GB1362284A - Process for the production of a catalyst and its use in the produ ction of hydroxy-diphenyls - Google Patents
Process for the production of a catalyst and its use in the produ ction of hydroxy-diphenylsInfo
- Publication number
- GB1362284A GB1362284A GB4696171A GB4696171A GB1362284A GB 1362284 A GB1362284 A GB 1362284A GB 4696171 A GB4696171 A GB 4696171A GB 4696171 A GB4696171 A GB 4696171A GB 1362284 A GB1362284 A GB 1362284A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- alkali metal
- nickel
- carbon dioxide
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 8
- 239000000203 mixture Substances 0.000 abstract 7
- 239000001569 carbon dioxide Substances 0.000 abstract 5
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 4
- 229910052759 nickel Inorganic materials 0.000 abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 abstract 3
- 150000008041 alkali metal carbonates Chemical class 0.000 abstract 3
- 239000012018 catalyst precursor Substances 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 3
- 238000000465 moulding Methods 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 2
- 229910052936 alkali metal sulfate Inorganic materials 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 abstract 1
- UOBQDYFTAJKQAL-UHFFFAOYSA-N 2-cyclohexylcyclohexan-1-one Chemical compound O=C1CCCCC1C1CCCCC1 UOBQDYFTAJKQAL-UHFFFAOYSA-N 0.000 abstract 1
- TYDSIOSLHQWFOU-UHFFFAOYSA-N 2-cyclohexylidenecyclohexan-1-one Chemical compound O=C1CCCCC1=C1CCCCC1 TYDSIOSLHQWFOU-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- GVHGNQUVBIQFCY-UHFFFAOYSA-J C([O-])([O-])=O.[Ni](O)O.[Al+3].[Cu+2] Chemical compound C([O-])([O-])=O.[Ni](O)O.[Al+3].[Cu+2] GVHGNQUVBIQFCY-UHFFFAOYSA-J 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 1
- 230000009849 deactivation Effects 0.000 abstract 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000002816 nickel compounds Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000010926 purge Methods 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 230000003019 stabilising effect Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/685—Processes comprising at least two steps in series
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/74—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/84—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by crystallisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2049809A DE2049809C3 (de) | 1970-10-10 | 1970-10-10 | Dehydrierungskatalysator |
| DE2102476A DE2102476C3 (de) | 1970-10-10 | 1971-01-20 | Verfahren zur Reinigung von o-Hydroxydiphenyl |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1362284A true GB1362284A (en) | 1974-08-07 |
Family
ID=25759865
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4696171A Expired GB1362284A (en) | 1970-10-10 | 1971-10-08 | Process for the production of a catalyst and its use in the produ ction of hydroxy-diphenyls |
| GB4696271A Expired GB1340370A (en) | 1970-10-10 | 1971-10-08 | Process for the purification of o-hydroxydiphenyl |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4696271A Expired GB1340370A (en) | 1970-10-10 | 1971-10-08 | Process for the purification of o-hydroxydiphenyl |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS541699B1 (enrdf_load_stackoverflow) |
| AU (1) | AU457367B2 (enrdf_load_stackoverflow) |
| CA (1) | CA952538A (enrdf_load_stackoverflow) |
| CH (2) | CH563808A5 (enrdf_load_stackoverflow) |
| DE (1) | DE2102476C3 (enrdf_load_stackoverflow) |
| FR (2) | FR2122841A5 (enrdf_load_stackoverflow) |
| GB (2) | GB1362284A (enrdf_load_stackoverflow) |
| NL (1) | NL166915C (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4057581A (en) * | 1975-05-10 | 1977-11-08 | Bayer Aktiengesellschaft | Process for preparing diphenylamines |
| CN102399135A (zh) * | 2010-09-09 | 2012-04-04 | 东营远大化工有限公司 | 一种邻苯基苯酚的制备和分离精制方法 |
| WO2012050665A1 (en) * | 2010-10-11 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5136445A (en) * | 1974-09-21 | 1976-03-27 | Sumitomo Chemical Co | Oo fuenirufuenooru no seiseiho |
| JPS6129655U (ja) * | 1984-07-28 | 1986-02-22 | 行雄 栗田 | 書画類掲示具 |
| CN115745750B (zh) * | 2022-09-28 | 2023-12-15 | 山东天隅新材料科技有限公司 | 邻苯基苯酚、制备方法及其应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1108221B (de) * | 1959-03-21 | 1961-06-08 | Bayer Ag | Verfahren zur Lenkung der Wirkungsweise von Dehydrierungskatalysatoren fuer hydroaromatische Verbindungen |
| DE2049809C3 (de) * | 1970-10-10 | 1975-10-30 | Bayer Ag, 5090 Leverkusen | Dehydrierungskatalysator |
-
1971
- 1971-01-20 DE DE2102476A patent/DE2102476C3/de not_active Expired
- 1971-10-05 AU AU34149/71A patent/AU457367B2/en not_active Expired
- 1971-10-07 CH CH1465171A patent/CH563808A5/xx not_active IP Right Cessation
- 1971-10-07 CA CA124,655A patent/CA952538A/en not_active Expired
- 1971-10-07 CH CH410275A patent/CH566948A5/xx not_active IP Right Cessation
- 1971-10-08 GB GB4696171A patent/GB1362284A/en not_active Expired
- 1971-10-08 FR FR7136351A patent/FR2122841A5/fr not_active Expired
- 1971-10-08 NL NL7113876.A patent/NL166915C/xx not_active IP Right Cessation
- 1971-10-08 FR FR7136350A patent/FR2111179A5/fr not_active Expired
- 1971-10-08 GB GB4696271A patent/GB1340370A/en not_active Expired
- 1971-10-11 JP JP8010771A patent/JPS541699B1/ja active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4057581A (en) * | 1975-05-10 | 1977-11-08 | Bayer Aktiengesellschaft | Process for preparing diphenylamines |
| CN102399135A (zh) * | 2010-09-09 | 2012-04-04 | 东营远大化工有限公司 | 一种邻苯基苯酚的制备和分离精制方法 |
| WO2012050665A1 (en) * | 2010-10-11 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| CN103153456A (zh) * | 2010-10-11 | 2013-06-12 | 埃克森美孚化学专利公司 | 用于制备苯酚的方法 |
| US8884075B2 (en) | 2010-10-11 | 2014-11-11 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
Also Published As
| Publication number | Publication date |
|---|---|
| CA952538A (en) | 1974-08-06 |
| AU457367B2 (en) | 1975-01-30 |
| JPS541699B1 (enrdf_load_stackoverflow) | 1979-01-27 |
| NL166915B (nl) | 1981-05-15 |
| FR2122841A5 (enrdf_load_stackoverflow) | 1972-09-01 |
| NL166915C (nl) | 1981-10-15 |
| DE2102476A1 (de) | 1972-08-03 |
| AU3414971A (en) | 1973-04-19 |
| CH563808A5 (enrdf_load_stackoverflow) | 1975-07-15 |
| GB1340370A (en) | 1973-12-12 |
| DE2102476C3 (de) | 1974-02-28 |
| FR2111179A5 (enrdf_load_stackoverflow) | 1972-06-02 |
| DE2102476B2 (de) | 1973-08-02 |
| CH566948A5 (enrdf_load_stackoverflow) | 1975-09-30 |
| NL7113876A (enrdf_load_stackoverflow) | 1972-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |