GB1336926A - Method of producing organochlorosilanes - Google Patents
Method of producing organochlorosilanesInfo
- Publication number
- GB1336926A GB1336926A GB3116971A GB3116971A GB1336926A GB 1336926 A GB1336926 A GB 1336926A GB 3116971 A GB3116971 A GB 3116971A GB 3116971 A GB3116971 A GB 3116971A GB 1336926 A GB1336926 A GB 1336926A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzene
- bis
- aryl
- organochlorosilanes
- chloroaryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001367 organochlorosilanes Chemical class 0.000 title abstract 2
- -1 C3S Organochlorosilanes Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000000732 arylene group Chemical group 0.000 abstract 2
- 229920001971 elastomer Polymers 0.000 abstract 2
- 230000005865 ionizing radiation Effects 0.000 abstract 2
- 239000005060 rubber Substances 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- COFLYCFUVHLITN-UHFFFAOYSA-N chloro-[4-[chloro(dimethyl)silyl]phenyl]-dimethylsilane Chemical compound C[Si](C)(Cl)C1=CC=C([Si](C)(C)Cl)C=C1 COFLYCFUVHLITN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- HWLXPMPWDYWLLV-UHFFFAOYSA-N dichloro-(2,3-dichlorophenyl)-methylsilane Chemical compound ClC=1C(=C(C=CC1)[Si](Cl)(Cl)C)Cl HWLXPMPWDYWLLV-UHFFFAOYSA-N 0.000 abstract 1
- VEUCVLXBNOEFRD-UHFFFAOYSA-N dichloro-[4-[dichloro(methyl)silyl]phenyl]-methylsilane Chemical compound C[Si](Cl)(Cl)C1=CC=C([Si](C)(Cl)Cl)C=C1 VEUCVLXBNOEFRD-UHFFFAOYSA-N 0.000 abstract 1
- PKIXSJOQYWIDLC-UHFFFAOYSA-N dichloro-methyl-(2,3,4,5,6-pentafluorophenyl)silane Chemical compound C[Si](Cl)(Cl)C1=C(F)C(F)=C(F)C(F)=C1F PKIXSJOQYWIDLC-UHFFFAOYSA-N 0.000 abstract 1
- GNEPOXWQWFSSOU-UHFFFAOYSA-N dichloro-methyl-phenylsilane Chemical compound C[Si](Cl)(Cl)C1=CC=CC=C1 GNEPOXWQWFSSOU-UHFFFAOYSA-N 0.000 abstract 1
- 238000010894 electron beam technology Methods 0.000 abstract 1
- 125000004407 fluoroaryl group Chemical group 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920001558 organosilicon polymer Polymers 0.000 abstract 1
- 239000005054 phenyltrichlorosilane Substances 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 abstract 1
- VPXMOPVXKIQKCJ-UHFFFAOYSA-N trichloro(thiophen-2-yl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CS1 VPXMOPVXKIQKCJ-UHFFFAOYSA-N 0.000 abstract 1
- OPFQVUPHZIFJLS-UHFFFAOYSA-N trichloro-(4-trichlorosilylphenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=C([Si](Cl)(Cl)Cl)C=C1 OPFQVUPHZIFJLS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicon Polymers (AREA)
Abstract
1336926 Organochlorosilanes B I VAINSHTEIN A V ZIMIN E A CHERNYSHOV M E KUREK A N POLIVANOY L P BOGOVTSEVA E S STARODUBTSEV Z A I MASLJUKOV V I ANDREEV A E ZERETS and B I ZOROV 2 July 1971 [4 July 1970] 31169/71 Heading C3S Organochlorosilanes of the formulµ RR<SP>1</SP> n Si- Cl 3-n and R<SP>11</SP>(SiR<SP>1</SP> n Cl 3-n ) 2 , wherein R denotes aryl, chloroaryl, fluoroaryl, fluorochloroaryl, functionally-substituted aryl or a heterocyclic radical, R<SP>1</SP> deontes aryl or alkyl, R<SP>11</SP> denotes arylene, chloroarylene, fluoroarylene or functonally-substituted arylene, and n is 0, 1 or 2, are prepared by vapour phase reaction between hydrochlorosilanes of the formula HSiR<SP>1</SP> n Cl 3-n and chloroaryl compounds of the formula RCl or R<SP>11</SP>Cl 2 at temperatures not exceeding 450‹ C. and under the action of ionizing radiation. Atmospheric or elevated pressures may be employed. Suitable ionizing radiation includes gamma and beta radiation, and fast electron beams. Examples describe the preparation of phenyltrichlorosilane, methylphenyldichlorosilane, methyldichlorophenyldichlorosilane, ortho - trichlorosilyldiphenyl, meta - trifluoromethylphenyltrichlorosilane, 2 - trichlorosilylthiophene, ortho - trichlorosilylbenzonitrile, methylpentafluorophenyldichlorosilane, 1,4-bis- (trichlorosilyl)benzene, 1,4 - bis - (methyldichlorosilyl)benzene and 1,4-bis-(dimethylchlorosilyl)benzene. Other possible products are also specified. Uses.-The monomer products may be used to prepare resins, rubbers, cured rubbers and other organosilicon polymers.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU1447056A SU316335A1 (en) | 1970-07-04 | Method of producing organochlorosilane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1336926A true GB1336926A (en) | 1973-11-14 |
Family
ID=20453833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3116971A Expired GB1336926A (en) | 1970-07-04 | 1971-07-02 | Method of producing organochlorosilanes |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE2132569C3 (en) |
| FR (1) | FR2100122A5 (en) |
| GB (1) | GB1336926A (en) |
| IT (1) | IT941420B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI845161A0 (en) * | 1984-12-28 | 1984-12-28 | Ksv Chemicals Oy | YTBEHANDLINGSMEDEL. |
| DE10349286A1 (en) | 2003-10-23 | 2005-05-25 | Wacker-Chemie Gmbh | Production of organosilane, e.g. phenyltrichlorosilane, involves reacting a hydrogen-silane with a halogenated hydrocarbon in presence of a radical initiator of the alkane, diazene or disilane type, e.g. 1,2-diphenylethane |
-
1971
- 1971-06-30 DE DE2132569A patent/DE2132569C3/en not_active Expired
- 1971-07-01 FR FR7124112A patent/FR2100122A5/fr not_active Expired
- 1971-07-02 GB GB3116971A patent/GB1336926A/en not_active Expired
- 1971-07-03 IT IT26639/71A patent/IT941420B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2100122A5 (en) | 1972-03-17 |
| IT941420B (en) | 1973-03-01 |
| DE2132569B2 (en) | 1974-10-31 |
| DE2132569C3 (en) | 1975-06-12 |
| DE2132569A1 (en) | 1972-02-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |