GB1387748A - Process for the isomerization of hydrocarbons - Google Patents

Process for the isomerization of hydrocarbons

Info

Publication number
GB1387748A
GB1387748A GB2464772A GB2464772A GB1387748A GB 1387748 A GB1387748 A GB 1387748A GB 2464772 A GB2464772 A GB 2464772A GB 2464772 A GB2464772 A GB 2464772A GB 1387748 A GB1387748 A GB 1387748A
Authority
GB
United Kingdom
Prior art keywords
acid
catalyst
fluoride
hydrocarbons
sulphuryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2464772A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1387748A publication Critical patent/GB1387748A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/36—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/271—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with inorganic acids; with salts or anhydrides of acids
    • C07C5/2718—Acids of halogen; Salts thereof; complexes thereof with organic compounds
    • C07C5/2721—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2727—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with hydrides or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/20—Non-coordinating groups comprising halogens
    • B01J2540/22—Non-coordinating groups comprising halogens comprising fluorine, e.g. trifluoroacetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1387748 Isomerisation catalyst EXXON RESEARCH & ENG CO 25 May 1972 [25 June 1971] 24647/72 Heading B1E [Also in Division C5] A catalyst, used for isomerising hydrocarbons, comprises (a) at least one Lewis acid of the formula MX n where M is selected from Ti, and the elements of groups V and VIB, X is halogen and n is 3 to 6; and (b) a Bronsted acid selected from fluorosulphuric acid, chlorosulphuric acid, trifluoromethane sulphonic acid and trifluoroacetic acid and mixtures thereof. A liquid diluent, such as sulphuryl chloride fluoride, sulphuryl fluoride, or fluorinated hydrocarbns, may be present, or the catalyst may be supported on an inert support such as fluoride-coated Al 2 O 3 , or aluminosilicates. Lewis acid components used in the Examples are SbF 5 , AsF 5 , TaF 5 , NbF 5 , VF 5 , TiF 4 and MoF 6 .
GB2464772A 1971-06-25 1972-05-25 Process for the isomerization of hydrocarbons Expired GB1387748A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US15682271A 1971-06-25 1971-06-25

Publications (1)

Publication Number Publication Date
GB1387748A true GB1387748A (en) 1975-03-19

Family

ID=22561235

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2464772A Expired GB1387748A (en) 1971-06-25 1972-05-25 Process for the isomerization of hydrocarbons

Country Status (8)

Country Link
US (1) US3766286A (en)
BE (1) BE785322A (en)
CA (1) CA980798A (en)
DE (1) DE2227336A1 (en)
FR (1) FR2143432B1 (en)
GB (1) GB1387748A (en)
IT (1) IT959972B (en)
NL (1) NL7208562A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2167765A (en) * 1984-11-28 1986-06-04 El Paso Products Co Process for isomerizing butane

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE789430A (en) * 1971-10-15 1973-03-29 Inst Francais Du Petrole LOW TEMPERATURE SATURATED HYDROCARBONS ISOMERIZATION PROCESS
US3855346A (en) * 1972-01-28 1974-12-17 Phillips Petroleum Co Isomerization of paraffinic hydrocarbons with trifluoromethanesulfonic acid
US4035286A (en) * 1972-12-20 1977-07-12 Standard Oil Company (Indiana) Octane upgrading of light naphtha streams using a fluoroalkanesulfonic acid-antimony pentafluoride mixture
US4144282A (en) * 1973-08-03 1979-03-13 Standard Oil Company (Indiana) Octane upgrading of light naphtha streams using a fluorosulfonic acid, hydrofluoric acid and antimony pentafluoride catalyst
US3878261A (en) * 1973-08-24 1975-04-15 Phillips Petroleum Co Hydroisomerization of paraffin hydrocarbon with a supported catalyst of SbF{HD 5 {B and CF{HD 3{B SO{HD 3{B H
US4048247A (en) * 1975-12-29 1977-09-13 Uop Inc. Process for the conversion of aromatic hydrocarbons
US4022847A (en) * 1976-03-04 1977-05-10 Shell Oil Company Hydrocarbon conversion process using an unsupported perfluorinated polymer catalyst
IT1129809B (en) * 1979-03-26 1986-06-11 Ugine Kuhlmann CATALYTIC COMPOSITION FOR THE CONVERSION OF HYDROCARBONS AND PROCEDURE FOR THE DEHYDRATION OF PERFLUOROALCANSOLPHONIC ACIDS INTENDED TO BE PART OF THE BEAUTIFUL COMPOSITION
US4547606A (en) * 1980-03-14 1985-10-15 Pcuk Produits Chimiques Ugine Kuhlmann Selective isomerization of di-isopropyl benzene to meta-di-isopropyl benzene
US4300008A (en) * 1980-09-25 1981-11-10 Standard Oil Company (Indiana) Preparation of 2,6-dimethyldecalin and its isomers
USRE33080E (en) * 1981-08-31 1989-10-03 Exxon Research And Engineering Company Adamantane catalyzed paraffin isomerization
FR2566794A1 (en) * 1984-06-28 1986-01-03 El Paso Products Co Process for improving a natural petrol of low octane value, derived from natural gas
FR2601601A1 (en) * 1986-07-16 1988-01-22 Total France HYDROCARBON ISOMERIZATION CATALYST, PROCESS FOR THE PREPARATION AND APPLICATION OF SAID CATALYST.
US5256277A (en) * 1991-07-24 1993-10-26 Mobil Oil Corporation Paraffin isomerization process utilizing a catalyst comprising a mesoporous crystalline material
US5245103A (en) * 1992-10-19 1993-09-14 Phillips Petroleum Company Isomerization processes and catalysts therefor
US5629257A (en) * 1994-01-21 1997-05-13 Sun Company, Inc. (R&M) Solid superacid catalysts comprising platinum metal
US5516964A (en) * 1994-01-21 1996-05-14 Sun Company, Inc. (R&M) Hydrocarbon isomerization using solid superacid catalysts comprising platinum metal
US5489564A (en) * 1994-09-07 1996-02-06 Phillips Petroleum Company Alkane disproportionation
EP1326947B1 (en) * 2000-10-11 2004-09-22 Bp Oil International Limited Isomerisation process
EP1345886A1 (en) * 2000-12-18 2003-09-24 Basf Aktiengesellschaft Method for producing higher (meth)acrylic acid esters
GB0121105D0 (en) * 2001-08-31 2001-10-24 Bp Oil Int An improved process for the production of triptane
JP4273301B2 (en) * 2002-11-01 2009-06-03 三菱瓦斯化学株式会社 Method for producing alkyl aromatic compound
DE10316465A1 (en) * 2003-04-09 2004-10-28 Basf Ag Heterogeneously catalyzed partial oxidation of propane and/or isobutane to (meth)acrylic acid involves separating product, dividing residual product gas into portions to be recycled and discharged, and recycling at pressure of feeding step
EP2868644B1 (en) 2012-06-29 2018-08-01 Mitsubishi Gas Chemical Company, Inc. Method and apparatus for separating alkyl aromatic hydrocarbon

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2167765A (en) * 1984-11-28 1986-06-04 El Paso Products Co Process for isomerizing butane

Also Published As

Publication number Publication date
US3766286A (en) 1973-10-16
CA980798A (en) 1975-12-30
FR2143432A1 (en) 1973-02-02
DE2227336A1 (en) 1972-12-28
BE785322A (en) 1972-12-27
NL7208562A (en) 1972-12-28
FR2143432B1 (en) 1977-12-23
IT959972B (en) 1973-11-10

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]