GB1339376A - Thermoplastic acrylic powder coating compositions - Google Patents

Thermoplastic acrylic powder coating compositions

Info

Publication number
GB1339376A
GB1339376A GB2564772A GB2564772A GB1339376A GB 1339376 A GB1339376 A GB 1339376A GB 2564772 A GB2564772 A GB 2564772A GB 2564772 A GB2564772 A GB 2564772A GB 1339376 A GB1339376 A GB 1339376A
Authority
GB
United Kingdom
Prior art keywords
methacrylate
ethyl
acrylate
poly
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2564772A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ford Motor Co Ltd
Ford Motor Co
Original Assignee
Ford Motor Co Ltd
Ford Motor Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ford Motor Co Ltd, Ford Motor Co filed Critical Ford Motor Co Ltd
Publication of GB1339376A publication Critical patent/GB1339376A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08Homopolymers or copolymers of acrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

1339376 Acrylic powder coating compositions FORD MOTOR CO Ltd 1 June 1972 [16 Aug 1971] 25647/72 Heading C3P A powder coating composition comprises a mixture of (A) a thermoplastic acrylic polymer of number average molecular weight 30,000 to 80,000 and a Tg of 60-110‹ C.; (B) an antistatic agent present in an amount sufficient to give the composition a resistivity of 10<SP>6</SP> to 10<SP>11</SP> ohm/cm; and (c) 0À1 to 10% by wt. based on the total composition, of a flow control agent which is a polymer having a number average molecular weight of at least 1000 and a Tg below 40‹ C. The acrylic polymer may be, for example, polymethyl methacrylate, polyethyl methacrylate, or a copolymer of two or more of methyl methacrylate, ethyl methacrylate, butyl methacrylate, ethyl acrylate, butyl acrylate, styrene, acrylonitrile and methacrylonitrile. The polymer may also contain units derived from glycidyl methacrylate or methacrylic acid. The antistatic agent may preferably be a solid tertiary amine or 2- methyl-4-ethyl imidazole. Others such as alkyl(polyethyleneoxy) phosphates, alkyl aryl (polyethyleneoxy) phosphates, polyethyleneimine, poly(2-vinylpyrollidone), pyridinium chloride, poly(vinyl pyridinium chloride); polyvinyl alcohol and certain inorganic salts, may also be used. Examples of the flow control agent are polylauryl acrylate or methacrylate, polybutyl acrylate, poly(2-ethyl-hexyl acrylate), or poly- (2-ethyl hexyl methacrylate). The flow control agent may also be a fluorinated polymer such as an ester of a polyethylene or polypropylene glycol with a fluorinated fatty acid such as perfluorooctanoic acid. The composition may also contain a pigment and/or plasticizer. In use the powders are coated on to substrates e.g. by electrostatic methods, and baked on. In the examples, steel panels are coated.
GB2564772A 1971-08-16 1972-06-01 Thermoplastic acrylic powder coating compositions Expired GB1339376A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17222771A 1971-08-16 1971-08-16

Publications (1)

Publication Number Publication Date
GB1339376A true GB1339376A (en) 1973-12-05

Family

ID=22626832

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2564772A Expired GB1339376A (en) 1971-08-16 1972-06-01 Thermoplastic acrylic powder coating compositions

Country Status (12)

Country Link
JP (1) JPS5032092B2 (en)
AT (1) AT321424B (en)
AU (1) AU469520B2 (en)
BE (1) BE787556A (en)
BR (1) BR7205246D0 (en)
CA (1) CA979132A (en)
FR (1) FR2149361B1 (en)
GB (1) GB1339376A (en)
IT (1) IT962104B (en)
NL (1) NL149207B (en)
SE (1) SE378835B (en)
ZA (1) ZA724301B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1015084A (en) * 1972-05-10 1977-08-02 Rohm And Haas Company Acrylic oligomers as melt flow modifiers of thermoplastic coatings and powders
JPS5138258A (en) * 1974-09-30 1976-03-30 Japan National Railway JIDOREER UNIKUMORY OSHASOCHI
US4113681A (en) 1977-05-10 1978-09-12 E. I. Du Pont De Nemours And Company Thermoplastic polyvinyl chloride-acrylic powder coating composition

Also Published As

Publication number Publication date
DE2240184A1 (en) 1973-03-01
AT321424B (en) 1975-03-25
NL149207B (en) 1976-04-15
JPS4828549A (en) 1973-04-16
CA979132A (en) 1975-12-02
BE787556A (en) 1972-12-01
BR7205246D0 (en) 1973-06-14
SE378835B (en) 1975-09-15
AU4456672A (en) 1974-01-17
DE2240184B2 (en) 1976-07-29
AU469520B2 (en) 1976-02-19
ZA724301B (en) 1973-03-28
IT962104B (en) 1973-12-20
FR2149361B1 (en) 1974-12-27
JPS5032092B2 (en) 1975-10-17
NL7211184A (en) 1973-02-20
FR2149361A1 (en) 1973-03-30

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Legal Events

Date Code Title Description
PS Patent sealed
435 Patent endorsed 'licences of right' on the date specified (sect. 35/1949)
PCNP Patent ceased through non-payment of renewal fee