GB1374300A - Process for producing allylcarboxylates - Google Patents

Process for producing allylcarboxylates

Info

Publication number
GB1374300A
GB1374300A GB6085071A GB6085071A GB1374300A GB 1374300 A GB1374300 A GB 1374300A GB 6085071 A GB6085071 A GB 6085071A GB 6085071 A GB6085071 A GB 6085071A GB 1374300 A GB1374300 A GB 1374300A
Authority
GB
United Kingdom
Prior art keywords
lead
compound
carboxylate
acetate
carrier material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6085071A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Toyo Soda Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Soda Manufacturing Co Ltd filed Critical Toyo Soda Manufacturing Co Ltd
Publication of GB1374300A publication Critical patent/GB1374300A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1374300 Carboxylation catalysts TOYO SODA MFG CO Ltd 30 Dec 1971 [30 Dec 1970] 60850/71 Heading B1E [Also in Division C2] Catalyst for use in the preparation of allyl carboxylate from propylene, molecular oxygen and carboxylic acid comprises carrier material upon which is supported (a) elemental palladium, (b) a compound of lead and (c) either an alkali metal carboxylate and/or an alkaline earth metal carboxylate or an alkali metal compound and/or an alkaline earth metal compound convertible to an alkali metal carboxylate and/or an alkaline earth metal carboxylate by reaction with the carboxylic acid reactant. The carrier material may comprise alumina, silica gel, silica-alumina, aluminium, phosphate, activated carbon, silicon carbide, pumice and/or diatomaceous earth. The elemental palladium may have been obtained by reducing palladium chloride, nitrate and/or acetate in situ on the carrier material. The compound of lead may be selected from oxides, chloride, nitrate and acetate of lead. The carboxylate, which may be derived from a carboxylic acid having from 1 to 4 carbon atoms, may be an acetate, propionate or butyrate of lithium, sodium, potassium or magnesium; alternatively, the catalyst may comprise, as the compound convertible to carboxylate, a carbonate or borate such as sodium carbonate, potassium carbonate or sodium borate. The catalyst may contain, per 100 parts by weight of carrier material, from 0.01 to 10.0 parts by weight of palladium, from 0.01 to 20.0 parts by weight of a compound of lead, calculated as elemental lead, and from 0.01 to 30.0 parts by weight of alkali metal/ alkaline earth metal carboxylate. As exemplified, catalyst is prepared from activated alumina, palladium chloride, lead nitrate and either potassium acetate (Example 1) or sodium tetraborate (Example 3) or from activated carbon, palladium chloride, lead (II) acetate and magnesium acetate (Example 2) by a procedure wherein the carrier material is composited with palladium chloride from aqueous hydrochloric acid (Examples 1 and 2) or ammonia (Example 3) solution, subjected to reduction with aqueous hydrazine hydrate/ caustic soda solution (Examples 1 and 2) or hydrogen (Example 3) and thereafter composited with the lead compound and with the alkali metal/alkaline earth metal compound.
GB6085071A 1970-12-30 1971-12-30 Process for producing allylcarboxylates Expired GB1374300A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12677570A JPS505685B1 (en) 1970-12-30 1970-12-30

Publications (1)

Publication Number Publication Date
GB1374300A true GB1374300A (en) 1974-11-20

Family

ID=14943611

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6085071A Expired GB1374300A (en) 1970-12-30 1971-12-30 Process for producing allylcarboxylates

Country Status (4)

Country Link
JP (1) JPS505685B1 (en)
DE (1) DE2165738C3 (en)
FR (1) FR2120147B1 (en)
GB (1) GB1374300A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010080090A1 (en) * 2008-12-18 2010-07-15 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1521560A (en) * 1975-11-13 1978-08-16 Columbia Ribbon Carbon Mfg Production of imaged master sheets
JPS5951850B2 (en) * 1980-03-19 1984-12-17 東亜燃料工業株式会社 Catalyst for diacyloxylation of conjugated dienes
JPH0729980B2 (en) * 1988-09-29 1995-04-05 昭和電工株式会社 Method for producing allyl acetate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010080090A1 (en) * 2008-12-18 2010-07-15 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst
US7767835B2 (en) 2008-12-18 2010-08-03 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst

Also Published As

Publication number Publication date
FR2120147A1 (en) 1972-08-11
DE2165738C3 (en) 1979-03-29
DE2165738B2 (en) 1973-05-10
FR2120147B1 (en) 1973-06-08
JPS505685B1 (en) 1975-03-06
DE2165738A1 (en) 1972-07-27

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee