GB1337752A - Zeolite - Google Patents

Zeolite

Info

Publication number
GB1337752A
GB1337752A GB5680370A GB5680370A GB1337752A GB 1337752 A GB1337752 A GB 1337752A GB 5680370 A GB5680370 A GB 5680370A GB 5680370 A GB5680370 A GB 5680370A GB 1337752 A GB1337752 A GB 1337752A
Authority
GB
United Kingdom
Prior art keywords
zeolite
catalyst
sio
formation
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5680370A
Inventor
H W Kouwenhoven
J F Cole
Beem M J L Van
K G Y A S Kuijpers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NLAANVRAGE6918060,A external-priority patent/NL167393C/en
Priority claimed from NL7014021A external-priority patent/NL7014021A/en
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1337752A publication Critical patent/GB1337752A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2869—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of other types characterised by an X-ray spectrum and a definite composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/28—Propane and butane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

1337752 Zeolite SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 30 Nov 1970 [2 Dec 1969 22 Sept 1970] 56803/70 Heading C1A [Also in Divisions B1 and C5] A novel zeolite KSO1 is characterized by (i) its X-ray diffraction pattern which includes the reflections listed in Table A (not shown), (ii) its molar composition expressed as 0À7-1À2 Na 2 O.Al 2 O 3 .4À7-5À3 SiO 2 .xH 2 O, where x is not more than 12, and (iii) specified absorption properties for hexane and 2,3-dimethylbutane. The zeolite is prepared from an aqueous mixture of sodium hydroxide and a cogel of aluminium hydroxide on a silica hydrogel, composition represented by 3À5-4À5 Na 2 O.Al 2 O 3 . 9À5-13À0 SiO 2 .100-400 H 2 O, by agitating at 70-160‹ C. at atmospheric, or autogenous pressure in an autoclave, until the product crystallizes (at least 4 hours), filtering, washing with water and drying at at least 100‹ C. Agitation is essential throughout the reaction (formation) to ensure the formation of the desired zeolite. The zeolite has value as a catalyst, a catalyst carrier, an adsorbent, extractant, drying agent, or ion exchanger. When used as a catalyst the zeolite is preferably stabilized exchanging with NH 4 <SP>+</SP>, H<SP>+</SP>, or Ca<SP>+</SP> + to reduce the Na<SP>+</SP> content to below 1%. The product zeolite when used as a catalyst may have ions of metals of Groups IB, IIB, VB, VI B , VIIB and/or VIII incorporated into it by ion exchange.
GB5680370A 1969-12-02 1970-11-30 Zeolite Expired GB1337752A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NLAANVRAGE6918060,A NL167393C (en) 1969-12-02 1969-12-02 METHOD FOR PREPARING A ZEOLITE
NL7014021A NL7014021A (en) 1970-09-22 1970-09-22 Zeolite ksoi prodn

Publications (1)

Publication Number Publication Date
GB1337752A true GB1337752A (en) 1973-11-21

Family

ID=26644497

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5680370A Expired GB1337752A (en) 1969-12-02 1970-11-30 Zeolite

Country Status (6)

Country Link
JP (1) JPS5023389B1 (en)
CA (1) CA986495A (en)
DE (2) DE2058908C3 (en)
FR (1) FR2072607A5 (en)
GB (1) GB1337752A (en)
SE (2) SE374386B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5041402A (en) * 1988-12-22 1991-08-20 Imperial Chemical Industries Plc Catalytic reactions using zeolites
US5178748A (en) * 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1012956A (en) * 1972-08-25 1977-06-28 Shell Canada Limited Process for the preparation of a catalyst
NL7313370A (en) * 1973-09-28 1975-04-02 Shell Int Research ZEOLITE.
JPS5179586U (en) * 1974-09-30 1976-06-23
JPS5525412U (en) * 1978-08-07 1980-02-19
JPS57186363U (en) * 1981-05-21 1982-11-26
US5192522A (en) * 1991-11-26 1993-03-09 Uop Zeolite LZ-277 and process for preparing same
DE10114985C5 (en) * 2001-03-26 2017-08-24 Hans-Peter Noack Process for the production of mineral wool

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1038017B (en) * 1953-12-24 1958-09-04 Union Carbide Corp Process for making crystalline zeolitic molecular sieves
DE1100010B (en) * 1958-03-31 1961-02-23 Union Carbide Corp Process for making crystalline zeolitic molecular sieves
DE1545332A1 (en) * 1965-08-10 1969-06-19 Mobil Oil Corp Process for the conversion of hydrocarbons
NL159635B (en) * 1967-09-29 1979-03-15 Shell Int Research METHOD OF PREPARING MORDENITE.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5041402A (en) * 1988-12-22 1991-08-20 Imperial Chemical Industries Plc Catalytic reactions using zeolites
US5178748A (en) * 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites
US5345021A (en) * 1988-12-22 1994-09-06 Imperial Chemical Industries Plc Catalytic reactions using zeolites

Also Published As

Publication number Publication date
CA986495A (en) 1976-03-30
JPS5023389B1 (en) 1975-08-07
DE2058871B2 (en) 1978-10-05
DE2058871A1 (en) 1971-06-09
DE2058908B2 (en) 1979-02-22
FR2072607A5 (en) 1971-09-24
SE374386B (en) 1975-03-03
SE364246B (en) 1974-02-18
DE2058908A1 (en) 1971-06-09
DE2058871C3 (en) 1983-12-08
DE2058908C3 (en) 1982-03-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee