-09-07 |
CH540382A (en) | 1973-08-15 |
FR2128692A1 (en) | 1972-10-20 |
DK143763C (en) | 1982-03-22 |
DE2211623A1 (en) | 1972-09-28 |
CA995411A (en) | 1976-08-24 |
DE2211623C3 (en) | 1980-02-28 |
ZA721516B (en) | 1972-11-29 |
NL169612B (en) | 1982-03-01 |
NL7202574A (en) | 1972-09-12 |
FR2128692B1 (en) | 1975-10-24 |
DK143763B (en) | 1981-10-05 |
SE411361B (en) | 1979-12-17 |
IT952154B (en) | 1973-07-20 |
DE2211623B2 (en) | 1979-06-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |