GB1344006A - Process for the manufacture of organopolysiloxane compositions which cure at room temperature to give elastomers - Google Patents
Process for the manufacture of organopolysiloxane compositions which cure at room temperature to give elastomersInfo
- Publication number
- GB1344006A GB1344006A GB2189371A GB2189371A GB1344006A GB 1344006 A GB1344006 A GB 1344006A GB 2189371 A GB2189371 A GB 2189371A GB 2189371 A GB2189371 A GB 2189371A GB 1344006 A GB1344006 A GB 1344006A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silane
- sio
- formula
- radical
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
Abstract
1344006 Organopolysiloxane compositions WACKER-CHEMIE GmbH 19 April 1971 [16 Feb 1970] 21893/71 Headings C3T and C3R A composition which cures to an elastomer on exposure to moisture at room temperature is made by mixing (1) a diorganopolysiloxane having reactive end groups preferably hydroxyl groups, with (2) a silicon compound having at least one nitrogen atom and three hydrolysable groups, (3) reinforcing fillers having a surface area of at least 50 m.<SP>2</SP>/g. and (4) a polyglycol which can be etherified and/or esterified, with the proviso that the said polyglycol is not etherified by a silyl radical containing an acyloxy, ketoximo, keto-oximato, amino- or aminoxy group and (5) optional conventional ingredients. Examples of (2) are silanes of formula R a Si(ON = X) 4-a , R a Si(NRR<SP>3</SP>) 4-a , where R is a hydrocarbon (h.c.) or substituted h.c., X is RR<SP>1</SP>C=, or R<SP>2</SP>C= where R<SP>1</SP>=H or R, R<SP>a</SP>h.c., a=0 or 1. Further examples include R a SiY 4-a where Y= ONR 2 , ONR<SP>2</SP>, NCO, NCS; organopolysiloxanes where m = 0-20, e =0-3; where d is at least 1. Component (2) is preferably used in amounts of 0À2-15% wt. of the total composition. Examples of component (3) are fillers having a surface area greater than 50 m.<SP>2</SP>/g. such as pyrogenic SiO 2 , SiO 2 aerogel, precipitated SiO 2 , metal oxides, e.g. TiO 2 , Fe 2 O 3 , Al 2 O 3 and ZnO. Component (3) is preferably used in amounts of 1-15% wt. relative to the total weight of all organo-silicon compounds in the composition. Examples of component (4) are polyglycol ethers of formula RO[(CHR<SP>6</SP>) p O) s H where R<SP>6</SP> is H or alkyl, p = 2-5, s = 2-100; polypropylene oxidepolyethylene oxide condensation products; organopolysiloxane-polyoxyalkylene copolymers of general formulµ A(R) 2 Si[OSi(R)A] p OSi(R) 2 A where A is [(CHR<SP>6</SP>) p O] s R<SP>7</SP> where R<SP>7</SP> is hydrogen, a monovalent h.c., an acyl radical, a triorganosilyl radical, a diorgano-(hydrocarbonoxy)silyl radical or a radical of the formula where p<SP>1</SP> is 1-50 and B is SiR 3 , A, or OSi(R) 2 A. The polyglycols are preferably used in amounts of 0À5-30% wt. relative to the diorganopolysiloxanes (1). In Example 1 the composition comprises an OH-terminated dimethylpolysiloxane of 18,800 cP/25‹ C., trimethylsiloxy-end-blocked dimethylpolysiloxane of 35 eP/25‹ C., pyrogenic SiO 2 , an organopolysiloxanepolyoxyalkylene block copolymer and methyl-tris-(cyclohexyl-amino)- silane. In Example 2 the silane of Example 1 is replaced by a mixture of and dibutyl tin dilaurate. In Example 3 the composition comprises OH-terminated dimethylpolysiloxanes of 350,000 cP/25‹ C. and 19,000 cP/25‹ C., a trimethylsiloxy-terminated dimethylpolysiloxane of 1000 cP/25‹ C., a tributyl phenol etherified with a polyethylene glycol of 13 ethylene oxide units, pyrogenic SiO 2 , calcined aluminium silicate and a mixture of a silane of the formula and methyl - tris - (cyclohexylamino) - silane, and dibutyl tin dilaurate. Uses.-Sealing joints and cavities; protective coatings; and electrical insulation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2007002A DE2007002C3 (en) | 1970-02-16 | 1970-02-16 | Improvement of the stability of organopolysiloxane compositions which cure to elastomers at room temperature |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1344006A true GB1344006A (en) | 1974-01-16 |
Family
ID=5762411
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2189371A Expired GB1344006A (en) | 1970-02-16 | 1971-04-19 | Process for the manufacture of organopolysiloxane compositions which cure at room temperature to give elastomers |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS4943377B1 (en) |
AT (1) | AT315492B (en) |
BE (1) | BE763011A (en) |
CA (1) | CA922827A (en) |
CH (1) | CH549616A (en) |
DE (1) | DE2007002C3 (en) |
ES (1) | ES388248A1 (en) |
FR (1) | FR2080523B1 (en) |
GB (1) | GB1344006A (en) |
NL (1) | NL164592C (en) |
NO (1) | NO140191C (en) |
SE (1) | SE368217B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2455622A1 (en) * | 1979-04-30 | 1980-11-28 | Gen Electric | AMBIENT TEMPERATURE VULCANIZABLE SILICONE RUBBER COMPOSITIONS HAVING CONTROLLED SUSPENSION, AND PROCESS FOR PREPARING THE SAME |
US4525565A (en) * | 1982-07-30 | 1985-06-25 | Rhone-Poulenc Specialites Chimiques | Single component organopolysiloxane compositions containing silanes with acyloxy or ketoniminoxy groups as cross linking agents and organic derivatives of titanium or zirconium as catalysts |
EP2966115A3 (en) * | 2014-07-11 | 2016-02-24 | The Boeing Company | Temperature-resistant silicone resins |
US10563017B2 (en) | 2014-07-11 | 2020-02-18 | The Boeing Company | Temperature-resistant silicone resins |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT326915B (en) * | 1971-02-12 | 1976-01-12 | Wacker Chemie Gmbh | PRODUCTION OF MOLDS FROM IMPRESSION MATERIALS BASED ON HARDABLE DIORGANOPOLYSILOXANES |
JP3024315U (en) * | 1995-11-01 | 1996-05-21 | 孝夫 菅野 | Tissue paper removal sheet |
-
1970
- 1970-02-16 DE DE2007002A patent/DE2007002C3/en not_active Expired
-
1971
- 1971-02-12 AT AT121471A patent/AT315492B/en not_active IP Right Cessation
- 1971-02-13 ES ES388248A patent/ES388248A1/en not_active Expired
- 1971-02-15 FR FR7104966A patent/FR2080523B1/fr not_active Expired
- 1971-02-15 NL NL7101996.A patent/NL164592C/en not_active IP Right Cessation
- 1971-02-15 SE SE01886/71A patent/SE368217B/xx unknown
- 1971-02-15 NO NO540/71A patent/NO140191C/en unknown
- 1971-02-15 CA CA105350A patent/CA922827A/en not_active Expired
- 1971-02-16 CH CH222371A patent/CH549616A/en not_active IP Right Cessation
- 1971-02-16 BE BE763011A patent/BE763011A/en not_active IP Right Cessation
- 1971-02-16 JP JP46007047A patent/JPS4943377B1/ja active Pending
- 1971-04-19 GB GB2189371A patent/GB1344006A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2455622A1 (en) * | 1979-04-30 | 1980-11-28 | Gen Electric | AMBIENT TEMPERATURE VULCANIZABLE SILICONE RUBBER COMPOSITIONS HAVING CONTROLLED SUSPENSION, AND PROCESS FOR PREPARING THE SAME |
US4525565A (en) * | 1982-07-30 | 1985-06-25 | Rhone-Poulenc Specialites Chimiques | Single component organopolysiloxane compositions containing silanes with acyloxy or ketoniminoxy groups as cross linking agents and organic derivatives of titanium or zirconium as catalysts |
EP2966115A3 (en) * | 2014-07-11 | 2016-02-24 | The Boeing Company | Temperature-resistant silicone resins |
US9534089B2 (en) | 2014-07-11 | 2017-01-03 | The Boeing Company | Temperature-resistant silicone resins |
US10189953B2 (en) | 2014-07-11 | 2019-01-29 | The Boeing Company | Temperature-resistant silicone resins |
US10563017B2 (en) | 2014-07-11 | 2020-02-18 | The Boeing Company | Temperature-resistant silicone resins |
Also Published As
Publication number | Publication date |
---|---|
SE368217B (en) | 1974-06-24 |
BE763011A (en) | 1971-08-16 |
NO140191C (en) | 1979-07-18 |
NL164592C (en) | 1981-01-15 |
CA922827A (en) | 1973-03-13 |
AT315492B (en) | 1974-05-27 |
JPS4943377B1 (en) | 1974-11-20 |
FR2080523B1 (en) | 1973-10-19 |
CH549616A (en) | 1974-05-31 |
FR2080523A1 (en) | 1971-11-19 |
NL164592B (en) | 1980-08-15 |
ES388248A1 (en) | 1973-05-01 |
NL7101996A (en) | 1971-08-18 |
DE2007002B2 (en) | 1973-07-05 |
DE2007002A1 (en) | 1971-08-26 |
DE2007002C3 (en) | 1974-02-14 |
NO140191B (en) | 1979-04-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |