GB1375178A - - Google Patents

Info

Publication number
GB1375178A
GB1375178A GB2846874A GB2846874A GB1375178A GB 1375178 A GB1375178 A GB 1375178A GB 2846874 A GB2846874 A GB 2846874A GB 2846874 A GB2846874 A GB 2846874A GB 1375178 A GB1375178 A GB 1375178A
Authority
GB
United Kingdom
Prior art keywords
anhydride
methacrylates
radiation
vinyl
acrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2846874A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to GB4677171A priority Critical patent/GB1375177A/en
Priority to GB2846874A priority patent/GB1375178A/en
Publication of GB1375178A publication Critical patent/GB1375178A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/06—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to oxygen-containing macromolecules
    • C08F291/10—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to oxygen-containing macromolecules on to macromolecules containing epoxy radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids

Abstract

1375178 Coating/polymerising with high energy radiation O'BRIEN CORP 7 Oct 1971 28468/74 Divided out of 1375177 Heading B2E [Also in Division C3] A method of coating a substrate at ambient temperatures comprises applying a film of a liquid coating composition to said substrate, said composition comprising an ethylenically unsaturated polymerisable monomer solvent and a prepolymer which is the reaction product of an acrylate functional intermediate and an epoxide containing compound, said intermediate being the reaction product of an organic acid anhydride comprising endic anhydride (2,2,1-bicyclo-5- heptene-2,3- dicarboxylic anhydride) and/or a chlorinated derivative of endic anhydride and/or an alkylated derivative of endic anahydride and a hydroxy acrylate of the formula wherein R is H or methyl and Z is an optionally substituted alkylene radical containing up to 12 carbon atoms; and curing the film by subjecting it to the influence of high energy ionising radiation, preferably electron beam radiation. If desired, the radiation curing may be followed by a thermal curing step. Suitable polymerisable solvents include vinyl esters of synthetic tertiary carboxylic acids, alkyl acrylates and methacrylates, cyclohexyl acrylate, hydroxyalkyl acrylates and methacrylates, ethylene glycol butyl ether monoacrylate, vinyl pyrrolidone, vinyl toluene, hexachlorobutadiene, styrene, ethyl vinyl benzene, isopropyl styrene, α-methyl styrene, acrylic acid, vinyl acetate, and polyol polyacrylates and methacrylates. The compositions may also include additives such as pigments, dyes, fillers and abrasives, such as CaCO 3 , MgO, BaSO 4 , Al 2 O 3 , powdered slate, asbestos or silicon carbide, or wallnut shell flour. In Examples the prepolymer is prepared by reacting together chlorendic anhydride and 2- hydroxyethyl acrylate in the presence of a polymerisation inhibitor, and then reacting the product with an epoxy novolac resin. Exemplified substrates include ceiling tiles, ABS panels and beverage containers.
GB2846874A 1970-10-23 1971-10-07 Expired GB1375178A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB4677171A GB1375177A (en) 1970-10-23 1971-10-07
GB2846874A GB1375178A (en) 1970-10-23 1971-10-07

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8364170A 1970-10-23 1970-10-23
GB2846874A GB1375178A (en) 1970-10-23 1971-10-07

Publications (1)

Publication Number Publication Date
GB1375178A true GB1375178A (en) 1974-11-27

Family

ID=60201775

Family Applications (2)

Application Number Title Priority Date Filing Date
GB2846874A Expired GB1375178A (en) 1970-10-23 1971-10-07
GB4677171A Expired GB1375177A (en) 1970-10-23 1971-10-07

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB4677171A Expired GB1375177A (en) 1970-10-23 1971-10-07

Country Status (1)

Country Link
GB (2) GB1375178A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431782A (en) * 1981-07-27 1984-02-14 The Dow Chemical Company Process for the preparation of radiation-curable, water-thinnable vinyl ester resins
DE3332503A1 (en) * 1983-09-09 1985-03-28 Basf Ag, 6700 Ludwigshafen MAGNETIC RECORDING CARRIERS
DE3332564A1 (en) * 1983-09-09 1985-03-28 Basf Ag, 6700 Ludwigshafen MAGNETIC RECORDING CARRIERS
DE3332504A1 (en) * 1983-09-09 1985-03-28 Basf Ag, 6700 Ludwigshafen MAGNETIC RECORDING CARRIERS
DE3418482A1 (en) * 1984-05-18 1985-11-21 Basf Ag, 6700 Ludwigshafen MAGNETIC RECORDING CARRIERS

Also Published As

Publication number Publication date
GB1375177A (en) 1974-11-27

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Legal Events

Date Code Title Description
PS Patent sealed
433D Application made for revocation (sect. 33/1949)
433G Case decided by the comptroller ** application refused (sect. 33/1949)
PCNP Patent ceased through non-payment of renewal fee